Modification of Multi-Component Building Blocks for Assembling Giant Chiral Lanthanide-Titanium Molecular Rings
Ming-Hao Du
Collaborative Innovation Center of Chemistry for Energy Materials, State Key Laboratory of Physical Chemistry of Solid Surface and Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen, 361005 China
These authors contributed equally to this work.
Search for more papers by this authorSu-Hui Xu
Collaborative Innovation Center of Chemistry for Energy Materials, State Key Laboratory of Physical Chemistry of Solid Surface and Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen, 361005 China
These authors contributed equally to this work.
Search for more papers by this authorGuan-Jun Li
Collaborative Innovation Center of Chemistry for Energy Materials, State Key Laboratory of Physical Chemistry of Solid Surface and Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen, 361005 China
Search for more papers by this authorHan Xu
Collaborative Innovation Center of Chemistry for Energy Materials, State Key Laboratory of Physical Chemistry of Solid Surface and Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen, 361005 China
Search for more papers by this authorYang Lin
Collaborative Innovation Center of Chemistry for Energy Materials, State Key Laboratory of Physical Chemistry of Solid Surface and Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen, 361005 China
Search for more papers by this authorWei-Dong Liu
Collaborative Innovation Center of Chemistry for Energy Materials, State Key Laboratory of Physical Chemistry of Solid Surface and Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen, 361005 China
Search for more papers by this authorProf. Dr. La-Sheng Long
Collaborative Innovation Center of Chemistry for Energy Materials, State Key Laboratory of Physical Chemistry of Solid Surface and Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen, 361005 China
Search for more papers by this authorProf. Dr. Lan-Sun Zheng
Collaborative Innovation Center of Chemistry for Energy Materials, State Key Laboratory of Physical Chemistry of Solid Surface and Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen, 361005 China
Search for more papers by this authorCorresponding Author
Prof. Dr. Xiang-Jian Kong
Collaborative Innovation Center of Chemistry for Energy Materials, State Key Laboratory of Physical Chemistry of Solid Surface and Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen, 361005 China
Search for more papers by this authorMing-Hao Du
Collaborative Innovation Center of Chemistry for Energy Materials, State Key Laboratory of Physical Chemistry of Solid Surface and Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen, 361005 China
These authors contributed equally to this work.
Search for more papers by this authorSu-Hui Xu
Collaborative Innovation Center of Chemistry for Energy Materials, State Key Laboratory of Physical Chemistry of Solid Surface and Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen, 361005 China
These authors contributed equally to this work.
Search for more papers by this authorGuan-Jun Li
Collaborative Innovation Center of Chemistry for Energy Materials, State Key Laboratory of Physical Chemistry of Solid Surface and Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen, 361005 China
Search for more papers by this authorHan Xu
Collaborative Innovation Center of Chemistry for Energy Materials, State Key Laboratory of Physical Chemistry of Solid Surface and Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen, 361005 China
Search for more papers by this authorYang Lin
Collaborative Innovation Center of Chemistry for Energy Materials, State Key Laboratory of Physical Chemistry of Solid Surface and Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen, 361005 China
Search for more papers by this authorWei-Dong Liu
Collaborative Innovation Center of Chemistry for Energy Materials, State Key Laboratory of Physical Chemistry of Solid Surface and Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen, 361005 China
Search for more papers by this authorProf. Dr. La-Sheng Long
Collaborative Innovation Center of Chemistry for Energy Materials, State Key Laboratory of Physical Chemistry of Solid Surface and Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen, 361005 China
Search for more papers by this authorProf. Dr. Lan-Sun Zheng
Collaborative Innovation Center of Chemistry for Energy Materials, State Key Laboratory of Physical Chemistry of Solid Surface and Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen, 361005 China
Search for more papers by this authorCorresponding Author
Prof. Dr. Xiang-Jian Kong
Collaborative Innovation Center of Chemistry for Energy Materials, State Key Laboratory of Physical Chemistry of Solid Surface and Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen, 361005 China
Search for more papers by this authorDedicated to the 100th anniversary of Xiamen University
Abstract
Building blocks with multiple components are promising for the synthesis of complex molecular assemblies, but are rarely available. Herein, we report a modification procedure for a multi-component building block [Ln3Ti(HSA)6(SA)4(H2O)]− ({Ln3Ti-SA}, H2SA=salicylic acid, Ln=Eu/Gd) to form new building blocks {Ln3Tix-MSA} (H2MSA=5-methoxysalicylic acid, x=1, 2, 3) by constructing [Ti(MSA)3]2− units. The obtained {Ln3Tix-MSA} can further assemble into a chiral Ln22Ti14 ring with the formulae [Eu22Ti14(MSA)48(HMSA)22(CH3COO)4(H2O)10(iPrOH)] and [Gd22Ti14(MSA)46(HMSA)26(CH3COO)4(H2O)8]. Parallel experiments without Ti4+ result in linear Ln chains. Detailed analysis shows that the [Ti(MSA)4]4− unit makes the originally variable Ln chains become available building blocks and the modified [Ti(MSA)3]2− further triggers interesting chiral-sorting behavior. Finally, the electronic adsorption and magneto-optic responses of these molecular rings are investigated.
