Assembly of Tungsten-Oxide-Based Pentagonal Motifs in Solution Leads to Nanoscale {W48}, {W56}, and {W92} Polyoxometalate Clusters
Cai-Hong Zhan
WestCHEM, School of Chemistry, The University of Glasgow, Glasgow G12 8QQ (UK) http://www.croninlab.com
These authors contributed equally to this work.
Search for more papers by this authorDr. Ross S. Winter
WestCHEM, School of Chemistry, The University of Glasgow, Glasgow G12 8QQ (UK) http://www.croninlab.com
These authors contributed equally to this work.
Search for more papers by this authorQi Zheng
WestCHEM, School of Chemistry, The University of Glasgow, Glasgow G12 8QQ (UK) http://www.croninlab.com
Search for more papers by this authorDr. Jun Yan
WestCHEM, School of Chemistry, The University of Glasgow, Glasgow G12 8QQ (UK) http://www.croninlab.com
Search for more papers by this authorDr. Jamie M. Cameron
WestCHEM, School of Chemistry, The University of Glasgow, Glasgow G12 8QQ (UK) http://www.croninlab.com
Search for more papers by this authorCorresponding Author
Dr. De-Liang Long
WestCHEM, School of Chemistry, The University of Glasgow, Glasgow G12 8QQ (UK) http://www.croninlab.com
WestCHEM, School of Chemistry, The University of Glasgow, Glasgow G12 8QQ (UK) http://www.croninlab.comSearch for more papers by this authorCorresponding Author
Prof. Dr. Leroy Cronin
WestCHEM, School of Chemistry, The University of Glasgow, Glasgow G12 8QQ (UK) http://www.croninlab.com
WestCHEM, School of Chemistry, The University of Glasgow, Glasgow G12 8QQ (UK) http://www.croninlab.comSearch for more papers by this authorCai-Hong Zhan
WestCHEM, School of Chemistry, The University of Glasgow, Glasgow G12 8QQ (UK) http://www.croninlab.com
These authors contributed equally to this work.
Search for more papers by this authorDr. Ross S. Winter
WestCHEM, School of Chemistry, The University of Glasgow, Glasgow G12 8QQ (UK) http://www.croninlab.com
These authors contributed equally to this work.
Search for more papers by this authorQi Zheng
WestCHEM, School of Chemistry, The University of Glasgow, Glasgow G12 8QQ (UK) http://www.croninlab.com
Search for more papers by this authorDr. Jun Yan
WestCHEM, School of Chemistry, The University of Glasgow, Glasgow G12 8QQ (UK) http://www.croninlab.com
Search for more papers by this authorDr. Jamie M. Cameron
WestCHEM, School of Chemistry, The University of Glasgow, Glasgow G12 8QQ (UK) http://www.croninlab.com
Search for more papers by this authorCorresponding Author
Dr. De-Liang Long
WestCHEM, School of Chemistry, The University of Glasgow, Glasgow G12 8QQ (UK) http://www.croninlab.com
WestCHEM, School of Chemistry, The University of Glasgow, Glasgow G12 8QQ (UK) http://www.croninlab.comSearch for more papers by this authorCorresponding Author
Prof. Dr. Leroy Cronin
WestCHEM, School of Chemistry, The University of Glasgow, Glasgow G12 8QQ (UK) http://www.croninlab.com
WestCHEM, School of Chemistry, The University of Glasgow, Glasgow G12 8QQ (UK) http://www.croninlab.comSearch for more papers by this authorAbstract
We report an approach to synthesize molecular tungsten-oxide-based pentagonal building blocks, in a new {W21O72} unit, and show how this leads to a family of gigantic molecular architectures including [H12W48O164]28− {W48}, [H20W56O190]24− {W56}, and [H12W92O311]58− {W92}. The {W48} and {W56} clusters are both dimeric species incorporating two {W21} units and the {W56} species is the first example of a molecular metal oxide cluster containing a chiral “double-stranded” motif which is stable in solution as confirmed by mass spectrometry. The {W92} anion having four {W21} units is one of the largest transition metal substituted isopolyoxotungstates known.
