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Innentitelbild: A Nanoarchitecture Based on Silver and Copper Oxide with an Exceptional Response in the Chlorine-Promoted Epoxidation of Ethylene (Angew. Chem. 37/2016)

Adrian Ramirez

Department of Chemical Engineering and Environmental Technology and Institute of Nanoscience of Aragon (INA), University of Zaragoza, 50018 Zaragoza, Spain

These authors contributed equally to this work.

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Dr. Jose L. Hueso,

Corresponding Author

Dr. Jose L. Hueso

[email protected]

orcid.org/0000-0002-4546-4111

Department of Chemical Engineering and Environmental Technology and Institute of Nanoscience of Aragon (INA), University of Zaragoza, 50018 Zaragoza, Spain

Networking Research Centre on Bioengineering, Biomaterials, and Nanomedicine, CIBER-BBN, 28029 Madrid, Spain

These authors contributed equally to this work.

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Hugo Suarez,

Hugo Suarez

Department of Chemical Engineering and Environmental Technology and Institute of Nanoscience of Aragon (INA), University of Zaragoza, 50018 Zaragoza, Spain

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Dr. Reyes Mallada,

Dr. Reyes Mallada

Department of Chemical Engineering and Environmental Technology and Institute of Nanoscience of Aragon (INA), University of Zaragoza, 50018 Zaragoza, Spain

Networking Research Centre on Bioengineering, Biomaterials, and Nanomedicine, CIBER-BBN, 28029 Madrid, Spain

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Dr. Alfonso Ibarra,

Dr. Alfonso Ibarra

Advanced Microscopy Laboratory and Institute of Nanoscience of Aragon (LMA-INA), University of Zaragoza, 50018 Zaragoza, Spain

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Dr. Silvia Irusta,

Dr. Silvia Irusta

Department of Chemical Engineering and Environmental Technology and Institute of Nanoscience of Aragon (INA), University of Zaragoza, 50018 Zaragoza, Spain

Networking Research Centre on Bioengineering, Biomaterials, and Nanomedicine, CIBER-BBN, 28029 Madrid, Spain

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Prof. Jesus Santamaria,

Corresponding Author

Prof. Jesus Santamaria

[email protected]

Department of Chemical Engineering and Environmental Technology and Institute of Nanoscience of Aragon (INA), University of Zaragoza, 50018 Zaragoza, Spain

Networking Research Centre on Bioengineering, Biomaterials, and Nanomedicine, CIBER-BBN, 28029 Madrid, Spain

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Adrian Ramirez,

Adrian Ramirez

Department of Chemical Engineering and Environmental Technology and Institute of Nanoscience of Aragon (INA), University of Zaragoza, 50018 Zaragoza, Spain

These authors contributed equally to this work.

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Dr. Jose L. Hueso,

Corresponding Author

Dr. Jose L. Hueso

[email protected]

orcid.org/0000-0002-4546-4111

Department of Chemical Engineering and Environmental Technology and Institute of Nanoscience of Aragon (INA), University of Zaragoza, 50018 Zaragoza, Spain

Networking Research Centre on Bioengineering, Biomaterials, and Nanomedicine, CIBER-BBN, 28029 Madrid, Spain

These authors contributed equally to this work.

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Hugo Suarez,

Hugo Suarez

Department of Chemical Engineering and Environmental Technology and Institute of Nanoscience of Aragon (INA), University of Zaragoza, 50018 Zaragoza, Spain

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Dr. Reyes Mallada,

Dr. Reyes Mallada

Department of Chemical Engineering and Environmental Technology and Institute of Nanoscience of Aragon (INA), University of Zaragoza, 50018 Zaragoza, Spain

Networking Research Centre on Bioengineering, Biomaterials, and Nanomedicine, CIBER-BBN, 28029 Madrid, Spain

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Dr. Alfonso Ibarra,

Dr. Alfonso Ibarra

Advanced Microscopy Laboratory and Institute of Nanoscience of Aragon (LMA-INA), University of Zaragoza, 50018 Zaragoza, Spain

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Dr. Silvia Irusta,

Dr. Silvia Irusta

Department of Chemical Engineering and Environmental Technology and Institute of Nanoscience of Aragon (INA), University of Zaragoza, 50018 Zaragoza, Spain

Networking Research Centre on Bioengineering, Biomaterials, and Nanomedicine, CIBER-BBN, 28029 Madrid, Spain

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Prof. Jesus Santamaria,

Corresponding Author

Prof. Jesus Santamaria

[email protected]

Department of Chemical Engineering and Environmental Technology and Institute of Nanoscience of Aragon (INA), University of Zaragoza, 50018 Zaragoza, Spain

Networking Research Centre on Bioengineering, Biomaterials, and Nanomedicine, CIBER-BBN, 28029 Madrid, Spain

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First published: 28 July 2016

https://doi.org/10.1002/ange.201606755

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Graphical Abstract

Silbernanostrukturen (dargestellt als Inseln) auf einem Kupferoxid-Träger (dargestellt als Meer) bilden einen hervorragenden Katalysator für die selektive Epoxidierung von Ethylen bei Temperaturen unter 250 °C. J. L. Hueso, J. Santamaria et al. berichten in der Zuschrift auf S. 11324 ff., dass der Katalysator in einem einzigen Vorbehandlungsschritt mit Chlorpromotoren versetzt werden kann. Das Kupferoxid wirkt als Cl-Schwamm und verhindert dadurch weitgehend eine irreversible Vergiftung des Katalysators.