Conflict of interest
The authors declare no conflict of interest.
Open Research
Data Availability Statement
The data that support the findings of this study are available in the supplementary material of this article.
Supporting Information
As a service to our authors and readers, this journal provides supporting information supplied by the authors. Such materials are peer reviewed and may be re-organized for online delivery, but are not copy-edited or typeset. Technical support issues arising from supporting information (other than missing files) should be addressed to the authors.
| Filename | Description |
|---|---|
| ange202116296-sup-0001-Compound_1D-Eu.cif445.3 KB | Supporting Information |
| ange202116296-sup-0001-Eu22Ti14.cif17.1 MB | Supporting Information |
| ange202116296-sup-0001-Gd22Ti14.cif3.2 MB | Supporting Information |
| ange202116296-sup-0001-misc_information.pdf1.8 MB | Supporting Information |
Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.
References
- 1
- 1aW.-X. Gao, H.-J. Feng, B.-B. Guo, Y. Lu, G.-X. Jin, Chem. Rev. 2020, 120, 6288–6325;
- 1bS. M. Jansze, K. Severin, Acc. Chem. Res. 2018, 51, 2139–2147;
- 1cG. Kumar, R. Gupta, Chem. Soc. Rev. 2013, 42, 9403–9453;
- 1dQ.-D. Liu, X. Wang, Matter 2020, 2, 816–841;
- 1eZ.-J. Zhang, L. Wojtas, M. J. Zaworotko, Chem. Sci. 2014, 5, 927–931;
- 1fR.-W. Huang, X.-Y. Dong, B.-J. Yan, X.-S. Du, D.-H. Wei, S.-Q. Zang, T. C. W. Mak, Angew. Chem. Int. Ed. 2018, 57, 8560–8566; Angew. Chem. 2018, 130, 8696–8702;
- 1gN. P. Martin, M. Nyman, Angew. Chem. Int. Ed. 2021, 60, 954–960; Angew. Chem. 2021, 133, 967–973.
- 2
- 2aD. Zhang, T. K. Ronson, J. R. Nitschke, Acc. Chem. Res. 2018, 51, 2423–2436;
- 2bS. L. James, Chem. Soc. Rev. 2009, 38, 1744–1758;
- 2cJ. Zhang, X. Bu, P. Feng, T. Wu, Acc. Chem. Res. 2020, 53, 2261–2272;
- 2dK. Su, W. Wang, S. Du, C. Ji, M. Zhou, D. Yuan, J. Am. Chem. Soc. 2020, 142, 18060–18072;
- 2eZ.-Y. Wang, M.-Q. Wang, Y.-L. Li, P. Luo, T.-T. Jia, R.-W. Huang, S.-Q. Zang, T. C. W. Mak, J. Am. Chem. Soc. 2018, 140, 1069–1076;
- 2fW. Xuan, A. J. Surman, Q. Zheng, D.-L. Long, L. Cronin, Angew. Chem. Int. Ed. 2016, 55, 12703–12707; Angew. Chem. 2016, 128, 12895–12899;
- 2gL. Chen, M. J. Turo, M. Gembicky, R. A. Reinicke, A. M. Schimpf, Angew. Chem. Int. Ed. 2020, 59, 16609–16615; Angew. Chem. 2020, 132, 16752–16758.
