Enzyme-Inspired Room-Temperature Lithium–Oxygen Chemistry via Reversible Cleavage and Formation of Dioxygen Bonds
Chengyi Wang
School of Materials Science and Engineering, Institute of New Energy Material Chemistry, Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education), Renewable Energy Conversion and Storage Center (ReCast), Nankai University, Tianjin, 300350 China
Search for more papers by this authorDr. Zihe Zhang
School of Materials Science and Engineering, Institute of New Energy Material Chemistry, Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education), Renewable Energy Conversion and Storage Center (ReCast), Nankai University, Tianjin, 300350 China
Search for more papers by this authorWeiwei Liu
School of Materials Science and Engineering, Institute of New Energy Material Chemistry, Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education), Renewable Energy Conversion and Storage Center (ReCast), Nankai University, Tianjin, 300350 China
Search for more papers by this authorQinming Zhang
School of Materials Science and Engineering, Institute of New Energy Material Chemistry, Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education), Renewable Energy Conversion and Storage Center (ReCast), Nankai University, Tianjin, 300350 China
Search for more papers by this authorDr. Xin-Gai Wang
School of Materials Science and Engineering, Institute of New Energy Material Chemistry, Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education), Renewable Energy Conversion and Storage Center (ReCast), Nankai University, Tianjin, 300350 China
Search for more papers by this authorCorresponding Author
Dr. Zhaojun Xie
School of Materials Science and Engineering, Institute of New Energy Material Chemistry, Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education), Renewable Energy Conversion and Storage Center (ReCast), Nankai University, Tianjin, 300350 China
Search for more papers by this authorCorresponding Author
Prof. Zhen Zhou
School of Materials Science and Engineering, Institute of New Energy Material Chemistry, Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education), Renewable Energy Conversion and Storage Center (ReCast), Nankai University, Tianjin, 300350 China
Engineering Research Center of Advanced Functional Material Manufacturing of Ministry of Education, School of Chemical Engineering, Zhengzhou University, Zhengzhou, 450001 China
Search for more papers by this authorChengyi Wang
School of Materials Science and Engineering, Institute of New Energy Material Chemistry, Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education), Renewable Energy Conversion and Storage Center (ReCast), Nankai University, Tianjin, 300350 China
Search for more papers by this authorDr. Zihe Zhang
School of Materials Science and Engineering, Institute of New Energy Material Chemistry, Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education), Renewable Energy Conversion and Storage Center (ReCast), Nankai University, Tianjin, 300350 China
Search for more papers by this authorWeiwei Liu
School of Materials Science and Engineering, Institute of New Energy Material Chemistry, Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education), Renewable Energy Conversion and Storage Center (ReCast), Nankai University, Tianjin, 300350 China
Search for more papers by this authorQinming Zhang
School of Materials Science and Engineering, Institute of New Energy Material Chemistry, Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education), Renewable Energy Conversion and Storage Center (ReCast), Nankai University, Tianjin, 300350 China
Search for more papers by this authorDr. Xin-Gai Wang
School of Materials Science and Engineering, Institute of New Energy Material Chemistry, Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education), Renewable Energy Conversion and Storage Center (ReCast), Nankai University, Tianjin, 300350 China
Search for more papers by this authorCorresponding Author
Dr. Zhaojun Xie
School of Materials Science and Engineering, Institute of New Energy Material Chemistry, Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education), Renewable Energy Conversion and Storage Center (ReCast), Nankai University, Tianjin, 300350 China
Search for more papers by this authorCorresponding Author
Prof. Zhen Zhou
School of Materials Science and Engineering, Institute of New Energy Material Chemistry, Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education), Renewable Energy Conversion and Storage Center (ReCast), Nankai University, Tianjin, 300350 China
Engineering Research Center of Advanced Functional Material Manufacturing of Ministry of Education, School of Chemical Engineering, Zhengzhou University, Zhengzhou, 450001 China
Search for more papers by this authorAbstract
Li-O2 batteries are promising energy storage systems due to their ultra-high theoretical capacity. However, most Li-O2 batteries are based on the reduction/oxidation of Li2O2 and involve highly reactive superoxide and peroxide species that would cause serious degradation of cathodes, especially carbon-based materials. It is important to explore lithium-oxygen reactions and find new Li-O2 chemistry which can restrict or even avoid the negative influence of superoxide/peroxide species. Here, inspired by enzyme-catalyzed oxygen reduction/oxidation reactions, we introduce a copper(I) complex 3 N-CuI (3 N=1,4,7-trimethyl-1,4,7-triazacyclononane) to Li-O2 batteries and successfully modulate the reaction pathway to a moderate one on reversible cleavage/formation of O−O bonds. This work demonstrates that the reaction pathways of Li-O2 batteries could be modulated by introducing an appropriate soluble catalyst, which is another powerful choice to construct better Li-O2 batteries.
