A Bifunctional CdS/MoO2/MoS2 Catalyst Enhances Photocatalytic H2 Evolution and Pyruvic Acid Synthesis
Dr. Chuanbiao Bie
Laboratory of Solar Fuel, Faculty of Materials Science and Chemistry, China University of Geosciences, 430074 Wuhan, P. R. China
State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology, 430070 Wuhan, P. R. China
Search for more papers by this authorDr. Bicheng Zhu
Laboratory of Solar Fuel, Faculty of Materials Science and Chemistry, China University of Geosciences, 430074 Wuhan, P. R. China
Search for more papers by this authorCorresponding Author
Dr. Linxi Wang
Laboratory of Solar Fuel, Faculty of Materials Science and Chemistry, China University of Geosciences, 430074 Wuhan, P. R. China
Search for more papers by this authorCorresponding Author
Prof. Huogen Yu
Laboratory of Solar Fuel, Faculty of Materials Science and Chemistry, China University of Geosciences, 430074 Wuhan, P. R. China
Search for more papers by this authorDr. Chenhui Jiang
Hefei National Laboratory for Physical Sciences at Microscale, CAS Key Laboratory of Materials for Energy Conversion, Department of Materials Science and Engineering, University of Science and Technology of China, 230026 Hefei, P. R. China
Search for more papers by this authorProf. Tao Chen
Hefei National Laboratory for Physical Sciences at Microscale, CAS Key Laboratory of Materials for Energy Conversion, Department of Materials Science and Engineering, University of Science and Technology of China, 230026 Hefei, P. R. China
Search for more papers by this authorCorresponding Author
Prof. Jiaguo Yu
Laboratory of Solar Fuel, Faculty of Materials Science and Chemistry, China University of Geosciences, 430074 Wuhan, P. R. China
State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology, 430070 Wuhan, P. R. China
Search for more papers by this authorDr. Chuanbiao Bie
Laboratory of Solar Fuel, Faculty of Materials Science and Chemistry, China University of Geosciences, 430074 Wuhan, P. R. China
State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology, 430070 Wuhan, P. R. China
Search for more papers by this authorDr. Bicheng Zhu
Laboratory of Solar Fuel, Faculty of Materials Science and Chemistry, China University of Geosciences, 430074 Wuhan, P. R. China
Search for more papers by this authorCorresponding Author
Dr. Linxi Wang
Laboratory of Solar Fuel, Faculty of Materials Science and Chemistry, China University of Geosciences, 430074 Wuhan, P. R. China
Search for more papers by this authorCorresponding Author
Prof. Huogen Yu
Laboratory of Solar Fuel, Faculty of Materials Science and Chemistry, China University of Geosciences, 430074 Wuhan, P. R. China
Search for more papers by this authorDr. Chenhui Jiang
Hefei National Laboratory for Physical Sciences at Microscale, CAS Key Laboratory of Materials for Energy Conversion, Department of Materials Science and Engineering, University of Science and Technology of China, 230026 Hefei, P. R. China
Search for more papers by this authorProf. Tao Chen
Hefei National Laboratory for Physical Sciences at Microscale, CAS Key Laboratory of Materials for Energy Conversion, Department of Materials Science and Engineering, University of Science and Technology of China, 230026 Hefei, P. R. China
Search for more papers by this authorCorresponding Author
Prof. Jiaguo Yu
Laboratory of Solar Fuel, Faculty of Materials Science and Chemistry, China University of Geosciences, 430074 Wuhan, P. R. China
State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology, 430070 Wuhan, P. R. China
Search for more papers by this authorAbstract
The best use of photogenerated electrons and holes is crucial to boosting photocatalytic activity. Herein, a bifunctional dual-cocatalyst-modified photocatalyst is constructed based on CdS/MoO2/MoS2 hollow spheres for hydrogen evolution coupled with selective pyruvic acid (PA) production from lactic acid (LA) oxidation. MoS2 and MoO2 are simultaneously obtained from the conversion of CdMoO4 in one step. In a photocatalytic process, the MoS2 and MoO2 function as the reduction and oxidation centers on which photogenerated electrons and holes accumulate and are used for hydrogen evolution reaction (HER) and PA synthesis, respectively. By monitoring the intermediates, a two-step single-electron route for PA production is proposed, initiated by the cleavage of the α-C(sp3)−H bond in the LA. The conversion of LA and the selectivity of PA can reach ca. 29 % and 95 % after a five-hour reaction, respectively.
Conflict of interest
The authors declare no conflict of interest.
Open Research
Data Availability Statement
The data that support the findings of this study are available from the corresponding author upon reasonable request.
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