Anion-Guided Stepwise Assembly of High-Nuclearity Lanthanide Hydroxide Clusters
Weiming Huang
Department of Chemistry, Southern University of Science and Technology, Shenzhen, 518055 China
Search for more papers by this authorDr. Wanmin Chen
Department of Chemistry, Southern University of Science and Technology, Shenzhen, 518055 China
Search for more papers by this authorQixia Bai
College of Environmental Science and Engineering, Guangzhou University, Guangzhou, 510006 China
Search for more papers by this authorDr. Zhe Zhang
College of Environmental Science and Engineering, Guangzhou University, Guangzhou, 510006 China
Search for more papers by this authorCorresponding Author
Dr. Min Feng
Department of Chemistry, Southern University of Science and Technology, Shenzhen, 518055 China
Search for more papers by this authorCorresponding Author
Prof. Zhiping Zheng
Department of Chemistry, Southern University of Science and Technology, Shenzhen, 518055 China
Search for more papers by this authorWeiming Huang
Department of Chemistry, Southern University of Science and Technology, Shenzhen, 518055 China
Search for more papers by this authorDr. Wanmin Chen
Department of Chemistry, Southern University of Science and Technology, Shenzhen, 518055 China
Search for more papers by this authorQixia Bai
College of Environmental Science and Engineering, Guangzhou University, Guangzhou, 510006 China
Search for more papers by this authorDr. Zhe Zhang
College of Environmental Science and Engineering, Guangzhou University, Guangzhou, 510006 China
Search for more papers by this authorCorresponding Author
Dr. Min Feng
Department of Chemistry, Southern University of Science and Technology, Shenzhen, 518055 China
Search for more papers by this authorCorresponding Author
Prof. Zhiping Zheng
Department of Chemistry, Southern University of Science and Technology, Shenzhen, 518055 China
Search for more papers by this authorAbstract
The ability to construct complex molecular architectures with precise control is critical for realizing molecule-based materials and functions. Using the assembly of a 60-metal complex of ErIII with histidine as an example, we demonstrate the rational assembly of otherwise synthetically elusive polynuclear lanthanide hydroxide clusters directed by the combined set of I− and CO32− as templates. We succeeded in the stepwise transformation starting from Er12 to Er60 by way of two key intermediates Er34 and Er48. The Er12, Er34, and Er48 core motifs represent respectively 1/6, 1/2, and 3/4 of the complete sodalite cage of Er60. This work, representing a rare example of rationally constructing high-nuclearity lanthanide clusters guided by judiciously chosen templates, is expected to stimulate more future efforts for the controllable synthesis of complex molecular or supramolecular architectures with unprecedented structural sophistication and possibly useful properties.
Conflict of interest
The authors declare no conflict of interest.
Open Research
Data Availability Statement
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