Conflict of interest
The authors declare no conflict of interest.
Supporting Information
As a service to our authors and readers, this journal provides supporting information supplied by the authors. Such materials are peer reviewed and may be re-organized for online delivery, but are not copy-edited or typeset. Technical support issues arising from supporting information (other than missing files) should be addressed to the authors.
| Filename | Description |
|---|---|
| ange202009792-sup-0001-misc_information.pdf1.1 MB | Supplementary |
Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.
References
- 1
- 1aJ. Lu, T. Wu, K. Amine, Nat. Energy 2017, 2, 17011;
- 1bX. Zhang, Y. Yang, Z. Zhou, Chem. Soc. Rev. 2020, 49, 3040–3071.
- 2
- 2aP. Zhang, Y. Zhao, X. Zhang, Chem. Soc. Rev. 2018, 47, 2921–3004;
- 2bT. Liu, J. P. Vivek, E. W. Zhao, J. Lei, N. Garcia-Araez, C. P. Grey, Chem. Rev. 2020, 120, 6558–6625;
- 2cH. D. Lim, B. Lee, Y. Bae, H. Park, Y. Ko, H. Kim, J. Kim, K. Kang, Chem. Soc. Rev. 2017, 46, 2873–2888;
- 2dJ. Lu, L. Li, J. B. Park, Y. K. Sun, F. Wu, K. Amine, Chem. Rev. 2014, 114, 5611–5640.
- 3D. Aurbach, B. D. McCloskey, L. F. Nazar, P. G. Bruce, Nat. Energy 2016, 1, 16128.
- 4
- 4aY. Li, X. Wang, S. Dong, X. Chen, G. Cui, Adv. Energy Mater. 2016, 6, 1600751;
- 4bC. Shu, J. Wang, J. Long, H. K. Liu, S. X. Dou, Adv. Mater. 2019, 31, 1804587.
- 5
- 5aD. M. Itkis, D. A. Semenenko, E. Y. Kataev, A. I. Belova, V. S. Neudachina, A. P. Sirotina, M. Havecker, D. Teschner, A. Knop-Gericke, P. Dudin, A. Barinov, E. A. Goodilin, Y. Shao-Horn, L. V. Yashina, Nano Lett. 2013, 13, 4697–4701;
- 5bM. M. Ottakam Thotiyl, S. A. Freunberger, Z. Peng, P. G. Bruce, J. Am. Chem. Soc. 2013, 135, 494–500.
- 6D. Wang, X. Mu, P. He, H. Zhou, Mater. Today 2019, 26, 87–99.
- 7
- 7aZ. Ma, X. Yuan, L. Li, Z.-F. Ma, D. P. Wilkinson, L. Zhang, J. Zhang, Energy Environ. Sci. 2015, 8, 2144–2198;
- 7bJ. Wang, Y. Li, X. Sun, Nano Energy 2013, 2, 443–467;
- 7cY. Shao, F. Ding, J. Xiao, J. Zhang, W. Xu, S. Park, J.-G. Zhang, Y. Wang, J. Liu, Adv. Funct. Mater. 2013, 23, 987–1004.
