Selective Recognition and Extraction of Short-Chain Perfluoroalkyl Carboxylates by a Supramolecular Receptor
Xue-Zhi Wang
Institut des Sciences et Ingénierie Chimiques, Ecole Polytechnique Fédérale de Lausanne (EPFL), Lausanne, 1015 Switzerland
College of Chemistry and Materials Science, Guangdong Provincial Key Laboratory of Supramolecular Coordination Chemistry, Jinan University, Guangzhou, 510632 P.R. China
Medical Imaging Center, The First Affiliated Hospital, Jinan University, Guangzhou, 510632 P.R. China
Search for more papers by this authorDamien W. Chen
Institut des Sciences et Ingénierie Chimiques, Ecole Polytechnique Fédérale de Lausanne (EPFL), Lausanne, 1015 Switzerland
Search for more papers by this authorFarzaneh Fadaei-Tirani
Institut des Sciences et Ingénierie Chimiques, Ecole Polytechnique Fédérale de Lausanne (EPFL), Lausanne, 1015 Switzerland
Search for more papers by this authorXiao-Ping Zhou
College of Chemistry and Materials Science, Guangdong Provincial Key Laboratory of Supramolecular Coordination Chemistry, Jinan University, Guangzhou, 510632 P.R. China
Search for more papers by this authorCorresponding Author
Kay Severin
Institut des Sciences et Ingénierie Chimiques, Ecole Polytechnique Fédérale de Lausanne (EPFL), Lausanne, 1015 Switzerland
E-mail: [email protected]
Search for more papers by this authorXue-Zhi Wang
Institut des Sciences et Ingénierie Chimiques, Ecole Polytechnique Fédérale de Lausanne (EPFL), Lausanne, 1015 Switzerland
College of Chemistry and Materials Science, Guangdong Provincial Key Laboratory of Supramolecular Coordination Chemistry, Jinan University, Guangzhou, 510632 P.R. China
Medical Imaging Center, The First Affiliated Hospital, Jinan University, Guangzhou, 510632 P.R. China
Search for more papers by this authorDamien W. Chen
Institut des Sciences et Ingénierie Chimiques, Ecole Polytechnique Fédérale de Lausanne (EPFL), Lausanne, 1015 Switzerland
Search for more papers by this authorFarzaneh Fadaei-Tirani
Institut des Sciences et Ingénierie Chimiques, Ecole Polytechnique Fédérale de Lausanne (EPFL), Lausanne, 1015 Switzerland
Search for more papers by this authorXiao-Ping Zhou
College of Chemistry and Materials Science, Guangdong Provincial Key Laboratory of Supramolecular Coordination Chemistry, Jinan University, Guangzhou, 510632 P.R. China
Search for more papers by this authorCorresponding Author
Kay Severin
Institut des Sciences et Ingénierie Chimiques, Ecole Polytechnique Fédérale de Lausanne (EPFL), Lausanne, 1015 Switzerland
E-mail: [email protected]
Search for more papers by this authorAbstract
A supramolecular receptor for short-chain perfluoroalkyl carboxylates was developed. The receptor displays a cage-like geometry, with a defined binding site for the carboxylate head groups and an opening for the perfluoroalkyl side chains. The anionic guests are bound via multiple CH···O hydrogen bonds, as revealed by the crystallographic analysis of an adduct between the receptor and trifluoroacetate. The receptor can be used for the selective extraction of perfluoroalkyl carboxylates from buffered aqueous solutions containing fluoride, chloride, nitrate, carbonate, acetate, and phosphate.
Conflict of Interests
The authors declare no conflict of interest.
Open Research
Data Availability Statement
The data that support the findings of this study are available from the corresponding author upon reasonable request.
Supporting Information
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