Delivery of a Masked Uranium(II) by an Oxide-Bridged Diuranium(III) Complex
Dieuwertje K. Modder
Institut des Sciences et Ingénierie Chimiques, Ecole Polytechnique Fédérale de Lausanne (EPFL), 1015 Lausanne, Switzerland
Search for more papers by this authorDr. Chad T. Palumbo
Institut des Sciences et Ingénierie Chimiques, Ecole Polytechnique Fédérale de Lausanne (EPFL), 1015 Lausanne, Switzerland
Search for more papers by this authorIskander Douair
Laboratoire de Physique et Chimie des Nano-objets, Institut National des Sciences Appliquées, 31077 Toulouse, Cedex 4, France
Search for more papers by this authorFarzaneh Fadaei-Tirani
Institut des Sciences et Ingénierie Chimiques, Ecole Polytechnique Fédérale de Lausanne (EPFL), 1015 Lausanne, Switzerland
Search for more papers by this authorProf. Laurent Maron
Laboratoire de Physique et Chimie des Nano-objets, Institut National des Sciences Appliquées, 31077 Toulouse, Cedex 4, France
Search for more papers by this authorCorresponding Author
Prof. Marinella Mazzanti
Institut des Sciences et Ingénierie Chimiques, Ecole Polytechnique Fédérale de Lausanne (EPFL), 1015 Lausanne, Switzerland
Search for more papers by this authorDieuwertje K. Modder
Institut des Sciences et Ingénierie Chimiques, Ecole Polytechnique Fédérale de Lausanne (EPFL), 1015 Lausanne, Switzerland
Search for more papers by this authorDr. Chad T. Palumbo
Institut des Sciences et Ingénierie Chimiques, Ecole Polytechnique Fédérale de Lausanne (EPFL), 1015 Lausanne, Switzerland
Search for more papers by this authorIskander Douair
Laboratoire de Physique et Chimie des Nano-objets, Institut National des Sciences Appliquées, 31077 Toulouse, Cedex 4, France
Search for more papers by this authorFarzaneh Fadaei-Tirani
Institut des Sciences et Ingénierie Chimiques, Ecole Polytechnique Fédérale de Lausanne (EPFL), 1015 Lausanne, Switzerland
Search for more papers by this authorProf. Laurent Maron
Laboratoire de Physique et Chimie des Nano-objets, Institut National des Sciences Appliquées, 31077 Toulouse, Cedex 4, France
Search for more papers by this authorCorresponding Author
Prof. Marinella Mazzanti
Institut des Sciences et Ingénierie Chimiques, Ecole Polytechnique Fédérale de Lausanne (EPFL), 1015 Lausanne, Switzerland
Search for more papers by this authorAbstract
Oxide is an attractive linker for building polymetallic complexes that provide molecular models for metal oxide activity, but studies of these systems are limited to metals in high oxidation states. Herein, we synthesized and characterized the molecular and electronic structure of diuranium bridged UIII/UIV and UIII/UIII complexes. Reactivity studies of these complexes revealed that the U−O bond is easily broken upon addition of N-heterocycles resulting in the delivery of a formal equivalent of UIII and UII, respectively, along with the uranium(IV) terminal-oxo coproduct. In particular, the UIII/UIII oxide complex effects the reductive coupling of pyridine and two-electron reduction of 4,4′-bipyridine affording unique examples of diuranium(III) complexes bridged by N-heterocyclic redox-active ligands. These results provide insight into the chemistry of low oxidation state metal oxides and demonstrate the use of oxo-bridged UIII/UIII complexes as a strategy to explore UII reactivity.
Conflict of interest
The authors declare no conflict of interest.
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