Molecular Dipole Engineering of Carbonyl Additives for Efficient and Stable Perovskite Solar Cells
Corresponding Author
Xiaoqing Jiang
College of Chemical Engineering, Qingdao University of Science and Technology, Qingdao, 266042 China
These authors contributed equally to this work.
Search for more papers by this authorBingqian Zhang
Qingdao Institute of Bioenergy and Bioprocess Technology, Chinese Academy of Sciences, Qingdao, 266101 China
College of Materials Science and Engineering, Qingdao University of Science and Technology, Qingdao, 266042 China
These authors contributed equally to this work.
Search for more papers by this authorGuangyue Yang
College of Chemical Engineering, Qingdao University of Science and Technology, Qingdao, 266042 China
These authors contributed equally to this work.
Search for more papers by this authorCorresponding Author
Zhongmin Zhou
College of Chemistry and Molecular Engineering, Qingdao University of Science and Technology, Qingdao, 266042 China
Search for more papers by this authorXin Guo
State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian National Laboratory for Clean Energy, Dalian, 116023 China
Search for more papers by this authorFengshan Zhang
Shan Dong Hua Tai Paper Industry Shareholding Co., Ltd., Dongying, 257335 China
Search for more papers by this authorShitao Yu
College of Chemical Engineering, Qingdao University of Science and Technology, Qingdao, 266042 China
Search for more papers by this authorCorresponding Author
Shiwei Liu
College of Chemical Engineering, Qingdao University of Science and Technology, Qingdao, 266042 China
Search for more papers by this authorCorresponding Author
Shuping Pang
Qingdao Institute of Bioenergy and Bioprocess Technology, Chinese Academy of Sciences, Qingdao, 266101 China
Search for more papers by this authorCorresponding Author
Xiaoqing Jiang
College of Chemical Engineering, Qingdao University of Science and Technology, Qingdao, 266042 China
These authors contributed equally to this work.
Search for more papers by this authorBingqian Zhang
Qingdao Institute of Bioenergy and Bioprocess Technology, Chinese Academy of Sciences, Qingdao, 266101 China
College of Materials Science and Engineering, Qingdao University of Science and Technology, Qingdao, 266042 China
These authors contributed equally to this work.
Search for more papers by this authorGuangyue Yang
College of Chemical Engineering, Qingdao University of Science and Technology, Qingdao, 266042 China
These authors contributed equally to this work.
Search for more papers by this authorCorresponding Author
Zhongmin Zhou
College of Chemistry and Molecular Engineering, Qingdao University of Science and Technology, Qingdao, 266042 China
Search for more papers by this authorXin Guo
State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian National Laboratory for Clean Energy, Dalian, 116023 China
Search for more papers by this authorFengshan Zhang
Shan Dong Hua Tai Paper Industry Shareholding Co., Ltd., Dongying, 257335 China
Search for more papers by this authorShitao Yu
College of Chemical Engineering, Qingdao University of Science and Technology, Qingdao, 266042 China
Search for more papers by this authorCorresponding Author
Shiwei Liu
College of Chemical Engineering, Qingdao University of Science and Technology, Qingdao, 266042 China
Search for more papers by this authorCorresponding Author
Shuping Pang
Qingdao Institute of Bioenergy and Bioprocess Technology, Chinese Academy of Sciences, Qingdao, 266101 China
Search for more papers by this authorAbstract
Carbonyl functional materials as additives are extensively applied to reduce the defects density of the perovskite film. However, there is still a lack of comprehensive understanding for the effect of carbonyl additives to improve device performance. In this work, we systematically study the effect of carbonyl additive molecules on the passivation of defects in perovskite films. After a comprehensive investigation, the results confirm the importance of molecular dipole in amplifying the passivation effect of additive molecules. The additive with strong molecular dipole possesses the advantages of enhancing the efficiency and stability of perovskite solar cells (PSCs). After optimization, the companion efficiency of PSCs is 23.20 %, and it can maintain long-term stability under harsh conditions. Additionally, a large-area solar cell module-modified DLBA was 20.18 % (14 cm2). This work provides an important reference for the selection and designing of efficient carbonyl additives.
Conflict of interest
The authors declare no conflict of interest.
Open Research
Data Availability Statement
The data that support the findings of this study are available from the corresponding author upon reasonable request.
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