Room-Temperature Ring-Opening Polymerization of δ-Valerolactone and ϵ-Caprolactone Caused by Uptake into Porous Pillar[5]arene Crystals
Dr. Kenichi Kato
Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, Nishikyo-ku, Kyoto, 615-8510 Japan
Search for more papers by this authorKoki Maeda
Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, Nishikyo-ku, Kyoto, 615-8510 Japan
Search for more papers by this authorProf. Dr. Motohiro Mizuno
Graduate School of Natural Science and Technology, Kanazawa University
NanoMaterials Research Institute (NanoMaRi), Kanazawa University, Kakuma-machi, Kanazawa, 920-1192 Japan
Search for more papers by this authorProf. Dr. Yuta Nishina
Research Core for Interdisciplinary Sciences, Okayama University, Okayama, 700-8530 Japan
Search for more papers by this authorDr. Shixin Fa
Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, Nishikyo-ku, Kyoto, 615-8510 Japan
Search for more papers by this authorDr. Shunsuke Ohtani
Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, Nishikyo-ku, Kyoto, 615-8510 Japan
Search for more papers by this authorCorresponding Author
Prof. Dr. Tomoki Ogoshi
Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, Nishikyo-ku, Kyoto, 615-8510 Japan
WPI Nano Life Science Institute, Kanazawa University, Kakuma-machi, Kanazawa, 920-1192 Japan
Search for more papers by this authorDr. Kenichi Kato
Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, Nishikyo-ku, Kyoto, 615-8510 Japan
Search for more papers by this authorKoki Maeda
Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, Nishikyo-ku, Kyoto, 615-8510 Japan
Search for more papers by this authorProf. Dr. Motohiro Mizuno
Graduate School of Natural Science and Technology, Kanazawa University
NanoMaterials Research Institute (NanoMaRi), Kanazawa University, Kakuma-machi, Kanazawa, 920-1192 Japan
Search for more papers by this authorProf. Dr. Yuta Nishina
Research Core for Interdisciplinary Sciences, Okayama University, Okayama, 700-8530 Japan
Search for more papers by this authorDr. Shixin Fa
Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, Nishikyo-ku, Kyoto, 615-8510 Japan
Search for more papers by this authorDr. Shunsuke Ohtani
Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, Nishikyo-ku, Kyoto, 615-8510 Japan
Search for more papers by this authorCorresponding Author
Prof. Dr. Tomoki Ogoshi
Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, Nishikyo-ku, Kyoto, 615-8510 Japan
WPI Nano Life Science Institute, Kanazawa University, Kakuma-machi, Kanazawa, 920-1192 Japan
Search for more papers by this authorAbstract
Confined space provides a reaction platform with altered reaction rate and selectivity compared with a homogeneous solution. In this work, porous phenolic pillar[5]arene crystals were used as a reaction space to promote and perturb equilibrium between lactones and their corresponding polyesters. Immersion of porous pillar[5]arene crystals in liquid lactones induced ring-opening polymerization of δ-valerolactone and ϵ-caprolactone at room temperature because the phenolic hydroxy groups have catalytic activity via hydrogen bonds and the pillar[5]arene cavities prefer linear guests. After the reaction, pillar[5]arene and polyesters formed pseudo-polyrotaxanes.
Conflict of interest
The authors declare no conflict of interest.
Open Research
Data Availability Statement
The data that support the findings of this study are available in the Supporting Information of this article.
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