Volume 41, Issue 13 pp. 2301-2303

Communication

A New Type of Chainlike Tetranuclear Rhodium Complexes with PR₃ and AsMe₃ as Bridging Ligands^†

Thomas Pechmann Dipl.-Chem.,

Thomas Pechmann Dipl.-Chem.

Institut für Anorganische Chemie Universität Würzburg Am Hubland, 97074 Würzburg (Germany) Fax: (+49) 931-888-4623

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Carsten D. Brandt Dipl.-Chem.,

Carsten D. Brandt Dipl.-Chem.

Institut für Anorganische Chemie Universität Würzburg Am Hubland, 97074 Würzburg (Germany) Fax: (+49) 931-888-4623

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Cornelia Röger,

Cornelia Röger

Institut für Anorganische Chemie Universität Würzburg Am Hubland, 97074 Würzburg (Germany) Fax: (+49) 931-888-4623

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Helmut Werner Prof. Dr.,

Helmut Werner Prof. Dr.

[email protected]

Institut für Anorganische Chemie Universität Würzburg Am Hubland, 97074 Würzburg (Germany) Fax: (+49) 931-888-4623

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Thomas Pechmann Dipl.-Chem.,

Thomas Pechmann Dipl.-Chem.

Institut für Anorganische Chemie Universität Würzburg Am Hubland, 97074 Würzburg (Germany) Fax: (+49) 931-888-4623

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Carsten D. Brandt Dipl.-Chem.,

Carsten D. Brandt Dipl.-Chem.

Institut für Anorganische Chemie Universität Würzburg Am Hubland, 97074 Würzburg (Germany) Fax: (+49) 931-888-4623

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Cornelia Röger,

Cornelia Röger

Institut für Anorganische Chemie Universität Würzburg Am Hubland, 97074 Würzburg (Germany) Fax: (+49) 931-888-4623

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Helmut Werner Prof. Dr.,

Helmut Werner Prof. Dr.

[email protected]

Institut für Anorganische Chemie Universität Würzburg Am Hubland, 97074 Würzburg (Germany) Fax: (+49) 931-888-4623

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First published: 01 July 2002

https://doi.org/10.1002/1521-3773(20020703)41:13<2301::AID-ANIE2301>3.0.CO;2-X

Citations: 39

^†

This work was supported by the Deutsche Forschungsgemeinschaft (SFB 347) and the Fonds der Chemischen Industrie.

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Graphical Abstract

A tertiary arsane ligand in a bridging position occurs for the first time in the structurally characterized transition-metal complex 2, which was prepared from 1 by stepwise ligand substitution of both the trialkylstibane and acetylacetonate ligands. The analogous chainlike phosphane-bridged dimer [ClRh(μ-PMe₃)(μ-CPh₂)₂Rh(μ-Cl )₂Rh(μ-PMe₃)(μ-CPh₂)₂RhCl] has also been isolated and characterized by X-ray crystallography.

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Volume41, Issue13

July 3, 2002

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A New Type of Chainlike Tetranuclear Rhodium Complexes with PR₃ and AsMe₃ as Bridging Ligands^†

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A New Type of Chainlike Tetranuclear Rhodium Complexes with PR3 and AsMe3 as Bridging Ligands†

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A New Type of Chainlike Tetranuclear Rhodium Complexes with PR₃ and AsMe₃ as Bridging Ligands^†