A Common Intermediate for N2 Formation in Enzymes and Zeolites: Side-On Cu–Nitrosyl Complexes†
Corresponding Author
Ja Hun Kwak
School of Nano-Bioscience & Chemical Engineering, Ulsan National Institute of Science and Technology (UNIST), Ulsan 689-798 (Korea)
Ja Hun Kwak, School of Nano-Bioscience & Chemical Engineering, Ulsan National Institute of Science and Technology (UNIST), Ulsan 689-798 (Korea)===
János Szanyi, Institute for Integrated Catalysis, Pacific Northwest National Laboratory, Richland, WA 99354 (USA)===
Search for more papers by this authorJong H. Lee
Institute for Integrated Catalysis, Pacific Northwest National Laboratory, Richland, WA 99354 (USA)
Current address: Daimler Trucks North America, Detroit, MI (USA)
Search for more papers by this authorSarah D. Burton
Environmental Molecular Sciences Laboratory, Pacific Northwest National Laboratory, Richland, WA 99354 (USA)
Search for more papers by this authorAndrew S. Lipton
Environmental Molecular Sciences Laboratory, Pacific Northwest National Laboratory, Richland, WA 99354 (USA)
Search for more papers by this authorCharles H. F. Peden
Institute for Integrated Catalysis, Pacific Northwest National Laboratory, Richland, WA 99354 (USA)
Search for more papers by this authorCorresponding Author
János Szanyi
Institute for Integrated Catalysis, Pacific Northwest National Laboratory, Richland, WA 99354 (USA)
Ja Hun Kwak, School of Nano-Bioscience & Chemical Engineering, Ulsan National Institute of Science and Technology (UNIST), Ulsan 689-798 (Korea)===
János Szanyi, Institute for Integrated Catalysis, Pacific Northwest National Laboratory, Richland, WA 99354 (USA)===
Search for more papers by this authorCorresponding Author
Ja Hun Kwak
School of Nano-Bioscience & Chemical Engineering, Ulsan National Institute of Science and Technology (UNIST), Ulsan 689-798 (Korea)
Ja Hun Kwak, School of Nano-Bioscience & Chemical Engineering, Ulsan National Institute of Science and Technology (UNIST), Ulsan 689-798 (Korea)===
János Szanyi, Institute for Integrated Catalysis, Pacific Northwest National Laboratory, Richland, WA 99354 (USA)===
Search for more papers by this authorJong H. Lee
Institute for Integrated Catalysis, Pacific Northwest National Laboratory, Richland, WA 99354 (USA)
Current address: Daimler Trucks North America, Detroit, MI (USA)
Search for more papers by this authorSarah D. Burton
Environmental Molecular Sciences Laboratory, Pacific Northwest National Laboratory, Richland, WA 99354 (USA)
Search for more papers by this authorAndrew S. Lipton
Environmental Molecular Sciences Laboratory, Pacific Northwest National Laboratory, Richland, WA 99354 (USA)
Search for more papers by this authorCharles H. F. Peden
Institute for Integrated Catalysis, Pacific Northwest National Laboratory, Richland, WA 99354 (USA)
Search for more papers by this authorCorresponding Author
János Szanyi
Institute for Integrated Catalysis, Pacific Northwest National Laboratory, Richland, WA 99354 (USA)
Ja Hun Kwak, School of Nano-Bioscience & Chemical Engineering, Ulsan National Institute of Science and Technology (UNIST), Ulsan 689-798 (Korea)===
János Szanyi, Institute for Integrated Catalysis, Pacific Northwest National Laboratory, Richland, WA 99354 (USA)===
Search for more papers by this authorThe authors acknowledge the US Department of Energy (DOE), Office of Energy Efficiency and Renewable Energy/Vehicle Technologies Program for support of this work. The research described in this paper was performed at the Environmental Molecular Sciences Laboratory (EMSL), a national scientific user facility sponsored by the DOE’s Office of Biological and Environmental Research and located at Pacific Northwest National Laboratory (PNNL). PNNL is operated for the US DOE by Battelle Memorial Institute.
Graphical Abstract
Eine Kombination aus FTIR- und NMR-spektroskopischen Studien zeigt das Vorhandensein einer Side-on-Nitrosylspezies im Zeolith Cu-SSZ-13. Dieses Intermediat ähnelt stark denjenigen in Nitritreduktasen. Seine Identifizierung führte zu einem postulierten Reaktionsmechanismus, der völlig in Einklang mit den Ergebnissen kinetischer und spektroskopischer Studien ist.
