Inorganic–Organic Hybrid Membrane Based on Pillararene-Intercalated MXene Nanosheets for Efficient Water Purification
Corresponding Author
Prof. Dr. Yue Sun
State Key Laboratory of Separation Membrane and Membrane Process, School of Chemistry, Tiangong University, 300387 Tianjin, China
Hubei Key Laboratory of Catalysis and Materials Science, College of Chemistry and Material Sciences, South-Central University for Nationalities, 430074 Wuhan, China
Search for more papers by this authorFan Yi
Hubei Key Laboratory of Catalysis and Materials Science, College of Chemistry and Material Sciences, South-Central University for Nationalities, 430074 Wuhan, China
Search for more papers by this authorRun-Hao Li
Hubei Key Laboratory of Catalysis and Materials Science, College of Chemistry and Material Sciences, South-Central University for Nationalities, 430074 Wuhan, China
Search for more papers by this authorXuehong Min
Hubei Key Laboratory of Catalysis and Materials Science, College of Chemistry and Material Sciences, South-Central University for Nationalities, 430074 Wuhan, China
Search for more papers by this authorHuan Qin
Hubei Key Laboratory of Catalysis and Materials Science, College of Chemistry and Material Sciences, South-Central University for Nationalities, 430074 Wuhan, China
Search for more papers by this authorShi-Qi Cheng
Hubei Key Laboratory of Catalysis and Materials Science, College of Chemistry and Material Sciences, South-Central University for Nationalities, 430074 Wuhan, China
Search for more papers by this authorCorresponding Author
Prof. Dr. Yi Liu
State Key Laboratory of Separation Membrane and Membrane Process, School of Chemistry, Tiangong University, 300387 Tianjin, China
Search for more papers by this authorCorresponding Author
Prof. Dr. Yue Sun
State Key Laboratory of Separation Membrane and Membrane Process, School of Chemistry, Tiangong University, 300387 Tianjin, China
Hubei Key Laboratory of Catalysis and Materials Science, College of Chemistry and Material Sciences, South-Central University for Nationalities, 430074 Wuhan, China
Search for more papers by this authorFan Yi
Hubei Key Laboratory of Catalysis and Materials Science, College of Chemistry and Material Sciences, South-Central University for Nationalities, 430074 Wuhan, China
Search for more papers by this authorRun-Hao Li
Hubei Key Laboratory of Catalysis and Materials Science, College of Chemistry and Material Sciences, South-Central University for Nationalities, 430074 Wuhan, China
Search for more papers by this authorXuehong Min
Hubei Key Laboratory of Catalysis and Materials Science, College of Chemistry and Material Sciences, South-Central University for Nationalities, 430074 Wuhan, China
Search for more papers by this authorHuan Qin
Hubei Key Laboratory of Catalysis and Materials Science, College of Chemistry and Material Sciences, South-Central University for Nationalities, 430074 Wuhan, China
Search for more papers by this authorShi-Qi Cheng
Hubei Key Laboratory of Catalysis and Materials Science, College of Chemistry and Material Sciences, South-Central University for Nationalities, 430074 Wuhan, China
Search for more papers by this authorCorresponding Author
Prof. Dr. Yi Liu
State Key Laboratory of Separation Membrane and Membrane Process, School of Chemistry, Tiangong University, 300387 Tianjin, China
Search for more papers by this authorAbstract
Discharge of antibiotic-containing wastewater causes environmental pollution and threatens biological and human health. An efficient treatment method for this wastewater is urgently required. We prepared inorganic–organic hybrid MXene–pillararene nanosheets with a large lateral size (5–8 μm). The hybrid nanosheets were stacked on supports via vacuum-assisted filtration to prepare membranes with regular parallel slits and an interlayer spacing of 1.36 nm, which were used to purify antibiotic-containing water. Permeance through the membrane increased 100-fold compared with most polymeric and other two-dimensional nanofiltration membranes with similar rejection. This high permeance and rejection was attributed to the large lateral size of the nanosheets, regular interlayer spacing, and electrostatic interaction between the membrane and antibiotics. These membranes will broaden the applications of lamellar materials for the separation of high-value-added drugs in academia and industry.
Conflict of interest
The authors declare no conflict of interest.
Open Research
Data Availability Statement
The data that support the findings of this study are available from the corresponding author upon reasonable request.
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