- 3
- 3aM. Yoshizawa, L. Catti, Acc. Chem. Res. 2019, 52, 2392–2404;
- 3bN. Hosono, S. Kitagawa, Acc. Chem. Res. 2018, 51, 2437–2446;
- 3cT. R. Cook, V. Vajpayee, M. H. Lee, P. J. Stang, K.-W. Chi, Acc. Chem. Res. 2013, 46, 2464–2474;
- 3dB. H. Northrop, Y.-R. Zheng, K.-W. Chi, P. J. Stang, Acc. Chem. Res. 2009, 42, 1554–1563;
- 3eM. Han, D. M. Engelhard, G. H. Clever, Chem. Soc. Rev. 2014, 43, 1848–1860;
- 3fZ. Wang, H.-F. Su, Y.-Z. Tan, S. Schein, S.-C. Lin, W. Liu, S.-A. Wang, W.-G. Wang, C.-H. Tung, D. Sun, L.-S. Zheng, Proc. Natl. Acad. Sci. USA 2017, 114, 12132–12137.
- 4
- 4aD. Fujita, Y. Ueda, S. Sato, H. Yokoyama, N. Mizuno, T. Kumasaka, M. Fujita, Chem 2016, 1, 91–101;
- 4bH. Takezawa, T. Kanda, H. Nanjo, M. Fujita, J. Am. Chem. Soc. 2019, 141, 5112–5115.
- 5
- 5aD. Foguet-Albiol, K. A. Abboud, G. Christou, Chem. Commun. 2005, 4282–4284;
- 5bD. Shi, X. Yang, H. Chen, D. Jiang, J. Liu, Y. Ma, D. Schipper, R. A. Jones, Chem. Commun. 2019, 55, 13116–13119;
- 5cX.-Y. Zheng, Y.-H. Jiang, G.-L. Zhuang, D.-P. Liu, H.-G. Liao, X.-J. Kong, L.-S. Long, L.-S. Zheng, J. Am. Chem. Soc. 2017, 139, 18178–18181;
- 5dJ.-C. Liu, J.-F. Wang, Q. Han, P. Shangguan, L.-L. Liu, L.-J. Chen, J.-W. Zhao, C. Streb, Y.-F. Song, Angew. Chem. Int. Ed. 2021, 60, 11153–11157; Angew. Chem. 2021, 133, 11253–11257.
- 6
- 6aY. Hou, L. N. Zakharov, M. Nyman, J. Am. Chem. Soc. 2013, 135, 16651–16657;
- 6bS.-T. Zheng, J. Zhang, X.-X. Li, W.-H. Fang, G.-Y. Yang, J. Am. Chem. Soc. 2010, 132, 15102–15103;
- 6cM.-H. Du, X.-Y. Zheng, X.-J. Kong, L.-S. Long, L.-S. Zheng, Matter 2020, 3, 1334–1349;
- 6dC.-H. Zhan, Q. Zheng, D.-L. Long, L. Vilà-Nadal, L. Cronin, Angew. Chem. Int. Ed. 2019, 58, 17282–17286; Angew. Chem. 2019, 131, 17442–17446;
- 6eH. He, G.-J. Cao, S.-T. Zheng, G.-Y. Yang, J. Am. Chem. Soc. 2009, 131, 15588–15589;
- 6fZ. Wang, H.-F. Su, Y.-W. Gong, Q.-P. Qu, Y.-F. Bi, C.-H. Tung, D. Sun, L.-S. Zheng, Nat. Commun. 2020, 11, 308.