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References
- 1K. E. Drexler, Proc. Natl. Acad. Sci. USA 1981, 78, 5275–5278.
- 2K. S. Chichak, S. J. Cantrill, A. R. Pease, S. H. Chiu, G. W. Cave, J. L. Atwood, J. F. Stoddart, Science 2004, 304, 1308–1312.
- 3O. M. Yaghi, M. O’Keeffe, N. W. Ockwig, H. K. Chae, M. Eddaoudi, J. Kim, Nature 2003, 423, 705–714.
- 4B. Therrien, G. Süss-Fink, P. Govindaswamy, A. K. Renfrew, P. J. Dyson, Angew. Chem. Int. Ed. 2008, 47, 3773–3776; Angew. Chem. 2008, 120, 3833–3836.
- 5A. Müller, P. Gouzerh, Chem. Soc. Rev. 2012, 41, 7431–7463.
- 6Y. Sasaki, T. Yamase, Y. Ohashi, Y. Sasada, Bull. Chem. Soc. Jpn. 1987, 60, 4285–4290.
- 7T. Lehmann, J. Z. Fuchs, Z. Naturforsch. B 1988, 43, 89–93.
- 8
- 8aJ. F. Keggin, Nature 1933, 131, 908–909;
- 8bJ. F. Keggin, Proc. R. Soc. London Ser. A 1934, 144, 75–100;
- 8cB. Dawson, Acta Crystallogr. 1953, 6, 113–126.
- 9aR. Allmann, Acta Crystallogr. Sect. B 1971, 27, 1393–1404;
- 9bA. Chrissafidou, J. Fuchs, H. Hartl, R. Palm, Z. Naturforsch. B 1995, 50, 217–222.
- 10I. Brüdgam, J. Fuchs, H. Hartl, R. Palm, Angew. Chem. Int. Ed. 1998, 37, 2668–2671;
10.1002/(SICI)1521-3773(19981016)37:19<2668::AID-ANIE2668>3.0.CO;2-8 CAS PubMed Web of Science® Google ScholarAngew. Chem. 1998, 110, 2814–2817.10.1002/(SICI)1521-3757(19981002)110:19<2814::AID-ANGE2814>3.0.CO;2-0 Web of Science® Google Scholar
- 11C. H. Zhan, J. M. Cameron, J. Gao, J. M. Purcell, D.-L. Long, L. Cronin, Angew. Chem. Int. Ed. 2014, 53, 10362–10366; Angew. Chem. 2014, 126, 10530–10534.
- 12H. N. Miras, J. Yan, D.-L. Long, L. Cronin, Angew. Chem. Int. Ed. 2008, 47, 8420–8423; Angew. Chem. 2008, 120, 8548–8551.
- 13D.-L. Long, H. Abbas, P. Kögerler, L. Cronin, J. Am. Chem. Soc. 2004, 126, 13880–13881.
- 14D.-L. Long, P. Kögerler, A. D. C. Parenty, J. Fielden, L. Cronin, Angew. Chem. Int. Ed. 2006, 45, 4798–4803; Angew. Chem. 2006, 118, 4916–4921.
- 15A. R. de la Oliva, V. Sans, H. N. Miras, J. Yan, H. Zang, C. J. Richmond, D.-L. Long, L. Cronin, Angew. Chem. Int. Ed. 2012, 51, 12759–12762; Angew. Chem. 2012, 124, 12931–12934.
