Volume 130, Issue 18
Frontispiz
Free Access

Frontispiz: Entropy-Driven Diastereoselectivity Improvement in the Paternò–Büchi Reaction of 1-Naphthyl Aryl Ethenes with a Chiral Cyanobenzoate through Remote Alkylation

Keisuke Nagasaki

Keisuke Nagasaki

Department of Applied Chemistry, Graduate School of Engineering, Osaka University, 2-1 Yamada-oka, Suita, 565-0871 Japan

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Prof. Dr. Yoshihisa Inoue

Prof. Dr. Yoshihisa Inoue

Department of Applied Chemistry, Graduate School of Engineering, Osaka University, 2-1 Yamada-oka, Suita, 565-0871 Japan

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Prof. Dr. Tadashi Mori

Corresponding Author

Prof. Dr. Tadashi Mori

Department of Applied Chemistry, Graduate School of Engineering, Osaka University, 2-1 Yamada-oka, Suita, 565-0871 Japan

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First published: 17 April 2018

Graphical Abstract

Photochemie In ihrer Zuschrift auf S. 4974 ff. zeigen T. Mori et al., dass die Entropie für die Diastereoselektivität von Paternò-Büchi-Reaktionen von 1-Naphthyl-1-arylethenen mit einem chiralen 4-Cyanbenzoat von entscheidender Bedeutung ist.

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