Cobalt Nanocubes in Ionic Liquids: Synthesis and Properties†
Morgana Scariot
Institute of Chemistry and Institute of Physics, UFRGS, Avenida Bento Gonçalves 9500, 91501-970, Porto Alegre, RS (Brazil), Fax: (+55) 5133087304
Search for more papers by this authorDagoberto O. Silva
Institute of Chemistry and Institute of Physics, UFRGS, Avenida Bento Gonçalves 9500, 91501-970, Porto Alegre, RS (Brazil), Fax: (+55) 5133087304
Search for more papers by this authorJackson D. Scholten
Institute of Chemistry and Institute of Physics, UFRGS, Avenida Bento Gonçalves 9500, 91501-970, Porto Alegre, RS (Brazil), Fax: (+55) 5133087304
Search for more papers by this authorGiovanna Machado Prof.
Departamento de Engenharia Química, Universidade de Caxias do Sul (Brazil)
Search for more papers by this authorSérgio R. Teixeira Prof.
Institute of Chemistry and Institute of Physics, UFRGS, Avenida Bento Gonçalves 9500, 91501-970, Porto Alegre, RS (Brazil), Fax: (+55) 5133087304
Search for more papers by this authorMiguel A. Novak Prof.
Institute of Physics, UFRJ, Cidade Universitária, 21941-972, Rio de Janeiro (Brazil)
Search for more papers by this authorGünter Ebeling Prof.
Institute of Chemistry and Institute of Physics, UFRGS, Avenida Bento Gonçalves 9500, 91501-970, Porto Alegre, RS (Brazil), Fax: (+55) 5133087304
Search for more papers by this authorJairton Dupont Prof.
Institute of Chemistry and Institute of Physics, UFRGS, Avenida Bento Gonçalves 9500, 91501-970, Porto Alegre, RS (Brazil), Fax: (+55) 5133087304
Search for more papers by this authorMorgana Scariot
Institute of Chemistry and Institute of Physics, UFRGS, Avenida Bento Gonçalves 9500, 91501-970, Porto Alegre, RS (Brazil), Fax: (+55) 5133087304
Search for more papers by this authorDagoberto O. Silva
Institute of Chemistry and Institute of Physics, UFRGS, Avenida Bento Gonçalves 9500, 91501-970, Porto Alegre, RS (Brazil), Fax: (+55) 5133087304
Search for more papers by this authorJackson D. Scholten
Institute of Chemistry and Institute of Physics, UFRGS, Avenida Bento Gonçalves 9500, 91501-970, Porto Alegre, RS (Brazil), Fax: (+55) 5133087304
Search for more papers by this authorGiovanna Machado Prof.
Departamento de Engenharia Química, Universidade de Caxias do Sul (Brazil)
Search for more papers by this authorSérgio R. Teixeira Prof.
Institute of Chemistry and Institute of Physics, UFRGS, Avenida Bento Gonçalves 9500, 91501-970, Porto Alegre, RS (Brazil), Fax: (+55) 5133087304
Search for more papers by this authorMiguel A. Novak Prof.
Institute of Physics, UFRJ, Cidade Universitária, 21941-972, Rio de Janeiro (Brazil)
Search for more papers by this authorGünter Ebeling Prof.
Institute of Chemistry and Institute of Physics, UFRGS, Avenida Bento Gonçalves 9500, 91501-970, Porto Alegre, RS (Brazil), Fax: (+55) 5133087304
Search for more papers by this authorJairton Dupont Prof.
Institute of Chemistry and Institute of Physics, UFRGS, Avenida Bento Gonçalves 9500, 91501-970, Porto Alegre, RS (Brazil), Fax: (+55) 5133087304
Search for more papers by this authorWe thank PETROBRAS for financial support.
Graphical Abstract
Würfel und Kugeln: Die einfache thermische Zersetzung von [Co2(CO)8], das in einem flüssigen 1-Alkyl-3-methylimidazoliumsalz dispergiert ist, liefert je nach spezieller Art der ionischen Flüssigkeit und Zersetzungszeit wahlweise ligandenfreie Cobaltnanowürfel oder sphärische Cobaltnanopartikel. Diese Nanostrukturen sind selektive Katalysatoren für die Fischer-Tropsch-Synthese. Tf=Triflat.
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