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Ruthenium Complexes Carrying Hydride, Dihydrogen, and Phosphine Ligands: Reversible Hydrogen Release^†

Mary Grellier Dr.

[email protected]

Laboratoire de Chimie de Coordination du CNRS, 205 route de Narbonne, 31077 Toulouse Cedex 04, France, Fax: (+33) 5-6155-3003 http://www.lcc-toulouse.fr

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Laure Vendier Dr.,

Laure Vendier Dr.

Laboratoire de Chimie de Coordination du CNRS, 205 route de Narbonne, 31077 Toulouse Cedex 04, France, Fax: (+33) 5-6155-3003 http://www.lcc-toulouse.fr

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Sylviane Sabo-Etienne Dr.,

Sylviane Sabo-Etienne Dr.

[email protected]

Laboratoire de Chimie de Coordination du CNRS, 205 route de Narbonne, 31077 Toulouse Cedex 04, France, Fax: (+33) 5-6155-3003 http://www.lcc-toulouse.fr

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Mary Grellier Dr.,

Mary Grellier Dr.

[email protected]

Laboratoire de Chimie de Coordination du CNRS, 205 route de Narbonne, 31077 Toulouse Cedex 04, France, Fax: (+33) 5-6155-3003 http://www.lcc-toulouse.fr

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Laure Vendier Dr.,

Laure Vendier Dr.

Laboratoire de Chimie de Coordination du CNRS, 205 route de Narbonne, 31077 Toulouse Cedex 04, France, Fax: (+33) 5-6155-3003 http://www.lcc-toulouse.fr

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Sylviane Sabo-Etienne Dr.,

Sylviane Sabo-Etienne Dr.

[email protected]

Laboratoire de Chimie de Coordination du CNRS, 205 route de Narbonne, 31077 Toulouse Cedex 04, France, Fax: (+33) 5-6155-3003 http://www.lcc-toulouse.fr

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First published: 22 March 2007

https://doi.org/10.1002/ange.200605038

Citations: 5

^†

This work is supported by the CNRS and the European network IDECAT.

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Graphical Abstract

Was frei sein will, soll frei sein: Der Bis(diwasserstoff)-Komplex 1, der durch zwei Tricyclopentylphosphanliganden (PCyp₃) stabilisiert wird, kann bis zu zehn Wasserstoffatome freisetzen, was letztlich zu dem neuen Komplex 2 mit nullwertigem Ruthenium führt. Diese einfache Wasserstoffabspaltung ist vollständig reversibel. Im ersten Schritt der Dehydrierung entstehen mehrere Dihydridisomere der Formel [RuH₂{(PCyp₂(η²-C₅H₇)}₂].

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References

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Volume119, Issue15

April 2, 2007

Pages 2667-2669

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Ruthenium Complexes Carrying Hydride, Dihydrogen, and Phosphine Ligands: Reversible Hydrogen Release^†

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Ruthenium Complexes Carrying Hydride, Dihydrogen, and Phosphine Ligands: Reversible Hydrogen Release†

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Ruthenium Complexes Carrying Hydride, Dihydrogen, and Phosphine Ligands: Reversible Hydrogen Release^†