Generation of Melamine Polymer Condensates upon Hypergolic Ignition of Dicyanamide Ionic Liquids†
Dr. Konstantin Chingin
Department of Chemistry, Stanford University, 333 Campus Drive, Stanford, CA 94305-5080 (USA)
Search for more papers by this authorDr. Richard H. Perry
Department of Chemistry, Stanford University, 333 Campus Drive, Stanford, CA 94305-5080 (USA)
Search for more papers by this authorDr. Steven D. Chambreau
Air Force Research Laboratory, AFRL/RZSP, Edwards Air Force Base, 10 East Saturn Boulevard, CA 93524 (USA)
Search for more papers by this authorDr. Ghanshyam L. Vaghjiani
Air Force Research Laboratory, AFRL/RZSP, Edwards Air Force Base, 10 East Saturn Boulevard, CA 93524 (USA)
Search for more papers by this authorCorresponding Author
Prof. Richard N. Zare
Department of Chemistry, Stanford University, 333 Campus Drive, Stanford, CA 94305-5080 (USA)
Department of Chemistry, Stanford University, 333 Campus Drive, Stanford, CA 94305-5080 (USA)Search for more papers by this authorDr. Konstantin Chingin
Department of Chemistry, Stanford University, 333 Campus Drive, Stanford, CA 94305-5080 (USA)
Search for more papers by this authorDr. Richard H. Perry
Department of Chemistry, Stanford University, 333 Campus Drive, Stanford, CA 94305-5080 (USA)
Search for more papers by this authorDr. Steven D. Chambreau
Air Force Research Laboratory, AFRL/RZSP, Edwards Air Force Base, 10 East Saturn Boulevard, CA 93524 (USA)
Search for more papers by this authorDr. Ghanshyam L. Vaghjiani
Air Force Research Laboratory, AFRL/RZSP, Edwards Air Force Base, 10 East Saturn Boulevard, CA 93524 (USA)
Search for more papers by this authorCorresponding Author
Prof. Richard N. Zare
Department of Chemistry, Stanford University, 333 Campus Drive, Stanford, CA 94305-5080 (USA)
Department of Chemistry, Stanford University, 333 Campus Drive, Stanford, CA 94305-5080 (USA)Search for more papers by this authorThis work has been supported by the Air Force Office of Scientific Research (AFOSR: FA 9550-10-1-0235) and the Center for Molecular Analysis and Design at Stanford University (CMAD: 1123893-1-AABGE). K.C. acknowledges financial help from the Swiss National Science Foundation (PBEZP2-133126). We thank Prof. Wolfgang Schnick (LMU Munich) and Dr. Joseph Mabry (AFRL, Edwards Air Force Base) for helpful discussions on nitride chemistry. We also thank Dr. Pavel Aronov and Dr. Allis Chien (Stanford University Mass Spectrometry) for providing instrumentation and their expertise in the field of mass spectrometry. Dr. Jun Ge (Stanford University) is acknowledged for his help with SEM measurements.
Graphical Abstract
Die Reaktion von ionischen Flüssigkeiten mit Dicyanamid-Ionen mit Salpetersäure hat eine hypergole Zündung und die Bildung eines stabilen Niederschlags zur Folge. Dieser besteht aus cyclischen Triazinen, darunter Melamin und seine Polymere wie Melam und Melem (siehe Schema). Diese Studie führt einen neuen Syntheseansatz für cyclische Azine ein, der hohe Temperaturen und Drücke umgeht.
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