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References
- 1B. Kartal, W. J. Maalcke, N. M. de Almeida, I. Cirpus, J. Gloerich, W. Geerts, H. J. M. O. den Camp, H. R. Harhangi, E. M. Janssen-Megens, K. J. Francoijs, H. G. Stunnenberg, J. T. Keltjens, M. S. M. Jetten, M. Strous, Nature 2011, 479, 127–130.
- 2P. A. Williams, V. Fulop, E. F. Garman, N. F. W. Saunders, S. J. Ferguson, J. Hajdu, Nature 1997, 389, 406–412.
- 3I. M. Wasser, S. de Vries, P. Moenne-Loccoz, I. Schroder, K. D. Karlin, Chem. Rev. 2002, 102, 1201–1234.
- 4E. I. Tocheva, F. I. Rosell, A. G. Mauk, M. E. P. Murphy, Science 2004, 304, 867–870.
- 5A. Weichsel, J. F. Anderson, S. A. Roberts, W. R. Montfort, Nat. Struct. Biol. 2000, 7, 551–556.
- 6A. Karlsson, J. V. Parales, R. E. Parales, D. T. Gibson, H. Eklund, S. Ramaswamy, Science 2003, 299, 1039–1042.
- 7M. D. Carducci, M. R. Pressprich, P. Coppens, J. Am. Chem. Soc. 1997, 119, 2669–2678.
- 8S. Brandenberger, O. Krocher, A. Tissler, R. Althoff, Catal. Rev. Sci. Eng. 2008, 50, 492–531.
- 9J. H. Kwak, D. Tran, S. D. Burton, J. Szanyi, J. H. Lee, C. H. F. Peden, J. Catal. 2012, 287, 203–209.
- 10D. W. Fickel, E. D′Addio, J. A. Lauterbach, R. F. Lobo, Appl. Catal. B 2011, 102, 441–448.
- 11J. H. Kwak, R. G. Tonkyn, D. H. Kim, J. Szanyi, C. H. F. Peden, J. Catal. 2010, 275, 187–190.
- 12U. Deka, A. Juhin, E. A. Eilertsen, H. Emerich, M. A. Green, S. T. Korhonen, B. M. Weckhuysen, A. M. Beale, J. Phys. Chem. C 2012, 116, 4809–4818.
- 13J. H. Kwak, D. Tran, J. Szanyi, C. H. F. Peden, J. H. Lee, Catal. Lett. 2012, 142, 295–301.
- 14A. Grossale, I. Nova, E. Tronconi, D. Chatterjee, M. Weibel, J. Catal. 2008, 256, 312–332.
- 15H. Zhu, J. H. Kwak, C. H. F. Peden, J. Szanyi, Catal. Today 2013, 205, 16–23.
- 16J. Szanyi, J. H. Kwak, H. Zhu, C. H. F. Peden, Phys. Chem. Chem. Phys. 2013, 15, 2368–2380.
- 17F. Gao, E. D. Walker, E. M. Karp, J. Y. Luo, R. G. Tonkyn, J. H. Kwak, J. Szanyi, C. H. F. Peden, J. Catal. 2013, 300, 20–29.
- 18J. H. Kwak, H. Y. Zhu, C. H. F. Peden, J. Szanyi, Chem. Commun. 2012, 48, 4758–4760.
- 19D. W. Fickel, R. F. Lobo, J. Phys. Chem. C 2010, 114, 1633–1640.
- 20M. Valiev, E. J. Bylaska, N. Govind, K. Kowalski, T. P. Straatsma, H. J. J. Van Dam, D. Wang, J. Nieplocha, E. Apra, T. L. Windus, W. de Jong, Comput. Phys. Commun. 2010, 181, 1477–1489.
- 21A. D. Becke, J. Chem. Phys. 1993, 98, 5648–5651.
- 22A. Schäfer, H. Horn, R. Ahlrichs, J. Chem. Phys. 1992, 97, 2571–2574.
- 23J.-S. McEwen, T. Anggara, W. F. Schneider, V. F. Kispersky, J. T. Miller, W. N. Delgass, F. H. Ribeiro, Catal. Today 2012, 184, 129–144.
- 24M. Bak, J. T. Rasmussen, N. C. Nielsen, J. Magn. Reson. 2000, 147, 296–330.
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