Multicomponent Self-Assembly of a Nested Co24@Co48 Metal–Organic Polyhedral Framework†
Dr. Shou-Tian Zheng
Department of Chemistry and Biochemistry, California State University, Long Beach, CA 90840 (USA)
Search for more papers by this authorTao Wu
Department of Chemistry, University of California, Riverside, CA 92521 (USA)
Search for more papers by this authorBurcin Irfanoglu
Department of Chemistry and Biochemistry, California State University, Long Beach, CA 90840 (USA)
Search for more papers by this authorFan Zuo
Department of Chemistry, University of California, Riverside, CA 92521 (USA)
Search for more papers by this authorCorresponding Author
Prof. Dr. Pingyun Feng
Department of Chemistry, University of California, Riverside, CA 92521 (USA)
Pingyun Feng, Department of Chemistry, University of California, Riverside, CA 92521 (USA)
Xianhui Bu, Department of Chemistry and Biochemistry, California State University, Long Beach, CA 90840 (USA)
Search for more papers by this authorCorresponding Author
Prof. Dr. Xianhui Bu
Department of Chemistry and Biochemistry, California State University, Long Beach, CA 90840 (USA)
Pingyun Feng, Department of Chemistry, University of California, Riverside, CA 92521 (USA)
Xianhui Bu, Department of Chemistry and Biochemistry, California State University, Long Beach, CA 90840 (USA)
Search for more papers by this authorDr. Shou-Tian Zheng
Department of Chemistry and Biochemistry, California State University, Long Beach, CA 90840 (USA)
Search for more papers by this authorTao Wu
Department of Chemistry, University of California, Riverside, CA 92521 (USA)
Search for more papers by this authorBurcin Irfanoglu
Department of Chemistry and Biochemistry, California State University, Long Beach, CA 90840 (USA)
Search for more papers by this authorFan Zuo
Department of Chemistry, University of California, Riverside, CA 92521 (USA)
Search for more papers by this authorCorresponding Author
Prof. Dr. Pingyun Feng
Department of Chemistry, University of California, Riverside, CA 92521 (USA)
Pingyun Feng, Department of Chemistry, University of California, Riverside, CA 92521 (USA)
Xianhui Bu, Department of Chemistry and Biochemistry, California State University, Long Beach, CA 90840 (USA)
Search for more papers by this authorCorresponding Author
Prof. Dr. Xianhui Bu
Department of Chemistry and Biochemistry, California State University, Long Beach, CA 90840 (USA)
Pingyun Feng, Department of Chemistry, University of California, Riverside, CA 92521 (USA)
Xianhui Bu, Department of Chemistry and Biochemistry, California State University, Long Beach, CA 90840 (USA)
Search for more papers by this authorThis work was supported by the Department of Energy-Basic Energy Sciences under Contract No. DE-SC0002235 (P.F.) and by NSF (X.B. DMR-0846958).
Graphical Abstract
Zwei archimedische Polyeder, ein Rhombikuboktaeder (Co48) und ein Kuboktaeder (Co24), werden in einem Metall-organischen Gerüst aus zwei Dicobalteinheiten und zwei komplementären Liganden aufgebaut. Die Co24-Käfige sind in den Co48-Käfigen des kubischen kovalenten Gerüsts verkapselt und untereinander zu einem „versteckten“ 3D-Gerüst verknüpft.
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