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Zweidimensionale Netzwerkstruktur und metamagnetische Eigenschaften des 2:1-Komplexes aus [Mn(3-MeOsalen)(H₂O)]ClO₄ und K₃[Fe(CN)₆]^†

Hitoshi Miyasaka

Department of Chemistry, Faculty of Science, Kyushu University Hakozaki, Higashi-ku. Fukuoka 812 (Japan), Telefax: Int. + 92/632-2734

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Prof. Naohide Matsumoto,

Corresponding Author

Prof. Naohide Matsumoto

Department of Chemistry, Faculty of Science, Kyushu University Hakozaki, Higashi-ku. Fukuoka 812 (Japan), Telefax: Int. + 92/632-2734

Naohide Matsumoto, Department of Chemistry, Faculty of Science, Kyushu University Hakozaki, Higashi-ku. Fukuoka 812 (Japan), Telefax: Int. + 92/632-2734

Carlo Floriani, Institut de Chimie Minérale et Analytique, Université de Lausanne (Schweiz)

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Prof. Hisashi Ökawa,

Prof. Hisashi Ökawa

Department of Chemistry, Faculty of Science, Kyushu University Hakozaki, Higashi-ku. Fukuoka 812 (Japan), Telefax: Int. + 92/632-2734

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Prof. Emma Gallo,

Prof. Emma Gallo

Institut de Chimie Minérale et Analytique, Université de Lausanne (Schweiz)

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Prof. Carlo Floriani,

Corresponding Author

Prof. Carlo Floriani

Institut de Chimie Minérale et Analytique, Université de Lausanne (Schweiz)

Naohide Matsumoto, Department of Chemistry, Faculty of Science, Kyushu University Hakozaki, Higashi-ku. Fukuoka 812 (Japan), Telefax: Int. + 92/632-2734

Carlo Floriani, Institut de Chimie Minérale et Analytique, Université de Lausanne (Schweiz)

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Dr. Nazzareno Re,

Dr. Nazzareno Re

Dipartimento di Chimica, Perugia (Italien)

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Hitoshi Miyasaka,

Hitoshi Miyasaka

Department of Chemistry, Faculty of Science, Kyushu University Hakozaki, Higashi-ku. Fukuoka 812 (Japan), Telefax: Int. + 92/632-2734

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Prof. Naohide Matsumoto,

Corresponding Author

Prof. Naohide Matsumoto

Department of Chemistry, Faculty of Science, Kyushu University Hakozaki, Higashi-ku. Fukuoka 812 (Japan), Telefax: Int. + 92/632-2734

Naohide Matsumoto, Department of Chemistry, Faculty of Science, Kyushu University Hakozaki, Higashi-ku. Fukuoka 812 (Japan), Telefax: Int. + 92/632-2734

Carlo Floriani, Institut de Chimie Minérale et Analytique, Université de Lausanne (Schweiz)

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Prof. Hisashi Ökawa,

Prof. Hisashi Ökawa

Department of Chemistry, Faculty of Science, Kyushu University Hakozaki, Higashi-ku. Fukuoka 812 (Japan), Telefax: Int. + 92/632-2734

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Prof. Emma Gallo,

Prof. Emma Gallo

Institut de Chimie Minérale et Analytique, Université de Lausanne (Schweiz)

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Prof. Carlo Floriani,

Corresponding Author

Prof. Carlo Floriani

Institut de Chimie Minérale et Analytique, Université de Lausanne (Schweiz)

Naohide Matsumoto, Department of Chemistry, Faculty of Science, Kyushu University Hakozaki, Higashi-ku. Fukuoka 812 (Japan), Telefax: Int. + 92/632-2734

Carlo Floriani, Institut de Chimie Minérale et Analytique, Université de Lausanne (Schweiz)

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Dr. Nazzareno Re,

Dr. Nazzareno Re

Dipartimento di Chimica, Perugia (Italien)

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First published: 7. Juli 1995

https://doi.org/10.1002/ange.19951071309

Citations: 20

^†

Wir danken den Gutachtern für ihre Beiträge zur Interpretation des magnetischen Verhaltens. Diese Arbeit wurde vom Ministry of Education, Science, and Culture of Japan gefördert. (3-MeOsalen)^{2 −} = Dianion von Bis(3-methoxysalicyliden)ethylendiamin.

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Abstract

Cyclische Einheiten ( ··· Mn-NC-Fe-CN ··· )₄ bilden das zweidimensionale Netzwerk der Titelverbindung. Dabei entstehen Schichten, die über van-der-Waals-Kontakte miteinander verknüpft sind. Die Verbindung zeigt Metamagnetismus: Innerhalb der Schichten tritt eine ferromagnetische, zwischen den Schichten eine antiferromagnetische Kopplung auf. Rechts ist ein Ausschnitt des zweidimensionalen Netzwerks gezeigt.

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Volume107, Issue13-14

7. Juli 1995

Pages 1565-1568

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Zweidimensionale Netzwerkstruktur und metamagnetische Eigenschaften des 2:1-Komplexes aus [Mn(3-MeOsalen)(H₂O)]ClO₄ und K₃[Fe(CN)₆]^†

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Zweidimensionale Netzwerkstruktur und metamagnetische Eigenschaften des 2:1-Komplexes aus [Mn(3-MeOsalen)(H2O)]ClO4 und K3[Fe(CN)6]†

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Zweidimensionale Netzwerkstruktur und metamagnetische Eigenschaften des 2:1-Komplexes aus [Mn(3-MeOsalen)(H₂O)]ClO₄ und K₃[Fe(CN)₆]^†