Phosphinoborane and Sulfidoborohydride as Chelating Ligands in Polyhydride Ruthenium Complexes: Agostic σ-Borane versus Dihydroborate Coordination†
Yann Gloaguen
CNRS, LCC (Laboratoire de Chimie de Coordination), 205 route de Narbonne, 31077 Toulouse (France) http://www.lcc-toulouse.fr/lcc/spip.php?article433
Université de Toulouse, UPS, INPT, 31077 Toulouse (France)
Search for more papers by this authorGilles Alcaraz Dr.
CNRS, LCC (Laboratoire de Chimie de Coordination), 205 route de Narbonne, 31077 Toulouse (France) http://www.lcc-toulouse.fr/lcc/spip.php?article433
Université de Toulouse, UPS, INPT, 31077 Toulouse (France)
Search for more papers by this authorAnne-Frédérique Pécharman
CNRS, LCC (Laboratoire de Chimie de Coordination), 205 route de Narbonne, 31077 Toulouse (France) http://www.lcc-toulouse.fr/lcc/spip.php?article433
Université de Toulouse, UPS, INPT, 31077 Toulouse (France)
Search for more papers by this authorEric Clot Dr.
Université Montpellier 2, Institut Charles Gerhardt, CNRS 5253, cc 1501, Place Eugène Bataillon, 34095 Montpellier (France)
Search for more papers by this authorLaure Vendier Dr.
CNRS, LCC (Laboratoire de Chimie de Coordination), 205 route de Narbonne, 31077 Toulouse (France) http://www.lcc-toulouse.fr/lcc/spip.php?article433
Université de Toulouse, UPS, INPT, 31077 Toulouse (France)
Search for more papers by this authorSylviane Sabo-Etienne Dr.
CNRS, LCC (Laboratoire de Chimie de Coordination), 205 route de Narbonne, 31077 Toulouse (France) http://www.lcc-toulouse.fr/lcc/spip.php?article433
Université de Toulouse, UPS, INPT, 31077 Toulouse (France)
Search for more papers by this authorYann Gloaguen
CNRS, LCC (Laboratoire de Chimie de Coordination), 205 route de Narbonne, 31077 Toulouse (France) http://www.lcc-toulouse.fr/lcc/spip.php?article433
Université de Toulouse, UPS, INPT, 31077 Toulouse (France)
Search for more papers by this authorGilles Alcaraz Dr.
CNRS, LCC (Laboratoire de Chimie de Coordination), 205 route de Narbonne, 31077 Toulouse (France) http://www.lcc-toulouse.fr/lcc/spip.php?article433
Université de Toulouse, UPS, INPT, 31077 Toulouse (France)
Search for more papers by this authorAnne-Frédérique Pécharman
CNRS, LCC (Laboratoire de Chimie de Coordination), 205 route de Narbonne, 31077 Toulouse (France) http://www.lcc-toulouse.fr/lcc/spip.php?article433
Université de Toulouse, UPS, INPT, 31077 Toulouse (France)
Search for more papers by this authorEric Clot Dr.
Université Montpellier 2, Institut Charles Gerhardt, CNRS 5253, cc 1501, Place Eugène Bataillon, 34095 Montpellier (France)
Search for more papers by this authorLaure Vendier Dr.
CNRS, LCC (Laboratoire de Chimie de Coordination), 205 route de Narbonne, 31077 Toulouse (France) http://www.lcc-toulouse.fr/lcc/spip.php?article433
Université de Toulouse, UPS, INPT, 31077 Toulouse (France)
Search for more papers by this authorSylviane Sabo-Etienne Dr.
CNRS, LCC (Laboratoire de Chimie de Coordination), 205 route de Narbonne, 31077 Toulouse (France) http://www.lcc-toulouse.fr/lcc/spip.php?article433
Université de Toulouse, UPS, INPT, 31077 Toulouse (France)
Search for more papers by this authorWe thank the CNRS and the ANR (programme blanc ANR-06-BLAN-0060-01) for support (Y.G., G.A., L.V., S.S.E.)
Abstract
Bindung ja, aber wie? Zwei neue Boranverbindungen wirken als difunktionelle Liganden und reagieren mit Rutheniumpolyhydriden zu zwei Arten von Komplexen (siehe Schema): Ein Produkt zeigt eine δ-agostische Wechselwirkung der η2-B-H-Bindung eines dreiwertigen Borzentrums, das andere eine Bindung als Dihydroborat-Ligand.
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