Innenrücktitelbild: Transition-Metal-Like Behavior of Monovalent Boron Compounds: Reduction, Migration, and Complete Cleavage of CO at a Boron Center (Angew. Chem. 28/2018)

Dr. Hao Wang

Department of Chemistry and State Key Laboratory of Synthetic Chemistry, The Chinese University of Hong Kong, Shatin, New Territories, Hong Kong, China

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Linlin Wu,

Linlin Wu

Department of Chemistry, The Hong Kong University of Science and Technology, Clear Water Bay, Kowloon, Hong Kong, China

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Prof. Dr. Zhenyang Lin,

Corresponding Author

Prof. Dr. Zhenyang Lin

[email protected]

Department of Chemistry, The Hong Kong University of Science and Technology, Clear Water Bay, Kowloon, Hong Kong, China

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Prof. Dr. Zuowei Xie,

Corresponding Author

Prof. Dr. Zuowei Xie

[email protected]

orcid.org/0000-0001-6206-004X

Department of Chemistry and State Key Laboratory of Synthetic Chemistry, The Chinese University of Hong Kong, Shatin, New Territories, Hong Kong, China

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Dr. Hao Wang,

Dr. Hao Wang

Department of Chemistry and State Key Laboratory of Synthetic Chemistry, The Chinese University of Hong Kong, Shatin, New Territories, Hong Kong, China

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Linlin Wu,

Linlin Wu

Department of Chemistry, The Hong Kong University of Science and Technology, Clear Water Bay, Kowloon, Hong Kong, China

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Prof. Dr. Zhenyang Lin,

Corresponding Author

Prof. Dr. Zhenyang Lin

[email protected]

Department of Chemistry, The Hong Kong University of Science and Technology, Clear Water Bay, Kowloon, Hong Kong, China

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Prof. Dr. Zuowei Xie,

Corresponding Author

Prof. Dr. Zuowei Xie

[email protected]

orcid.org/0000-0001-6206-004X

Department of Chemistry and State Key Laboratory of Synthetic Chemistry, The Chinese University of Hong Kong, Shatin, New Territories, Hong Kong, China

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First published: 26 April 2018

https://doi.org/10.1002/ange.201804537

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Graphical Abstract

Monovalente Bor-Verbindungen imitieren das chemische Verhalten von Übergangsmetallkomplexen. In ihrer Zuschrift auf S. 8844 beschreiben Z. Xie et al. diverse Reaktionen einer Borylen-Carbonyl-Verbindung mit verschiedenen Reduktionsmitteln und Nucleophilen, die z. B. zu CO-Reduktion, -Migration und -Spaltung führen. Das Titelbild veranschaulicht die unterschiedlichen Reaktionen, die für diese Verbindung beobachtet werden.