Volume 154, Issue 1 pp. 15-24
Article

Electro-optic effects and phase behavior of liquid-crystalline physical gels: self-assembly of hydrogen-bonded molecules for the formation of dynamically functional composites

Takashi Kato

Takashi Kato

Department of Chemistry and Biotechnology, Graduate School of Engineering, The University of Tokyo, Hongo, Bunkyo-ku, Tokyo 113-8656, Japan

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Norihiro Mizoshita

Norihiro Mizoshita

Department of Chemistry and Biotechnology, Graduate School of Engineering, The University of Tokyo, Hongo, Bunkyo-ku, Tokyo 113-8656, Japan

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Takaaki Kutsuna

Takaaki Kutsuna

Department of Chemistry and Biotechnology, Graduate School of Engineering, The University of Tokyo, Hongo, Bunkyo-ku, Tokyo 113-8656, Japan

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Gohta Kondo

Gohta Kondo

Department of Chemistry and Biotechnology, Graduate School of Engineering, The University of Tokyo, Hongo, Bunkyo-ku, Tokyo 113-8656, Japan

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Kenji Hanabusa

Kenji Hanabusa

Department of Functional Polymer Science, Faculty of Textile Science and Technology, Shinshu University, Ueda, Nagano 386-8567, Japan

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Abstract

Anisotropic physical gels of liquid crystals are obtained by the formation of non-covalently-bonded networks through self-organization of low molecular weight compounds in nematic solvents. They exhibit thermoreversible transitions between isotropic liquid and isotropic gel, and between isotropic gel and liquid-crystalline gel, whose temperatures are dependent on the components. Electro-optic properties of liquid-crystalline gels are examined with twisted nematic cells. A nematic liquid crystal in a gel structure can respond to electric fields twice faster than a single liquid-crystalline component.

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