Ruthenium Bis(σ-BH) Aminoborane Complexes from Dehydrogenation of Amine–Boranes: Trapping of H2BNH2†
Gilles Alcaraz Dr.
CNRS, LCC (Laboratoire de Chimie de Coordination), 205 route de Narbonne, 31077 Toulouse (France) http://www.lcc-toulouse.fr/lcc/spip.php?article434
Université de Toulouse, UPS, INPT, 31077 Toulouse (France), Fax: (+33) 5-6155-3003
Search for more papers by this authorLaure Vendier Dr.
CNRS, LCC (Laboratoire de Chimie de Coordination), 205 route de Narbonne, 31077 Toulouse (France) http://www.lcc-toulouse.fr/lcc/spip.php?article434
Université de Toulouse, UPS, INPT, 31077 Toulouse (France), Fax: (+33) 5-6155-3003
Search for more papers by this authorEric Clot Dr.
Institut Charles Gerhardt, Université Montpellier 2, CNRS 5253 cc 1501 Place Eugène Bataillon, 34095 Montpellier (France)
Search for more papers by this authorSylviane Sabo-Etienne Dr.
CNRS, LCC (Laboratoire de Chimie de Coordination), 205 route de Narbonne, 31077 Toulouse (France) http://www.lcc-toulouse.fr/lcc/spip.php?article434
Université de Toulouse, UPS, INPT, 31077 Toulouse (France), Fax: (+33) 5-6155-3003
Search for more papers by this authorGilles Alcaraz Dr.
CNRS, LCC (Laboratoire de Chimie de Coordination), 205 route de Narbonne, 31077 Toulouse (France) http://www.lcc-toulouse.fr/lcc/spip.php?article434
Université de Toulouse, UPS, INPT, 31077 Toulouse (France), Fax: (+33) 5-6155-3003
Search for more papers by this authorLaure Vendier Dr.
CNRS, LCC (Laboratoire de Chimie de Coordination), 205 route de Narbonne, 31077 Toulouse (France) http://www.lcc-toulouse.fr/lcc/spip.php?article434
Université de Toulouse, UPS, INPT, 31077 Toulouse (France), Fax: (+33) 5-6155-3003
Search for more papers by this authorEric Clot Dr.
Institut Charles Gerhardt, Université Montpellier 2, CNRS 5253 cc 1501 Place Eugène Bataillon, 34095 Montpellier (France)
Search for more papers by this authorSylviane Sabo-Etienne Dr.
CNRS, LCC (Laboratoire de Chimie de Coordination), 205 route de Narbonne, 31077 Toulouse (France) http://www.lcc-toulouse.fr/lcc/spip.php?article434
Université de Toulouse, UPS, INPT, 31077 Toulouse (France), Fax: (+33) 5-6155-3003
Search for more papers by this authorWe thank the CNRS and the ANR (programme blanc ANR HyBoCat 2009) for support.
Graphical Abstract
Ein kleiner Schritt für Ammoniak-Boran: Die einfachste Aminoboranverbindung H2BNH2, die bei der Dehydrierung von Ammoniak-Boran entsteht, wurde mit einem Rutheniumkomplexfragment in Form eines Bis(σ-BH)-Aminoborankomplexes abgefangen. Auch die analogen Komplexe mit H2BNHMe und H2BNMe2 wurden synthetisiert. (Bild: Rutheniumkomplex; Ru violett, P orange, N blau, B braun, H weiß.)
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