Atomic-Layered Cu5 Nanoclusters on FeS2 with Dual Catalytic Sites for Efficient and Selective H2O2 Activation
Cancan Ling
Key Laboratory of Pesticide & Chemical Biology of Ministry of Education, Institute of Applied & Environmental Chemistry, College of Chemistry, Central China Normal University, Wuhan, 430079 P. R. China
These authors contributed equally to this work.
Search for more papers by this authorXiufan Liu
Key Laboratory of Pesticide & Chemical Biology of Ministry of Education, Institute of Applied & Environmental Chemistry, College of Chemistry, Central China Normal University, Wuhan, 430079 P. R. China
These authors contributed equally to this work.
Search for more papers by this authorCorresponding Author
Dr. Hao Li
School of Environmental Science and Engineering, Shanghai Jiao Tong University, Shanghai, 200240 P. R. China
Search for more papers by this authorDr. Xiaobing Wang
Key Laboratory of Pesticide & Chemical Biology of Ministry of Education, Institute of Applied & Environmental Chemistry, College of Chemistry, Central China Normal University, Wuhan, 430079 P. R. China
Search for more papers by this authorHuayu Gu
Key Laboratory of Pesticide & Chemical Biology of Ministry of Education, Institute of Applied & Environmental Chemistry, College of Chemistry, Central China Normal University, Wuhan, 430079 P. R. China
Search for more papers by this authorKai Wei
Key Laboratory of Pesticide & Chemical Biology of Ministry of Education, Institute of Applied & Environmental Chemistry, College of Chemistry, Central China Normal University, Wuhan, 430079 P. R. China
Search for more papers by this authorMeiqi Li
Key Laboratory of Pesticide & Chemical Biology of Ministry of Education, Institute of Applied & Environmental Chemistry, College of Chemistry, Central China Normal University, Wuhan, 430079 P. R. China
Search for more papers by this authorDr. Yanbiao Shi
Key Laboratory of Pesticide & Chemical Biology of Ministry of Education, Institute of Applied & Environmental Chemistry, College of Chemistry, Central China Normal University, Wuhan, 430079 P. R. China
School of Environmental Science and Engineering, Shanghai Jiao Tong University, Shanghai, 200240 P. R. China
Search for more papers by this authorDr. Haijie Ben
Key Laboratory of Pesticide & Chemical Biology of Ministry of Education, Institute of Applied & Environmental Chemistry, College of Chemistry, Central China Normal University, Wuhan, 430079 P. R. China
Search for more papers by this authorGuangming Zhan
Key Laboratory of Pesticide & Chemical Biology of Ministry of Education, Institute of Applied & Environmental Chemistry, College of Chemistry, Central China Normal University, Wuhan, 430079 P. R. China
Search for more papers by this authorChuan Liang
Key Laboratory of Pesticide & Chemical Biology of Ministry of Education, Institute of Applied & Environmental Chemistry, College of Chemistry, Central China Normal University, Wuhan, 430079 P. R. China
Search for more papers by this authorDr. Wenjuan Shen
Key Laboratory of Pesticide & Chemical Biology of Ministry of Education, Institute of Applied & Environmental Chemistry, College of Chemistry, Central China Normal University, Wuhan, 430079 P. R. China
Search for more papers by this authorYaling Li
Key Laboratory of Pesticide & Chemical Biology of Ministry of Education, Institute of Applied & Environmental Chemistry, College of Chemistry, Central China Normal University, Wuhan, 430079 P. R. China
Search for more papers by this authorProf. Jincai Zhao
Key Laboratory of Pesticide & Chemical Biology of Ministry of Education, Institute of Applied & Environmental Chemistry, College of Chemistry, Central China Normal University, Wuhan, 430079 P. R. China
Search for more papers by this authorCorresponding Author
Prof. Lizhi Zhang
Key Laboratory of Pesticide & Chemical Biology of Ministry of Education, Institute of Applied & Environmental Chemistry, College of Chemistry, Central China Normal University, Wuhan, 430079 P. R. China
School of Environmental Science and Engineering, Shanghai Jiao Tong University, Shanghai, 200240 P. R. China
Search for more papers by this authorCancan Ling
Key Laboratory of Pesticide & Chemical Biology of Ministry of Education, Institute of Applied & Environmental Chemistry, College of Chemistry, Central China Normal University, Wuhan, 430079 P. R. China
These authors contributed equally to this work.
Search for more papers by this authorXiufan Liu
Key Laboratory of Pesticide & Chemical Biology of Ministry of Education, Institute of Applied & Environmental Chemistry, College of Chemistry, Central China Normal University, Wuhan, 430079 P. R. China
These authors contributed equally to this work.