- 8
- 8aJ. B. Park, S. H. Lee, H. G. Jung, D. Aurbach, Y. K. Sun, Adv. Mater. 2018, 30, 1704162;
- 8bH. Deng, Y. Qiao, X. Zhang, F. Qiu, Z. Chang, P. He, H. Zhou, J. Mater. Chem. A 2019, 7, 17261–17265;
- 8cG. Leverick, M. Tułodziecki, R. Tatara, F. Bardé, Y. Shao-Horn, Joule 2019, 3, 1106–1126;
- 8dY. Zhang, L. Wang, X. Zhang, L. Guo, Y. Wang, Z. Peng, Adv. Mater. 2018, 30, 1705571;
- 8eY. Qiao, S. Wu, Y. Sun, S. Guo, J. Yi, P. He, H. Zhou, ACS Energy Lett. 2017, 2, 1869–1878.
- 9J. Lu, Y. J. Lee, X. Luo, K. C. Lau, M. Asadi, H. H. Wang, S. Brombosz, J. Wen, D. Zhai, Z. Chen, D. J. Miller, Y. S. Jeong, J. B. Park, Z. Z. Fang, B. Kumar, A. Salehi-Khojin, Y. K. Sun, L. A. Curtiss, K. Amine, Nature 2016, 529, 377–382.
- 10
- 10aC. M. Burke, R. Black, I. R. Kochetkov, V. Giordani, D. Addison, L. F. Nazar, B. D. McCloskey, ACS Energy Lett. 2016, 1, 747–756;
- 10bY. G. Zhu, Q. Liu, Y. Rong, H. Chen, J. Yang, C. Jia, L. J. Yu, A. Karton, Y. Ren, X. Xu, S. Adams, Q. Wang, Nat. Commun. 2017, 8, 14308;
- 10cF. Li, S. Wu, D. Li, T. Zhang, P. He, A. Yamada, H. Zhou, Nat. Commun. 2015, 6, 7843;
- 10dA. Dai, Q. Li, T. Liu, K. Amine, J. Lu, Adv. Mater. 2019, 31, 1805602.
- 11T. Liu, M. Leskes, W. Yu, A. J. Moore, L. Zhou, P. M. Bayley, G. Kim, C. P. Grey, Science 2015, 350, 530–533.
- 12C. Xia, C. Y. Kwok, L. F. Nazar, Science 2018, 361, 777–781.
- 13W. H. Ryu, F. S. Gittleson, J. M. Thomsen, J. Li, M. J. Schwab, G. W. Brudvig, A. D. Taylor, Nat. Commun. 2016, 7, 12925.
- 14E. I. Solomon, D. E. Heppner, E. M. Johnston, J. W. Ginsbach, J. Cirera, M. Qayyum, M. T. Kieber-Emmons, C. H. Kjaergaard, R. G. Hadt, L. Tian, Chem. Rev. 2014, 114, 3659–3853.
- 15J. A. Halfen, S. Mahapatra, E. C. Wilkinson, S. Kaderli, V. G. Young, Jr., L. Que, Jr., A. D. Zuberbuhler, W. B. Tolman, Science 1996, 271, 1397–1400.
- 16T. Liu, Z. Liu, G. Kim, J. T. Frith, N. Garcia-Araez, C. P. Grey, Angew. Chem. Int. Ed. 2017, 56, 16057–16062; Angew. Chem. 2017, 129, 16273–16278.
- 17N. B. Aetukuri, B. D. McCloskey, J. M. Garcia, L. E. Krupp, V. Viswanathan, A. C. Luntz, Nat. Chem. 2015, 7, 50–56.
- 18
- 18aL. Tahsini, H. Kotani, Y. M. Lee, J. Cho, W. Nam, K. D. Karlin, S. Fukuzumi, Chem. Eur. J. 2012, 18, 1084–1093;
- 18bL. M. Berreau, S. Mahapatra, J. A. Halfen, R. P. Houser, J. V. G. Young, W. B. Tolman, Angew. Chem. Int. Ed. 1999, 38, 207–210;
10.1002/(SICI)1521-3773(19990115)38:1/2<207::AID-ANIE207>3.0.CO;2-U CAS Web of Science® Google ScholarAngew. Chem. 1999, 111, 180–183.
Citing Literature
This is the
German version
of Angewandte Chemie.
Note for articles published since 1962:
Do not cite this version alone.
Take me to the International Edition version with citable page numbers, DOI, and citation export.
We apologize for the inconvenience.
