Magnesium Borohydride Confined in a Metal–Organic Framework: A Preorganized System for Facile Arene Hydroboration†
Michael J. Ingleson Dr.
Department of Chemistry, University of Liverpool, Liverpool, L69 7ZD (UK), Fax: (+44) 151-794-3598
Search for more papers by this authorJorge Perez Barrio
Department of Chemistry, University of Liverpool, Liverpool, L69 7ZD (UK), Fax: (+44) 151-794-3598
Search for more papers by this authorJohn Bacsa Dr.
Department of Chemistry, University of Liverpool, Liverpool, L69 7ZD (UK), Fax: (+44) 151-794-3598
Search for more papers by this authorAlexander Steiner Dr.
Department of Chemistry, University of Liverpool, Liverpool, L69 7ZD (UK), Fax: (+44) 151-794-3598
Search for more papers by this authorGeorge R. Darling Dr.
Department of Chemistry, University of Liverpool, Liverpool, L69 7ZD (UK), Fax: (+44) 151-794-3598
Search for more papers by this authorJames T. A. Jones
Department of Chemistry, University of Liverpool, Liverpool, L69 7ZD (UK), Fax: (+44) 151-794-3598
Search for more papers by this authorYaroslav Z. Khimyak Dr.
Department of Chemistry, University of Liverpool, Liverpool, L69 7ZD (UK), Fax: (+44) 151-794-3598
Search for more papers by this authorMatthew J. Rosseinsky Prof.
Department of Chemistry, University of Liverpool, Liverpool, L69 7ZD (UK), Fax: (+44) 151-794-3598
Search for more papers by this authorMichael J. Ingleson Dr.
Department of Chemistry, University of Liverpool, Liverpool, L69 7ZD (UK), Fax: (+44) 151-794-3598
Search for more papers by this authorJorge Perez Barrio
Department of Chemistry, University of Liverpool, Liverpool, L69 7ZD (UK), Fax: (+44) 151-794-3598
Search for more papers by this authorJohn Bacsa Dr.
Department of Chemistry, University of Liverpool, Liverpool, L69 7ZD (UK), Fax: (+44) 151-794-3598
Search for more papers by this authorAlexander Steiner Dr.
Department of Chemistry, University of Liverpool, Liverpool, L69 7ZD (UK), Fax: (+44) 151-794-3598
Search for more papers by this authorGeorge R. Darling Dr.
Department of Chemistry, University of Liverpool, Liverpool, L69 7ZD (UK), Fax: (+44) 151-794-3598
Search for more papers by this authorJames T. A. Jones
Department of Chemistry, University of Liverpool, Liverpool, L69 7ZD (UK), Fax: (+44) 151-794-3598
Search for more papers by this authorYaroslav Z. Khimyak Dr.
Department of Chemistry, University of Liverpool, Liverpool, L69 7ZD (UK), Fax: (+44) 151-794-3598
Search for more papers by this authorMatthew J. Rosseinsky Prof.
Department of Chemistry, University of Liverpool, Liverpool, L69 7ZD (UK), Fax: (+44) 151-794-3598
Search for more papers by this authorThis work was supported by EPSRC grant number EP/C511794. Dr. D. Bradshaw is thanked for assistance with air-sensitive TGA analysis and Dr. A Ganin with Raman spectroscopy.
Abstract
In nächster Nähe: Anders als unter analogen Bedingungen in homogener Lösung reagiert Magnesiumborhydrid als Teil eines metall-organischen Netzwerks mit Arenen unter Hydroborierung (siehe Schema). Die erforderliche Ausrichtung der reaktiven Gruppen im Netzwerk wird durch Metallkoordination und Diwasserstoffbrücken erzielt.
Supporting Information
Detailed facts of importance to specialist readers are published as ”Supporting Information”. Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors.
| Filename | Description |
|---|---|
| ange_200804196_sm_miscellaneous_information.pdf4.6 MB | miscellaneous_information |
Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.
References
- 1T. Haneda, M. Kawano, T. Kawamichi, M. Fujita, J. Am. Chem. Soc. 2008, 130, 1578.
- 2S. S. Kaye, J. R. Long, J. Am. Chem. Soc. 2008, 130, 806.