Search for more papers by this authorCorresponding Author
Dr. Hao Li
School of Environmental Science and Engineering, Shanghai Jiao Tong University, Shanghai, 200240 P. R. China
Search for more papers by this authorDr. Xiaobing Wang
Key Laboratory of Pesticide & Chemical Biology of Ministry of Education, Institute of Applied & Environmental Chemistry, College of Chemistry, Central China Normal University, Wuhan, 430079 P. R. China
Search for more papers by this authorHuayu Gu
Key Laboratory of Pesticide & Chemical Biology of Ministry of Education, Institute of Applied & Environmental Chemistry, College of Chemistry, Central China Normal University, Wuhan, 430079 P. R. China
Search for more papers by this authorKai Wei
Key Laboratory of Pesticide & Chemical Biology of Ministry of Education, Institute of Applied & Environmental Chemistry, College of Chemistry, Central China Normal University, Wuhan, 430079 P. R. China
Search for more papers by this authorMeiqi Li
Key Laboratory of Pesticide & Chemical Biology of Ministry of Education, Institute of Applied & Environmental Chemistry, College of Chemistry, Central China Normal University, Wuhan, 430079 P. R. China
Search for more papers by this authorDr. Yanbiao Shi
Key Laboratory of Pesticide & Chemical Biology of Ministry of Education, Institute of Applied & Environmental Chemistry, College of Chemistry, Central China Normal University, Wuhan, 430079 P. R. China
School of Environmental Science and Engineering, Shanghai Jiao Tong University, Shanghai, 200240 P. R. China
Search for more papers by this authorDr. Haijie Ben
Key Laboratory of Pesticide & Chemical Biology of Ministry of Education, Institute of Applied & Environmental Chemistry, College of Chemistry, Central China Normal University, Wuhan, 430079 P. R. China
Search for more papers by this authorGuangming Zhan
Key Laboratory of Pesticide & Chemical Biology of Ministry of Education, Institute of Applied & Environmental Chemistry, College of Chemistry, Central China Normal University, Wuhan, 430079 P. R. China
Search for more papers by this authorChuan Liang
Key Laboratory of Pesticide & Chemical Biology of Ministry of Education, Institute of Applied & Environmental Chemistry, College of Chemistry, Central China Normal University, Wuhan, 430079 P. R. China
Search for more papers by this authorDr. Wenjuan Shen
Key Laboratory of Pesticide & Chemical Biology of Ministry of Education, Institute of Applied & Environmental Chemistry, College of Chemistry, Central China Normal University, Wuhan, 430079 P. R. China
Search for more papers by this authorYaling Li
Key Laboratory of Pesticide & Chemical Biology of Ministry of Education, Institute of Applied & Environmental Chemistry, College of Chemistry, Central China Normal University, Wuhan, 430079 P. R. China
Search for more papers by this authorProf. Jincai Zhao
Key Laboratory of Pesticide & Chemical Biology of Ministry of Education, Institute of Applied & Environmental Chemistry, College of Chemistry, Central China Normal University, Wuhan, 430079 P. R. China
Search for more papers by this authorCorresponding Author
Prof. Lizhi Zhang
Key Laboratory of Pesticide & Chemical Biology of Ministry of Education, Institute of Applied & Environmental Chemistry, College of Chemistry, Central China Normal University, Wuhan, 430079 P. R. China
School of Environmental Science and Engineering, Shanghai Jiao Tong University, Shanghai, 200240 P. R. China
Search for more papers by this authorAbstract
Regulating the distribution of reactive oxygen species generated from H2O2 activation is the prerequisite to ensuring the efficient and safe use of H2O2 in the chemistry and life science fields. Herein, we demonstrate that constructing a dual Cu−Fe site through the self-assembly of single-atomic-layered Cu5 nanoclusters onto a FeS2 surface achieves selective H2O2 activation with high efficiency. Unlike its unitary Cu or Fe counterpart, the dual Cu−Fe sites residing at the perimeter zone of the Cu5/FeS2 interface facilitate H2O2 adsorption and barrierless decomposition into ⋅OH via forming a bridging Cu-O-O-Fe complex. The robust in situ formation of ⋅OH governed by this atomic-layered catalyst enables the effective oxidation of several refractory toxic pollutants across a broad pH range, including alachlor, sulfadimidine, p-nitrobenzoic acid, p-chlorophenol, p-chloronitrobenzene. This work highlights the concept of building a dual catalytic site in manipulating selective H2O2 activation on the surface molecular level towards efficient environmental control and beyond.
Conflict of interest
The authors declare no conflict of interest.
Open Research
Data Availability Statement
The data that support the findings of this study are available from the corresponding author upon reasonable request.
Supporting Information
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| Filename | Description |
|---|---|
| ange202200670-sup-0001-Cu5-FeS2(001)_structure.cif12.1 KB | Supporting Information |
| ange202200670-sup-0001-Cu5_cluster.cif1.4 KB | Supporting Information |
| ange202200670-sup-0001-FeS2(001)_surface.cif11.4 KB | Supporting Information |
| ange202200670-sup-0001-FeS2_unit_cell.cif1.7 KB | Supporting Information |
| ange202200670-sup-0001-misc_information.pdf3.6 MB | Supporting Information |
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