Developing Synthetic Approaches with Non-Innocent Metalloligands: Easy Access to IrI/Pd0 and IrI/Pd0/IrI Cores†
Corresponding Author
Dr. Cristina Tejel
Instituto de Síntesis Química y Catálisis Homogénea (ISQCH), CSIC—Universidad de Zaragoza, Pedro Cerbuna 12, 50009-Zaragoza (Spain)
Instituto de Síntesis Química y Catálisis Homogénea (ISQCH), CSIC—Universidad de Zaragoza, Pedro Cerbuna 12, 50009-Zaragoza (Spain)Search for more papers by this authorLaura Asensio
Instituto de Síntesis Química y Catálisis Homogénea (ISQCH), CSIC—Universidad de Zaragoza, Pedro Cerbuna 12, 50009-Zaragoza (Spain)
Search for more papers by this authorDr. M. Pilar del Río
Instituto de Síntesis Química y Catálisis Homogénea (ISQCH), CSIC—Universidad de Zaragoza, Pedro Cerbuna 12, 50009-Zaragoza (Spain)
Search for more papers by this authorDr. Bas de Bruin
Van't Hoff Institute for Molecular Sciences (HIMS), University of Amsterdam (UvA), Science Park 904, 1098 XH Amsterdam (The Netherlands)
Search for more papers by this authorDr. José A. López
Instituto de Síntesis Química y Catálisis Homogénea (ISQCH), CSIC—Universidad de Zaragoza, Pedro Cerbuna 12, 50009-Zaragoza (Spain)
Search for more papers by this authorProf. Dr. Miguel A. Ciriano
Instituto de Síntesis Química y Catálisis Homogénea (ISQCH), CSIC—Universidad de Zaragoza, Pedro Cerbuna 12, 50009-Zaragoza (Spain)
Search for more papers by this authorCorresponding Author
Dr. Cristina Tejel
Instituto de Síntesis Química y Catálisis Homogénea (ISQCH), CSIC—Universidad de Zaragoza, Pedro Cerbuna 12, 50009-Zaragoza (Spain)
Instituto de Síntesis Química y Catálisis Homogénea (ISQCH), CSIC—Universidad de Zaragoza, Pedro Cerbuna 12, 50009-Zaragoza (Spain)Search for more papers by this authorLaura Asensio
Instituto de Síntesis Química y Catálisis Homogénea (ISQCH), CSIC—Universidad de Zaragoza, Pedro Cerbuna 12, 50009-Zaragoza (Spain)
Search for more papers by this authorDr. M. Pilar del Río
Instituto de Síntesis Química y Catálisis Homogénea (ISQCH), CSIC—Universidad de Zaragoza, Pedro Cerbuna 12, 50009-Zaragoza (Spain)
Search for more papers by this authorDr. Bas de Bruin
Van't Hoff Institute for Molecular Sciences (HIMS), University of Amsterdam (UvA), Science Park 904, 1098 XH Amsterdam (The Netherlands)
Search for more papers by this authorDr. José A. López
Instituto de Síntesis Química y Catálisis Homogénea (ISQCH), CSIC—Universidad de Zaragoza, Pedro Cerbuna 12, 50009-Zaragoza (Spain)
Search for more papers by this authorProf. Dr. Miguel A. Ciriano
Instituto de Síntesis Química y Catálisis Homogénea (ISQCH), CSIC—Universidad de Zaragoza, Pedro Cerbuna 12, 50009-Zaragoza (Spain)
Search for more papers by this authorThe generous financial support from MICINN/FEDER (Project CTQ2008-03860) and Gobierno de Aragón (GA, Project: PI 155/08) is gratefully acknowledged. L.A. and P.R. thank MICINN/FEDER for a fellowship and a post-doctoral contract, respectively.
Graphical Abstract
Schuldig der Anklage, so lautet das Urteil für den anionischen Iridium-Komplex [Ir(bpa−2 H)(cod)]− in Reaktionen mit Palladium(II)-Verbindungen. Der Transfer von zwei Elektronen vom Ir-Komplex zu Pd ermöglicht die einfache Herstellung von zwei- und dreikernigen π-Imin-koordinierten Pd0-Verbindungen wie [{Ir(PyCH2NCHPy)(cod)}2Pd] (siehe Bild; C weiß, Ir rot, N blau, Pd gelb). bpa−2 H: doppelt deprotoniertes N,N-Bis(2-picolyl)amin (bpa); cod: 1,5-Cyclooctadien.
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