A Dynamic Chemical Clip in Supramolecular Framework for Sorting Alkylaromatic Isomers using Thermodynamic and Kinetic Preferences
Subhajit Laha
Chemistry and Physics of Materials Unit (CPMU), School of Adv. Mat. (SAMat), Jawaharlal Nehru Centre for Advanced Scientific Research (JNCASR), Bangalore, 560064 India
These authors contributed equally to this work.
Search for more papers by this authorDr. Ritesh Haldar
New Chemistry Unit (NCU), School of Adv. Mat. (SAMat), Jawaharlal Nehru Centre for Advanced Scientific Research (JNCASR), Bangalore, 560064 India
Present address: Tata Institute of Fundamental Research Hyderabad, Gopanpally, 500046 Telangana, India
These authors contributed equally to this work.
Search for more papers by this authorNimish Dwarkanath
Chemistry and Physics of Materials Unit (CPMU), School of Adv. Mat. (SAMat), Jawaharlal Nehru Centre for Advanced Scientific Research (JNCASR), Bangalore, 560064 India
Search for more papers by this authorDr. Satyanarayana Bonakala
Chemistry and Physics of Materials Unit (CPMU), School of Adv. Mat. (SAMat), Jawaharlal Nehru Centre for Advanced Scientific Research (JNCASR), Bangalore, 560064 India
Search for more papers by this authorDr. Abhishek Sharma
Chemistry and Physics of Materials Unit (CPMU), School of Adv. Mat. (SAMat), Jawaharlal Nehru Centre for Advanced Scientific Research (JNCASR), Bangalore, 560064 India
Search for more papers by this authorDr. Arpan Hazra
Chemistry and Physics of Materials Unit (CPMU), School of Adv. Mat. (SAMat), Jawaharlal Nehru Centre for Advanced Scientific Research (JNCASR), Bangalore, 560064 India
Search for more papers by this authorProf. Sundaram Balasubramanian
Chemistry and Physics of Materials Unit (CPMU), School of Adv. Mat. (SAMat), Jawaharlal Nehru Centre for Advanced Scientific Research (JNCASR), Bangalore, 560064 India
Search for more papers by this authorCorresponding Author
Prof. Tapas Kumar Maji
Chemistry and Physics of Materials Unit (CPMU), School of Adv. Mat. (SAMat), Jawaharlal Nehru Centre for Advanced Scientific Research (JNCASR), Bangalore, 560064 India
New Chemistry Unit (NCU), School of Adv. Mat. (SAMat), Jawaharlal Nehru Centre for Advanced Scientific Research (JNCASR), Bangalore, 560064 India
Search for more papers by this authorSubhajit Laha
Chemistry and Physics of Materials Unit (CPMU), School of Adv. Mat. (SAMat), Jawaharlal Nehru Centre for Advanced Scientific Research (JNCASR), Bangalore, 560064 India
These authors contributed equally to this work.
Search for more papers by this authorDr. Ritesh Haldar
New Chemistry Unit (NCU), School of Adv. Mat. (SAMat), Jawaharlal Nehru Centre for Advanced Scientific Research (JNCASR), Bangalore, 560064 India
Present address: Tata Institute of Fundamental Research Hyderabad, Gopanpally, 500046 Telangana, India
These authors contributed equally to this work.
Search for more papers by this authorNimish Dwarkanath
Chemistry and Physics of Materials Unit (CPMU), School of Adv. Mat. (SAMat), Jawaharlal Nehru Centre for Advanced Scientific Research (JNCASR), Bangalore, 560064 India
Search for more papers by this authorDr. Satyanarayana Bonakala
Chemistry and Physics of Materials Unit (CPMU), School of Adv. Mat. (SAMat), Jawaharlal Nehru Centre for Advanced Scientific Research (JNCASR), Bangalore, 560064 India
Search for more papers by this authorDr. Abhishek Sharma
Chemistry and Physics of Materials Unit (CPMU), School of Adv. Mat. (SAMat), Jawaharlal Nehru Centre for Advanced Scientific Research (JNCASR), Bangalore, 560064 India
Search for more papers by this authorDr. Arpan Hazra
Chemistry and Physics of Materials Unit (CPMU), School of Adv. Mat. (SAMat), Jawaharlal Nehru Centre for Advanced Scientific Research (JNCASR), Bangalore, 560064 India
Search for more papers by this authorProf. Sundaram Balasubramanian
Chemistry and Physics of Materials Unit (CPMU), School of Adv. Mat. (SAMat), Jawaharlal Nehru Centre for Advanced Scientific Research (JNCASR), Bangalore, 560064 India
Search for more papers by this authorCorresponding Author
Prof. Tapas Kumar Maji
Chemistry and Physics of Materials Unit (CPMU), School of Adv. Mat. (SAMat), Jawaharlal Nehru Centre for Advanced Scientific Research (JNCASR), Bangalore, 560064 India
New Chemistry Unit (NCU), School of Adv. Mat. (SAMat), Jawaharlal Nehru Centre for Advanced Scientific Research (JNCASR), Bangalore, 560064 India
Search for more papers by this authorAbstract
Adsorptive chemical separation is at the forefront of future technologies, for use in chemical and petrochemical industries. In this process, a porous adsorbent selectively allows a single component from a mixture of three or more chemical components to be adsorbed or permeate. To separate the unsorted chemicals, a different adsorbent is needed. A unique adsorbent which can recognize and separate each of the chemicals from a mixture of three or more components is the necessity for the next generation porous materials. In this regard, we demonstrate a “dynamic chemical clip” in a supramolecular framework capable of thermodynamic and kinetics-based chemical separation. The dynamic space, featuring a strong preference for aromatic guests through π-π and C-H⋅⋅⋅π interactions and adaptability, can recognize the individual chemical isomers from mixtures and separate those based on thermodynamic and kinetic factors. The liquid-phase selectivity and separation of the aromatic isomers are possible by the adaptability of the “chemical clip” and here we elucidate the prime factors in a combinatorial approach involving crystallographic evidence and detailed computational studies.
Conflict of interest
The authors declare no conflict of interest.
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