A Topology-Defined Polyester Elastomer from CO2 and 1,3-Butadiene: A One-Pot-One-Step “Scrambling Polymerizations” Strategy
Kaihao Chen
MOE Key Laboratory of Macromolecular Synthesis and Functionalization, Department of Polymer Science and Engineering, Zhejiang University, Hangzhou, 310027 China
These authors contributed equally to this work.
Search for more papers by this authorZhiqi Zhu
MOE Key Laboratory of Macromolecular Synthesis and Functionalization, Department of Polymer Science and Engineering, Zhejiang University, Hangzhou, 310027 China
These authors contributed equally to this work.
Search for more papers by this authorDr. Tianwen Bai
College of Biological, Chemical Sciences and Engineering, Jiaxing University, Jiaxing, 314001 China
Search for more papers by this authorYixuan Mei
MOE Key Laboratory of Macromolecular Synthesis and Functionalization, Department of Polymer Science and Engineering, Zhejiang University, Hangzhou, 310027 China
Search for more papers by this authorTianlun Shen
MOE Key Laboratory of Macromolecular Synthesis and Functionalization, Department of Polymer Science and Engineering, Zhejiang University, Hangzhou, 310027 China
Search for more papers by this authorProf. Jun Ling
MOE Key Laboratory of Macromolecular Synthesis and Functionalization, Department of Polymer Science and Engineering, Zhejiang University, Hangzhou, 310027 China
Search for more papers by this authorCorresponding Author
Prof. Xufeng Ni
MOE Key Laboratory of Macromolecular Synthesis and Functionalization, Department of Polymer Science and Engineering, Zhejiang University, Hangzhou, 310027 China
Search for more papers by this authorKaihao Chen
MOE Key Laboratory of Macromolecular Synthesis and Functionalization, Department of Polymer Science and Engineering, Zhejiang University, Hangzhou, 310027 China
These authors contributed equally to this work.
Search for more papers by this authorZhiqi Zhu
MOE Key Laboratory of Macromolecular Synthesis and Functionalization, Department of Polymer Science and Engineering, Zhejiang University, Hangzhou, 310027 China
These authors contributed equally to this work.
Search for more papers by this authorDr. Tianwen Bai
College of Biological, Chemical Sciences and Engineering, Jiaxing University, Jiaxing, 314001 China
Search for more papers by this authorYixuan Mei
MOE Key Laboratory of Macromolecular Synthesis and Functionalization, Department of Polymer Science and Engineering, Zhejiang University, Hangzhou, 310027 China
Search for more papers by this authorTianlun Shen
MOE Key Laboratory of Macromolecular Synthesis and Functionalization, Department of Polymer Science and Engineering, Zhejiang University, Hangzhou, 310027 China
Search for more papers by this authorProf. Jun Ling
MOE Key Laboratory of Macromolecular Synthesis and Functionalization, Department of Polymer Science and Engineering, Zhejiang University, Hangzhou, 310027 China
Search for more papers by this authorCorresponding Author
Prof. Xufeng Ni
MOE Key Laboratory of Macromolecular Synthesis and Functionalization, Department of Polymer Science and Engineering, Zhejiang University, Hangzhou, 310027 China
Search for more papers by this authorAbstract
It is significant and challenging to use CO2 to produce polymeric materials, especially with olefins. Here, a novel strategy named “scrambling polymerizations” is designed and performed for the copolymerization of a CO2-and-1,3-butadiene-derived valerolactone, 3-ethylidene-6-vinyltetrahydro-2H-pyran-2-one (EVL), with ϵ-caprolactone (CL) to prepare polyesters. Anionic ring-opening polymerization of CL and conjugated addition oligomerization of EVL take place individually to form PCL and EVL oligomers, respectively. Then EVL oligomers insert into PCL by transesterification resulting in polyester P(CL-co-EVL) with a tunable topology and composition. The non-cytotoxic and degradable polyester network with elongation at break of >600 % can be used as an elastomer. We propose a method to provide polyester elastomers from CO2 and olefins for the first time, and expand the potential of transformation from sustainable feedstocks to polymeric materials.
Open Research
Data Availability Statement
The data that support the findings of this study are available in the supplementary material of this article.
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