Borane-Mediated Carbon Dioxide Reduction at Ruthenium: Formation of C1 and C2 Compounds†
Dr. Sébastien Bontemps
CNRS, LCC (Laboratoire de Chimie de Coordination), 205 route de Narbonne, 31077 Toulouse (France) http://www.lcc-toulouse.fr/lcc/spip.php?article433
Université de Toulouse, UPS, INPT, 31077 Toulouse (France)
Search for more papers by this authorDr. Laure Vendier
CNRS, LCC (Laboratoire de Chimie de Coordination), 205 route de Narbonne, 31077 Toulouse (France) http://www.lcc-toulouse.fr/lcc/spip.php?article433
Université de Toulouse, UPS, INPT, 31077 Toulouse (France)
Search for more papers by this authorCorresponding Author
Dr. Sylviane Sabo-Etienne
CNRS, LCC (Laboratoire de Chimie de Coordination), 205 route de Narbonne, 31077 Toulouse (France) http://www.lcc-toulouse.fr/lcc/spip.php?article433
Université de Toulouse, UPS, INPT, 31077 Toulouse (France)
CNRS, LCC (Laboratoire de Chimie de Coordination), 205 route de Narbonne, 31077 Toulouse (France) http://www.lcc-toulouse.fr/lcc/spip.php?article433Search for more papers by this authorDr. Sébastien Bontemps
CNRS, LCC (Laboratoire de Chimie de Coordination), 205 route de Narbonne, 31077 Toulouse (France) http://www.lcc-toulouse.fr/lcc/spip.php?article433
Université de Toulouse, UPS, INPT, 31077 Toulouse (France)
Search for more papers by this authorDr. Laure Vendier
CNRS, LCC (Laboratoire de Chimie de Coordination), 205 route de Narbonne, 31077 Toulouse (France) http://www.lcc-toulouse.fr/lcc/spip.php?article433
Université de Toulouse, UPS, INPT, 31077 Toulouse (France)
Search for more papers by this authorCorresponding Author
Dr. Sylviane Sabo-Etienne
CNRS, LCC (Laboratoire de Chimie de Coordination), 205 route de Narbonne, 31077 Toulouse (France) http://www.lcc-toulouse.fr/lcc/spip.php?article433
Université de Toulouse, UPS, INPT, 31077 Toulouse (France)
CNRS, LCC (Laboratoire de Chimie de Coordination), 205 route de Narbonne, 31077 Toulouse (France) http://www.lcc-toulouse.fr/lcc/spip.php?article433Search for more papers by this authorWe thank the ANR (Programme blanc “HyBoCat” ANR-09-BLAN-0184), the CNRS for support, and Johnson Matthey plc for the generous gift of hydrated ruthenium trichloride.
Graphical Abstract
Eins und zwei: Die C2-Verbindung pinBOCH2OCHO (siehe Schema, HBpin=Pinakolboran) und mehrere C1-Verbindungen werden bei der boranvermittelten CO2-Reduktion mit der Katalysatorvorstufe [RuH2(H2)2(PCy3)2] unter milden Bedingungen erhalten. Mechanistische Studien decken die Rolle verschiedener neuer Carbonylruthenium-Komplexe auf, die mit Mehrkern-NMR-Spektroskopie, IR-Spektroskopie und Röntgenstrukturanalyse charakterisiert wurden.
Supporting Information
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