In Situ Magnetic Resonance Investigation of Styrene Oxidation over TS-1 Zeolites†
Jianqin Zhuang Dr.
State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, P.R. China
BASF Aktiengesellschaft, GCC/Z–M301, 67056 Ludwigshafen, Germany
Search for more papers by this authorGang Yang
State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, P.R. China
Search for more papers by this authorDing Ma Dr.
State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, P.R. China
School of Chemistry, University of Bristol, Bristol, BS8 1TS, UK, Fax: (+44) 117-925-1295
Search for more papers by this authorXijie Lan
State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, P.R. China
Search for more papers by this authorXiumei Liu
State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, P.R. China
Search for more papers by this authorXiuwen Han Prof.
State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, P.R. China
Search for more papers by this authorXinhe Bao Prof. Dr.
State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, P.R. China
Search for more papers by this authorUlrich Mueller Dr.
BASF Aktiengesellschaft, GCC/Z–M301, 67056 Ludwigshafen, Germany
Search for more papers by this authorJianqin Zhuang Dr.
State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, P.R. China
BASF Aktiengesellschaft, GCC/Z–M301, 67056 Ludwigshafen, Germany
Search for more papers by this authorGang Yang
State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, P.R. China
Search for more papers by this authorDing Ma Dr.
State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, P.R. China
School of Chemistry, University of Bristol, Bristol, BS8 1TS, UK, Fax: (+44) 117-925-1295
Search for more papers by this authorXijie Lan
State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, P.R. China
Search for more papers by this authorXiumei Liu
State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, P.R. China
Search for more papers by this authorXiuwen Han Prof.
State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, P.R. China
Search for more papers by this authorXinhe Bao Prof. Dr.
State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, P.R. China
Search for more papers by this authorUlrich Mueller Dr.
BASF Aktiengesellschaft, GCC/Z–M301, 67056 Ludwigshafen, Germany
Search for more papers by this authorFinancial support from the National Natural Science Foundation and the Ministry of Science and Technology of the People's Republic of China is gratefully acknowledged. The authors thank Dr. R. Hong and X. Ruan for helpful discussions and K. Perkin for his kind help in composing this paper.
Graphical Abstract
Nicht Folge-, sondern Konkurrenzreaktionen sind die Oxidation von Styrol zu Styroloxid und die Bildung von Phenylacetaldehyd (PADH). In-situ-NMR- und -EPR-spektroskopische Untersuchungen der Styroloxidation an TS-1-Zeolithen (siehe Bild) zeigten, dass Brønsted-Säure-Funktionen als aktive Zentren benötigt werden, um eine Halbacetal-Zwischenstufe in PADH umzuwandeln.
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