Coordinated Anionic Inorganic Module—An Efficient Approach Towards Highly Efficient Blue-Emitting Copper Halide Ionic Hybrid Structures
Haibo Li
School of Chemical Engineering and Technology, Sun Yat-sen University, Zhuhai, 519082, Guangdong P. R. China
School of Materials Science and Engineering, Sun Yat-sen University, Guangzhou, 510275, Guangdong P. R. China
Search for more papers by this authorYi Lv
School of Chemical Engineering and Technology, Sun Yat-sen University, Zhuhai, 519082, Guangdong P. R. China
Search for more papers by this authorZhennan Zhou
School of Chemical Engineering and Technology, Sun Yat-sen University, Zhuhai, 519082, Guangdong P. R. China
Search for more papers by this authorHua Tong
School of Chemical Engineering and Technology, Sun Yat-sen University, Zhuhai, 519082, Guangdong P. R. China
Search for more papers by this authorCorresponding Author
Dr. Wei Liu
School of Chemical Engineering and Technology, Sun Yat-sen University, Zhuhai, 519082, Guangdong P. R. China
Search for more papers by this authorCorresponding Author
Prof. Gangfeng Ouyang
School of Chemical Engineering and Technology, Sun Yat-sen University, Zhuhai, 519082, Guangdong P. R. China
Search for more papers by this authorHaibo Li
School of Chemical Engineering and Technology, Sun Yat-sen University, Zhuhai, 519082, Guangdong P. R. China
School of Materials Science and Engineering, Sun Yat-sen University, Guangzhou, 510275, Guangdong P. R. China
Search for more papers by this authorYi Lv
School of Chemical Engineering and Technology, Sun Yat-sen University, Zhuhai, 519082, Guangdong P. R. China
Search for more papers by this authorZhennan Zhou
School of Chemical Engineering and Technology, Sun Yat-sen University, Zhuhai, 519082, Guangdong P. R. China
Search for more papers by this authorHua Tong
School of Chemical Engineering and Technology, Sun Yat-sen University, Zhuhai, 519082, Guangdong P. R. China
Search for more papers by this authorCorresponding Author
Dr. Wei Liu
School of Chemical Engineering and Technology, Sun Yat-sen University, Zhuhai, 519082, Guangdong P. R. China
Search for more papers by this authorCorresponding Author
Prof. Gangfeng Ouyang
School of Chemical Engineering and Technology, Sun Yat-sen University, Zhuhai, 519082, Guangdong P. R. China
Search for more papers by this authorAbstract
Copper halide based organic–inorganic hybrid semiconductors exhibit great potential as light-emitting materials with excellent structural variety and optical tunability. Among them, copper halide hybrid molecular compounds with discrete inorganic modules are particularly interesting due to their high quantum efficiency. However, synthesizing highly efficient blue-emitting molecular clusters remains challenging. Here, we report a novel and facile strategy for the design and synthesis of highly luminescent copper halide hybrid structures by fabricating coordinated anionic inorganic modules in these ionic species. By using this approach, a family of strongly blue-emitting copper halide hybrid ionic structures has been prepared with high internal quantum yields up to 98 %. Strong luminescence from the combination of ionic and covalent bonds in these compounds make them ideal candidates as alternative, rare-earth-element free light-emitting materials for possible use in optoelectronic devices.
Conflict of interest
The authors declare no conflict of interest.
Open Research
Data Availability Statement
The data that support the findings of this study are available from the corresponding author upon reasonable request.
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