Dehydrogenation of Diamine–Monoboranes to Cyclic Diaminoboranes: Efficient Ruthenium-Catalyzed Dehydrogenative Cyclization†
Dr. Christopher J. Wallis
CNRS, LCC (Laboratoire de Chimie de Coordination), 205 route de Narbonne, 31077 Toulouse (France) and Université de Toulouse, UPS, INPT, 31077 Toulouse (France) http://www.lcc-toulouse.fr/lcc/spip.php?article434
Search for more papers by this authorDr. Hellen Dyer
CNRS, LCC (Laboratoire de Chimie de Coordination), 205 route de Narbonne, 31077 Toulouse (France) and Université de Toulouse, UPS, INPT, 31077 Toulouse (France) http://www.lcc-toulouse.fr/lcc/spip.php?article434
Search for more papers by this authorDr. Laure Vendier
CNRS, LCC (Laboratoire de Chimie de Coordination), 205 route de Narbonne, 31077 Toulouse (France) and Université de Toulouse, UPS, INPT, 31077 Toulouse (France) http://www.lcc-toulouse.fr/lcc/spip.php?article434
Search for more papers by this authorCorresponding Author
Dr. Gilles Alcaraz
CNRS, LCC (Laboratoire de Chimie de Coordination), 205 route de Narbonne, 31077 Toulouse (France) and Université de Toulouse, UPS, INPT, 31077 Toulouse (France) http://www.lcc-toulouse.fr/lcc/spip.php?article434
CNRS, LCC (Laboratoire de Chimie de Coordination), 205 route de Narbonne, 31077 Toulouse (France) and Université de Toulouse, UPS, INPT, 31077 Toulouse (France) http://www.lcc-toulouse.fr/lcc/spip.php?article434Search for more papers by this authorCorresponding Author
Dr. Sylviane Sabo-Etienne
CNRS, LCC (Laboratoire de Chimie de Coordination), 205 route de Narbonne, 31077 Toulouse (France) and Université de Toulouse, UPS, INPT, 31077 Toulouse (France) http://www.lcc-toulouse.fr/lcc/spip.php?article434
CNRS, LCC (Laboratoire de Chimie de Coordination), 205 route de Narbonne, 31077 Toulouse (France) and Université de Toulouse, UPS, INPT, 31077 Toulouse (France) http://www.lcc-toulouse.fr/lcc/spip.php?article434Search for more papers by this authorDr. Christopher J. Wallis
CNRS, LCC (Laboratoire de Chimie de Coordination), 205 route de Narbonne, 31077 Toulouse (France) and Université de Toulouse, UPS, INPT, 31077 Toulouse (France) http://www.lcc-toulouse.fr/lcc/spip.php?article434
Search for more papers by this authorDr. Hellen Dyer
CNRS, LCC (Laboratoire de Chimie de Coordination), 205 route de Narbonne, 31077 Toulouse (France) and Université de Toulouse, UPS, INPT, 31077 Toulouse (France) http://www.lcc-toulouse.fr/lcc/spip.php?article434
Search for more papers by this authorDr. Laure Vendier
CNRS, LCC (Laboratoire de Chimie de Coordination), 205 route de Narbonne, 31077 Toulouse (France) and Université de Toulouse, UPS, INPT, 31077 Toulouse (France) http://www.lcc-toulouse.fr/lcc/spip.php?article434
Search for more papers by this authorCorresponding Author
Dr. Gilles Alcaraz
CNRS, LCC (Laboratoire de Chimie de Coordination), 205 route de Narbonne, 31077 Toulouse (France) and Université de Toulouse, UPS, INPT, 31077 Toulouse (France) http://www.lcc-toulouse.fr/lcc/spip.php?article434
CNRS, LCC (Laboratoire de Chimie de Coordination), 205 route de Narbonne, 31077 Toulouse (France) and Université de Toulouse, UPS, INPT, 31077 Toulouse (France) http://www.lcc-toulouse.fr/lcc/spip.php?article434Search for more papers by this authorCorresponding Author
Dr. Sylviane Sabo-Etienne
CNRS, LCC (Laboratoire de Chimie de Coordination), 205 route de Narbonne, 31077 Toulouse (France) and Université de Toulouse, UPS, INPT, 31077 Toulouse (France) http://www.lcc-toulouse.fr/lcc/spip.php?article434
CNRS, LCC (Laboratoire de Chimie de Coordination), 205 route de Narbonne, 31077 Toulouse (France) and Université de Toulouse, UPS, INPT, 31077 Toulouse (France) http://www.lcc-toulouse.fr/lcc/spip.php?article434Search for more papers by this authorWe thank the CNRS and the ANR for support through the HyBoCat ANR-09-BLAN-0184 program. Johnson Matthey is gratefully acknowledged for a generous loan of RuCl3 nH2O.
Graphical Abstract
Ferngesteuert: Als Titelreaktion wird die erste katalytische dehydrierende Cyclisierung (CDC) von Diamin-Monoboranen zur Bildung cyclischer Diaminoborane vorgestellt. Die Cyclisierung hängt stark vom Substitutionsmuster der entfernt stehenden Aminogruppe ab.
Supporting Information
Detailed facts of importance to specialist readers are published as ”Supporting Information”. Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors.
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