Eintopfsynthese von Menthol in Gegenwart eines hoch diastereoselektiven Au/MgF2-Katalysators†
Dipl.-Chem. Alina Negoi
Department of Chemical Technology and Catalysis, Faculty of Chemistry, University of Bucharest, Bdul Regina Elisabeta 4–12, 030016 Bukarest (Rumänien), Fax: (+40) 214-100-241
Search for more papers by this authorDr. Stefan Wuttke
Institut für Chemie, Humboldt-Universität zu Berlin, Brook-Taylor-Straße 2, 12489 Berlin (Deutschland), Fax: (+49) 30-2093-7468
Search for more papers by this authorProf. Dr. Erhard Kemnitz
Institut für Chemie, Humboldt-Universität zu Berlin, Brook-Taylor-Straße 2, 12489 Berlin (Deutschland), Fax: (+49) 30-2093-7468
Search for more papers by this authorDr. Dan Macovei
National Institute of Materials Physics, Bukarest (Rumänien)
Search for more papers by this authorProf. Dr. Vasile I. Parvulescu
Department of Chemical Technology and Catalysis, Faculty of Chemistry, University of Bucharest, Bdul Regina Elisabeta 4–12, 030016 Bukarest (Rumänien), Fax: (+40) 214-100-241
Search for more papers by this authorDr. C. M. Teodorescu
National Institute of Materials Physics, Bukarest (Rumänien)
Search for more papers by this authorProf. Dr. Simona M. Coman
Department of Chemical Technology and Catalysis, Faculty of Chemistry, University of Bucharest, Bdul Regina Elisabeta 4–12, 030016 Bukarest (Rumänien), Fax: (+40) 214-100-241
Search for more papers by this authorDipl.-Chem. Alina Negoi
Department of Chemical Technology and Catalysis, Faculty of Chemistry, University of Bucharest, Bdul Regina Elisabeta 4–12, 030016 Bukarest (Rumänien), Fax: (+40) 214-100-241
Search for more papers by this authorDr. Stefan Wuttke
Institut für Chemie, Humboldt-Universität zu Berlin, Brook-Taylor-Straße 2, 12489 Berlin (Deutschland), Fax: (+49) 30-2093-7468
Search for more papers by this authorProf. Dr. Erhard Kemnitz
Institut für Chemie, Humboldt-Universität zu Berlin, Brook-Taylor-Straße 2, 12489 Berlin (Deutschland), Fax: (+49) 30-2093-7468
Search for more papers by this authorDr. Dan Macovei
National Institute of Materials Physics, Bukarest (Rumänien)
Search for more papers by this authorProf. Dr. Vasile I. Parvulescu
Department of Chemical Technology and Catalysis, Faculty of Chemistry, University of Bucharest, Bdul Regina Elisabeta 4–12, 030016 Bukarest (Rumänien), Fax: (+40) 214-100-241
Search for more papers by this authorDr. C. M. Teodorescu
National Institute of Materials Physics, Bukarest (Rumänien)
Search for more papers by this authorProf. Dr. Simona M. Coman
Department of Chemical Technology and Catalysis, Faculty of Chemistry, University of Bucharest, Bdul Regina Elisabeta 4–12, 030016 Bukarest (Rumänien), Fax: (+40) 214-100-241
Search for more papers by this authorDie Autoren danken CNCSIS (PNCDI II 40/2007) für die finanzielle Unterstützung.
Graphical Abstract
Ohne hochtoxische Verbindungen wie KCN und eine thermische Nachbehandlung wurden Au/MgF2-Komplexe durch eine einfache simultane Nassimprägnierung mit Tetrachlorogoldsäure als Goldvorstufe zugänglich. Einer der so erhaltenen Komplexe weist einzigartige katalytische Eigenschaften auf und ermöglichte die heterogen katalysierte hoch diastereoselektive Eintopfreaktion von Citronellal zu (±)-Menthol (siehe Bild).
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