Kinetics of the Fischer–Tropsch Reaction†
Corresponding Author
Dr. Albert J. Markvoort
Institute for Complex Molecular Systems, Department of Biomedical Engineering, Eindhoven University of Technology, PO Box 513, 5600 MB, Eindhoven (The Netherlands)
Institute for Complex Molecular Systems, Department of Biomedical Engineering, Eindhoven University of Technology, PO Box 513, 5600 MB, Eindhoven (The Netherlands)Search for more papers by this authorProf. Dr. Rutger A. van Santen
Institute for Complex Molecular Systems, Eindhoven University of Technology, PO Box 513, 5600 MB, Eindhoven (The Netherlands)
Search for more papers by this authorProf. Dr. Peter A. J. Hilbers
Institute for Complex Molecular Systems, Department of Biomedical Engineering, Eindhoven University of Technology, PO Box 513, 5600 MB, Eindhoven (The Netherlands)
Search for more papers by this authorProf. Dr. Emiel J. M. Hensen
Institute for Complex Molecular Systems, Eindhoven University of Technology, PO Box 513, 5600 MB, Eindhoven (The Netherlands)
Search for more papers by this authorCorresponding Author
Dr. Albert J. Markvoort
Institute for Complex Molecular Systems, Department of Biomedical Engineering, Eindhoven University of Technology, PO Box 513, 5600 MB, Eindhoven (The Netherlands)
Institute for Complex Molecular Systems, Department of Biomedical Engineering, Eindhoven University of Technology, PO Box 513, 5600 MB, Eindhoven (The Netherlands)Search for more papers by this authorProf. Dr. Rutger A. van Santen
Institute for Complex Molecular Systems, Eindhoven University of Technology, PO Box 513, 5600 MB, Eindhoven (The Netherlands)
Search for more papers by this authorProf. Dr. Peter A. J. Hilbers
Institute for Complex Molecular Systems, Department of Biomedical Engineering, Eindhoven University of Technology, PO Box 513, 5600 MB, Eindhoven (The Netherlands)
Search for more papers by this authorProf. Dr. Emiel J. M. Hensen
Institute for Complex Molecular Systems, Eindhoven University of Technology, PO Box 513, 5600 MB, Eindhoven (The Netherlands)
Search for more papers by this authorWe thank Mark Peletier and Huub ten Eikelder for useful discussions on the mathematics of reversible chain growth partial differential equations.
Graphical Abstract
Lange Kohlenstoffketten: Monomere Kohlenstoff-Zwischenstufen, die sich zu langkettigen Kohlenwasserstoffen (siehe Bild) selbstorganisieren, wurden auf katalytisch aktiven Oberflächen bei vollständig reversiblem Kettenwachstum kinetisch untersucht. Mithilfe von Brønsted-Evans-Polanyi-Beziehungen kann das maximale Kettenwachstum als Funktion der Oberflächenreaktivität vorhergesagt werden.
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