Volume 135, Issue 21 e202304253

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Rücktitelbild: Metal-Organic Framework Supported Copper Photoredox Catalysts for Iminyl Radical-Mediated Reactions (Angew. Chem. 21/2023)

Dr. Ben Ma,

Dr. Ben Ma

Department of Chemistry, The University of Hong Kong, Pokfulam Road, Hong Kong, P. R. China

State Key Laboratory of Synthetic Chemistry, The University of Hong Kong, Pokfulam Road, Hong Kong, P. R. China

These authors contributed equally to this work.

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Qi Xia,

Qi Xia

Department of Chemistry, The University of Hong Kong, Pokfulam Road, Hong Kong, P. R. China

These authors contributed equally to this work.

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Deyang Wang,

Deyang Wang

Department of Chemistry, The University of Hong Kong, Pokfulam Road, Hong Kong, P. R. China

These authors contributed equally to this work.

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Dr. Ji-Kang Jin,

Dr. Ji-Kang Jin

Department of Chemistry, The University of Hong Kong, Pokfulam Road, Hong Kong, P. R. China

College of Chemistry and Materials Science, Guangdong Provincial Key Laboratory of Functional Supramolecular Coordination Materials and Applications, Jinan University, Guangzhou, 510632 P. R. China

These authors contributed equally to this work.

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Zekun Li,

Zekun Li

Department of Chemistry, The University of Hong Kong, Pokfulam Road, Hong Kong, P. R. China

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Qiu-Jiang Liang,

Qiu-Jiang Liang

Department of Chemistry, The University of Hong Kong, Pokfulam Road, Hong Kong, P. R. China

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Meng-Ying Sun,

Meng-Ying Sun

Department of Chemistry, The University of Hong Kong, Pokfulam Road, Hong Kong, P. R. China

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Dongyi Liu,

Dongyi Liu

Department of Chemistry, The University of Hong Kong, Pokfulam Road, Hong Kong, P. R. China

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Li-Juan Liu,

Li-Juan Liu

Department of Chemistry, The University of Hong Kong, Pokfulam Road, Hong Kong, P. R. China

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Dr. Hui-Xing Shu,

Dr. Hui-Xing Shu

Department of Chemistry, The University of Hong Kong, Pokfulam Road, Hong Kong, P. R. China

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Prof. Dr. Jun Yang,

Prof. Dr. Jun Yang

Department of Chemistry, The University of Hong Kong, Pokfulam Road, Hong Kong, P. R. China

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Prof. Dr. Dan Li,

Corresponding Author

Prof. Dr. Dan Li

[email protected]

College of Chemistry and Materials Science, Guangdong Provincial Key Laboratory of Functional Supramolecular Coordination Materials and Applications, Jinan University, Guangzhou, 510632 P. R. China

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Prof. Dr. Jian He,

Corresponding Author

Prof. Dr. Jian He

[email protected]

orcid.org/0000-0002-3388-3239

Department of Chemistry, The University of Hong Kong, Pokfulam Road, Hong Kong, P. R. China

State Key Laboratory of Synthetic Chemistry, The University of Hong Kong, Pokfulam Road, Hong Kong, P. R. China

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Dr. Ben Ma,

Dr. Ben Ma

Department of Chemistry, The University of Hong Kong, Pokfulam Road, Hong Kong, P. R. China

State Key Laboratory of Synthetic Chemistry, The University of Hong Kong, Pokfulam Road, Hong Kong, P. R. China

These authors contributed equally to this work.

Search for more papers by this author

Qi Xia,

Qi Xia

Department of Chemistry, The University of Hong Kong, Pokfulam Road, Hong Kong, P. R. China

These authors contributed equally to this work.

Search for more papers by this author

Deyang Wang,

Deyang Wang

Department of Chemistry, The University of Hong Kong, Pokfulam Road, Hong Kong, P. R. China

These authors contributed equally to this work.

Search for more papers by this author

Dr. Ji-Kang Jin,

Dr. Ji-Kang Jin

Department of Chemistry, The University of Hong Kong, Pokfulam Road, Hong Kong, P. R. China

College of Chemistry and Materials Science, Guangdong Provincial Key Laboratory of Functional Supramolecular Coordination Materials and Applications, Jinan University, Guangzhou, 510632 P. R. China

These authors contributed equally to this work.

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Zekun Li,

Zekun Li

Department of Chemistry, The University of Hong Kong, Pokfulam Road, Hong Kong, P. R. China

Search for more papers by this author

Qiu-Jiang Liang,

Qiu-Jiang Liang

Department of Chemistry, The University of Hong Kong, Pokfulam Road, Hong Kong, P. R. China

Search for more papers by this author

Meng-Ying Sun,

Meng-Ying Sun

Department of Chemistry, The University of Hong Kong, Pokfulam Road, Hong Kong, P. R. China

Search for more papers by this author

Dongyi Liu,

Dongyi Liu

Department of Chemistry, The University of Hong Kong, Pokfulam Road, Hong Kong, P. R. China

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Li-Juan Liu,

Li-Juan Liu

Department of Chemistry, The University of Hong Kong, Pokfulam Road, Hong Kong, P. R. China

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Dr. Hui-Xing Shu,

Dr. Hui-Xing Shu

Department of Chemistry, The University of Hong Kong, Pokfulam Road, Hong Kong, P. R. China

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Prof. Dr. Jun Yang,

Prof. Dr. Jun Yang

Department of Chemistry, The University of Hong Kong, Pokfulam Road, Hong Kong, P. R. China

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Prof. Dr. Dan Li,

Corresponding Author

Prof. Dr. Dan Li

[email protected]

College of Chemistry and Materials Science, Guangdong Provincial Key Laboratory of Functional Supramolecular Coordination Materials and Applications, Jinan University, Guangzhou, 510632 P. R. China

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Prof. Dr. Jian He,

Corresponding Author

Prof. Dr. Jian He

[email protected]

orcid.org/0000-0002-3388-3239

Department of Chemistry, The University of Hong Kong, Pokfulam Road, Hong Kong, P. R. China

State Key Laboratory of Synthetic Chemistry, The University of Hong Kong, Pokfulam Road, Hong Kong, P. R. China

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First published: 04 May 2023

https://doi.org/10.1002/ange.202304253

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Graphical Abstract

A binap-ligated copper iodide dimer embedded on a metal−-organic framework (MOF) was designed as an effective photoredox catalyst by Dan Li, Jian He, and co-workers in their Research Article (e202300233). Under visible-light irradiation, this heterogenized copper(I) complex promotes multiple iminyl radical-mediated reactions initiated by N−O bond cleavage, with significantly enhanced photocatalytic activity compared to its homogeneous counterparts. The use of a hydroxamic acid linker for post-synthetic modification renders the catalyst recyclable.