K2Sb(P2O7)F: Cairo Pentagonal Layer with Bifunctional Genes Reveal Optical Performance
Yalan Deng
College of Chemistry, Sichuan University, Chengdu, 610064 P. R. China
College of Chemistry and Materials Science, Sichuan Normal University, Chengdu, 610066 P. R. China
These authors contributed equally to this work.
Search for more papers by this authorProf. Ling Huang
College of Chemistry and Materials Science, Sichuan Normal University, Chengdu, 610066 P. R. China
These authors contributed equally to this work.
Search for more papers by this authorXuehua Dong
College of Chemistry, Sichuan University, Chengdu, 610064 P. R. China
Search for more papers by this authorLei Wang
College of Chemistry and Materials Science, Sichuan Normal University, Chengdu, 610066 P. R. China
Search for more papers by this authorProf. Kang Min Ok
Department of Chemistry, Sogang University, Seoul, 04107 Republic of Korea
Search for more papers by this authorProf. Hongmei Zeng
College of Chemistry, Sichuan University, Chengdu, 610064 P. R. China
Search for more papers by this authorProf. Zhien Lin
College of Chemistry, Sichuan University, Chengdu, 610064 P. R. China
Search for more papers by this authorCorresponding Author
Prof. Guohong Zou
College of Chemistry, Sichuan University, Chengdu, 610064 P. R. China
Search for more papers by this authorYalan Deng
College of Chemistry, Sichuan University, Chengdu, 610064 P. R. China
College of Chemistry and Materials Science, Sichuan Normal University, Chengdu, 610066 P. R. China
These authors contributed equally to this work.
Search for more papers by this authorProf. Ling Huang
College of Chemistry and Materials Science, Sichuan Normal University, Chengdu, 610066 P. R. China
These authors contributed equally to this work.
Search for more papers by this authorXuehua Dong
College of Chemistry, Sichuan University, Chengdu, 610064 P. R. China
Search for more papers by this authorLei Wang
College of Chemistry and Materials Science, Sichuan Normal University, Chengdu, 610066 P. R. China
Search for more papers by this authorProf. Kang Min Ok
Department of Chemistry, Sogang University, Seoul, 04107 Republic of Korea
Search for more papers by this authorProf. Hongmei Zeng
College of Chemistry, Sichuan University, Chengdu, 610064 P. R. China
Search for more papers by this authorProf. Zhien Lin
College of Chemistry, Sichuan University, Chengdu, 610064 P. R. China
Search for more papers by this authorCorresponding Author
Prof. Guohong Zou
College of Chemistry, Sichuan University, Chengdu, 610064 P. R. China
Search for more papers by this authorAbstract
Discovering new functional genes, designing perfect crystal structures, and developing high-performance materials are the goals being pursued by scientists. Herein, the first antimony pyrophosphate, K2Sb(P2O7)F, possessing an optimal layered structure, is reported, where the perfect structural arrangement induces excellent optical properties. K2Sb(P2O7)F not only displays a sharply enhanced birefringence (0.157@546 nm) compared to the existing phosphate optical materials, but also exhibits a strong second-harmonic generation response (4.0×KDP). Remarkably, a new bifunctional gene, the square-pyramidal SbO4F group, was discovered, and a unique two-dimensional arrangement of Cairo pentagonal tiling units was observed in inorganic compounds for the first time.
Conflict of interest
The authors declare no conflict of interest.
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