Actuation of Asymmetric Cyclopropanation Catalysts: Reversible Single-Crystal to Single-Crystal Reduction of Metal–Organic Frameworks†
Joseph M. Falkowski
Department of Chemistry, CB#3290, University of North Carolina, Chapel Hill, NC 27599 (USA) http://www.chem.unc.edu/people/faculty/linw/wlindex.html
Search for more papers by this authorCheng Wang
Department of Chemistry, CB#3290, University of North Carolina, Chapel Hill, NC 27599 (USA) http://www.chem.unc.edu/people/faculty/linw/wlindex.html
Search for more papers by this authorSophie Liu
Department of Chemistry, CB#3290, University of North Carolina, Chapel Hill, NC 27599 (USA) http://www.chem.unc.edu/people/faculty/linw/wlindex.html
Search for more papers by this authorCorresponding Author
Prof. Wenbin Lin
Department of Chemistry, CB#3290, University of North Carolina, Chapel Hill, NC 27599 (USA) http://www.chem.unc.edu/people/faculty/linw/wlindex.html
Department of Chemistry, CB#3290, University of North Carolina, Chapel Hill, NC 27599 (USA) http://www.chem.unc.edu/people/faculty/linw/wlindex.htmlSearch for more papers by this authorJoseph M. Falkowski
Department of Chemistry, CB#3290, University of North Carolina, Chapel Hill, NC 27599 (USA) http://www.chem.unc.edu/people/faculty/linw/wlindex.html
Search for more papers by this authorCheng Wang
Department of Chemistry, CB#3290, University of North Carolina, Chapel Hill, NC 27599 (USA) http://www.chem.unc.edu/people/faculty/linw/wlindex.html
Search for more papers by this authorSophie Liu
Department of Chemistry, CB#3290, University of North Carolina, Chapel Hill, NC 27599 (USA) http://www.chem.unc.edu/people/faculty/linw/wlindex.html
Search for more papers by this authorCorresponding Author
Prof. Wenbin Lin
Department of Chemistry, CB#3290, University of North Carolina, Chapel Hill, NC 27599 (USA) http://www.chem.unc.edu/people/faculty/linw/wlindex.html
Department of Chemistry, CB#3290, University of North Carolina, Chapel Hill, NC 27599 (USA) http://www.chem.unc.edu/people/faculty/linw/wlindex.htmlSearch for more papers by this authorWe thank the NSF (CHE-0809776) for financial support, and Kathryn DeKrafft and Rachel Huxford for experimental help. J.M.F. is supported by a DOE Office of Science graduate fellowship under the DOE contract number DE-AC05-06OR23100. C.W. acknowledges the UNC Department of Chemistry for an Ernest L. Eliel Fellowship. S.L. is supported by a UNC William W. and Ida W. Taylor Fellowship.
Graphical Abstract
Nur reduziert aktiv: Chirale Metall-organische Gerüste (CMOFs) mit redoxaktiven Ruthenium-Salen-Bausteinen gehen eine reversible Reduktion und Oxidation im Einkristall ein. Nicht katalytisch aktive RuIII-CMOFs (grün) wurden zu RuII-CMOFs (rot) reduziert, die hoch diastereo- und enantioselektive Cyclopropanierungen von Alkenen vermitteln.
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