- 7
- 7aX.-Y. Zheng, X.-J. Kong, L.-S. Long, L.-S. Zheng, Z. Zheng, Z. Zheng, Acc. Chem. Res. 2018, 51, 517–525;
- 7bW.-G. Wang, A.-J. Zhou, W.-X. Zhang, M.-L. Tong, X.-M. Chen, M. Nakano, C. C. Beedle, D. N. Hendrickson, J. Am. Chem. Soc. 2007, 129, 1014–1015;
- 7cW.-H. Fang, G.-Y. Yang, Acc. Chem. Res. 2018, 51, 2888–2896.
- 8
- 8aY.-R. Zhao, H. Zheng, L.-Q. Chen, H.-J. Chen, X.-J. Kong, L.-S. Long, L.-S. Zheng, Inorg. Chem. 2019, 58, 10078–10083;
- 8bD.-F. Lu, Z.-F. Hong, J. Xie, X.-J. Kong, L.-S. Long, L.-S. Zheng, Inorg. Chem. 2017, 56, 12186–12192;
- 8cY. Lv, J. Willkomm, M. Leskes, A. Steiner, T. C. King, L. Gan, E. Reisner, P. T. Wood, D. S. Wright, Chem. Eur. J. 2012, 18, 11867–11870;
- 8dY.-P. He, L.-B. Yuan, G.-H. Chen, Q.-P. Lin, F. Wang, L. Zhang, J. Zhang, J. Am. Chem. Soc. 2017, 139, 16845–16851;
- 8eD.-F. Lu, X.-J. Kong, T.-B. Lu, L.-S. Long, L.-S. Zheng, Inorg. Chem. 2017, 56, 1057–1060.
- 9H. Zheng, M.-H. Du, S.-C. Lin, Z.-C. Tang, X.-J. Kong, L.-S. Long, L.-S. Zheng, Angew. Chem. Int. Ed. 2018, 57, 10976–10979; Angew. Chem. 2018, 130, 11142–11145.
- 10
- 10aM.-Y. Gao, K. Wang, Y. Sun, D. Li, B.-Q. Song, Y. H. Andaloussi, M. J. Zaworotko, J. Zhang, L. Zhang, J. Am. Chem. Soc. 2020, 142, 12784–12790;
- 10bB.-C. Zhu, W.-H. Fang, J. Wang, Y. Du, T. Zhou, K. Wu, L. Zhang, J. Zhang, Chem. Eur. J. 2018, 24, 14358–14362.
- 11
- 11aM. Jupa, G. Kickelbick, U. Schubert, Eur. J. Inorg. Chem. 2004, 1835–1839;
- 11bC. Artner, S. Kronister, M. Czakler, U. Schubert, Eur. J. Inorg. Chem. 2014, 5596–5602.
- 12T. Behrsing, G. B. Deacon, J. Luu, P. C. Junk, B. W. Skelton, A. H. White, Polyhedron 2016, 120, 69–81.
- 13N. Li, G. S. Subramanian, P. D. Matthews, J. Xiao, V. Chellappan, T. E. Rosser, E. Reisner, H.-K. Luo, D. S. Wright, Dalton Trans. 2018, 47, 5679–5686.
- 14B. Han, X. Gao, J. Lv, Z. Tang, Adv. Mater. 2020, 32, 1801491.
- 15T. Nakanishi, Y. Suzuki, Y. Doi, T. Seki, H. Koizumi, K. Fushimi, K. Fujita, Y. Hinatsu, H. Ito, K. Tanaka, Y. Hasegawa, Inorg. Chem. 2014, 53, 7635–7641.
- 16Deposition Numbers 2057817 (Eu22Ti14), 2109768 (Gd22Ti14), and 2124870 (1D-Eu chain) contain the supplementary crystallographic data for this paper. These data are provided free of charge by the joint Cambridge Crystallographic Data Centre and Fachinformationszentrum Karlsruhe Access Structures service.
Citing Literature
This is the
German version
of Angewandte Chemie.
Note for articles published since 1962:
Do not cite this version alone.
Take me to the International Edition version with citable page numbers, DOI, and citation export.
We apologize for the inconvenience.