- 16
- 16aX. K. Fang, T. M. Anderson, C. L. Hill, Angew. Chem. Int. Ed. 2005, 44, 3540–3544; Angew. Chem. 2005, 117, 3606–3610;
- 16bJ. Zhang, J. Hao, Y. Wei, F. Xiao, P. Yin, L. Wang, J. Am. Chem. Soc. 2010, 132, 14–15;
- 16cB. Hasenknopf, K. Micoine, E. Lacote, S. Thorimbert, M. Malacria, R. Thouvenot, Eur. J. Inorg. Chem. 2008, 5001–5013;
- 16dQ. Han, C. He, M. Zhao, B. Qi, J. Niu, C. Duan, J. Am. Chem. Soc. 2013, 135, 10186–10189;
- 16eC. Zhao, E. N. Glass, J. M. Sumliner, J. Bacsa, D. T. Kim, W. Guo, C. L. Hill, Dalton Trans. 2014, 43, 4040–4047;
- 16fC. Brazel, N. Dupré, M. Malacria, B. Hasenknopf, E. Lacôte, S. Thorimbert, Eur. J. Inorg. Chem. 2014, 16074–16077;
- 16gG. Zhu, Y. V. Geletii, P. Kögerler, H. Schilder, J. Song, S. Lense, C. Zhao, K. I. Hardcastle, D. G. Musaev, C. L. Hill, Dalton Trans. 2012, 41, 2084–2090;
- 16hA. Seliverstov, C. Streb, Chem. Commun. 2014, 50, 1827–1829.
- 17The directly acidified solution reaction of tungstate, sulfite and DMAH+ at the same pH without redox process only leads the isolation of [H4W22O76]12− as compound Na6(DMAH)6[H4W22O76], which is the dimer motif of [H4W11O38]6− anion.
- 18A similar phenomenon has recently been observed by other researchers. J. Forster, B. Rösner, R. H. Fink, L. C. Nye, I. Ivanovic-Burmazovic, K. Kastner, J. Tucher, C. Streb, Chem. Sci. 2013, 4, 418–424.
- 19J. Yan, D.-L. Long, E. F. Wilson, L. Cronin, Angew. Chem. Int. Ed. 2009, 48, 4376–4380; Angew. Chem. 2009, 121, 4440–4444.
- 20This behavior, that is, the necessity of another element for cluster formation without it being incorporated into the final structure, has been reported by other researchers. K. Kastner, J. T. Margraf, T. Clark, C. Streb, Chem. Eur. J. 2014, 20, 12269–12273.
- 21R. Tsunashima, D.-L. Long, H. N. Miras, D. Gabb, C. P. Pradeep, L. Cronin, Angew. Chem. Int. Ed. 2010, 49, 113–116; Angew. Chem. 2010, 122, 117–120.
- 22A. H. Ismail, M. H. Dickman, U. Kortz, Inorg. Chem. 2009, 48, 1559–1565.
- 23
- 23aA. M. Todea, A. Merca, H. Bögge, T. Glaser, J. M. Pigga, M. L. K. Langston, T. Liu, R. Prozorov, M. Luban, C. Schröder, W. H. Casey, A. Müller, Angew. Chem. Int. Ed. 2010, 49, 514–519; Angew. Chem. 2010, 122, 524–529;
- 23bA. M. Todea, A. Merca, H. Bögge, T. Glaser, L. Engelhardt, R. Prozorov, M. Luban, A. Müller, Chem. Commun. 2009, 3351–3353;
- 23cC. Schäffer, A. M. Todea, H. Bögge, E. Cadot, P. Gouzerh, S. Kopilevich, I. A. Weinstock, A. Müller, Angew. Chem. Int. Ed. 2011, 50, 12326–12329; Angew. Chem. 2011, 123, 12534–12537;
- 23dC. Schäffer, A. Merca, H. Bögge, A. M. Todea, M. L. Kistler, T. Liu, R. Thouvenot, P. Gouzerh, A. Müller, Angew. Chem. Int. Ed. 2009, 48, 149–153; Angew. Chem. 2009, 121, 155–159.
- 24N. Leclerc-Laronze, J. Marrot, R. Thouvenot, E. Cadot, Angew. Chem. Int. Ed. 2009, 48, 4986–4989; Angew. Chem. 2009, 121, 5086–5089.
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