- 3M. J. Ingleson, J. P. Barrio, J. Bacsa, C. Dickinson, H. Park, M. J. Rosseinsky, Chem. Commun. 2008, 1287.
- 4F. Schüth, B. Bogdanovic, M. Felderhoff, Chem. Commun. 2004, 2249.
- 5S. Orimo, Y. Nakamori, J. R. Eliseo, A. Zuttel, C. M. Jensen, Chem. Rev. 2007, 107, 4111.
- 6W. Grochala, P. P. Edwards, Chem. Rev. 2004, 104, 1283.
- 7K. Chlopek, C. Frommen, A. Leon, O. Zabara, M. Fichtner, J. Mater. Chem. 2007, 17, 3465.
- 8G. Soloveichik, J.-H. Her, P. W. Stephens, Y. Gao, J. Rijssenbeek, M. Andrus, J.-C. Zhao, Inorg. Chem. 2008, 47, 4290.
- 9R. Custelcean, J. E. Jackson, Chem. Rev. 2001, 101, 1963.
- 10Y. Filinchuk, H. Hagemann, Eur. J. Inorg. Chem. 2008, 3127.
- 11S. J. Grabowski, W. A. Sokalski, J. Leszczynski, J. Phys. Chem. A 2004, 108, 5823.
- 12W. T. Klooster, T. F. Koetzle, P. E. M. Siegbahn, T. B. Richardson, R. H. Crabtree, J. Am. Chem. Soc. 1999, 121, 6337.
- 13P. Lipkowski, S. J. Grabowski, T. L. Robinson, J. Leszczynski, J. Phys. Chem. A 2004, 108, 10865.
- 14C. A. Jaska, A. J. Lough, I. Manners, Inorg. Chem. 2004, 43, 1090.
- 15A. C. Stowe, W. J. Shaw, J. C. Linehan, B. Schmid, T. Autrey, Phys. Chem. Chem. Phys. 2007, 9, 1831.
- 16M. Bremer, H. Noth, M. Warchhold, Eur. J. Inorg. Chem. 2003, 111.
- 17P. Zanella, L. Crociani, N. Masciocchi, G. Giunchi, Inorg. Chem. 2007, 46, 9039.
- 18J.-H. Her, P. W. Stephens, Y. Gao, G. L. Soloveichik, J. Rijssenbeek, M. Andrus, J.-C. Zhao, Acta Crystallogr. Sect. B 2007, 63, 561.
- 19R. Cerny, Y. Filinchuk, H. Hagemann, K. Yvon, Angew. Chem. 2007, 119, 5867;
10.1002/ange.200700773 Google ScholarAngew. Chem. Int. Ed. 2007, 46, 5765.
- 20See the Supporting Information.
- 21T. Ramnial, H. Jong, I. D. McKenzie, M. Jennings, J. A. C. Clyburne, Chem. Commun. 2003, 1722.
- 22M. Guizado-Rodriguez, A. Ariza-Castolo, G. Merion, A. Vela, H. Noth, V. I. Bakhmutov, R. Contreras, J. Am. Chem. Soc. 2001, 123, 9144.
- 23M. E. Bluhm, M. G. Bradley, R. Butterick III, U. Kusari, L. G. Sneddon, J. Am. Chem. Soc. 2006, 128, 7748.
- 24M. S. Eisen, T. J. Marks, J. Am. Chem. Soc. 1992, 114, 10358.
- 25M. Yalpani, T. Lunow, R. Koster, Chem. Ber. 1989, 122, 687.
- 26R. Choukroun, B. Douziech, B. Donnadieu, Organometallics 1997, 16, 5517.
- 27H. Noeth, M. Schmidt, Organometallics 1995, 14, 4601.
- 28C. Villiers, M. Ephritikhine, Tetrahedron Lett. 2003, 44, 8077.
- 29G. W. Gribble, Chem. Soc. Rev. 1998, 27, 295.
- 30R. Köster, W. Schussler, M. Yalpani, Chem. Ber. 1989, 122, 677.
- 31M. Scheideman, P. Shapland, E. Vedejs, J. Am. Chem. Soc. 2003, 125, 10502.
Citing Literature
This is the
German version
of Angewandte Chemie.
Note for articles published since 1962:
Do not cite this version alone.
Take me to the International Edition version with citable page numbers, DOI, and citation export.
We apologize for the inconvenience.
