Metal Complexes of an N-Confused Calix[4]phyrin Derivative—The First X-ray Structure of an Organometallic Compound of Divalent Copper
Hiroyuki Furuta Prof.
Department of Chemistry Graduate School of Science Kyoto University, Kyoto 606-8502 (Japan) Fax: (+81) 75-753-3970
Search for more papers by this authorTomoya Ishizuka
Department of Chemistry Graduate School of Science Kyoto University, Kyoto 606-8502 (Japan) Fax: (+81) 75-753-3970
Search for more papers by this authorAtsuhiro Osuka Prof.
Department of Chemistry Graduate School of Science Kyoto University, Kyoto 606-8502 (Japan) Fax: (+81) 75-753-3970
Search for more papers by this authorYoshiya Uwatoko Prof.
Faculty of Science Saitama University, Saitama 338-8570 (Japan)
Search for more papers by this authorYuichi Ishikawa Prof.
Department of Applied Chemistry Faculty of Engineering, Oita University Oita 870-1192 (Japan) Fax: (+81) 97-554-7907
Search for more papers by this authorHiroyuki Furuta Prof.
Department of Chemistry Graduate School of Science Kyoto University, Kyoto 606-8502 (Japan) Fax: (+81) 75-753-3970
Search for more papers by this authorTomoya Ishizuka
Department of Chemistry Graduate School of Science Kyoto University, Kyoto 606-8502 (Japan) Fax: (+81) 75-753-3970
Search for more papers by this authorAtsuhiro Osuka Prof.
Department of Chemistry Graduate School of Science Kyoto University, Kyoto 606-8502 (Japan) Fax: (+81) 75-753-3970
Search for more papers by this authorYoshiya Uwatoko Prof.
Faculty of Science Saitama University, Saitama 338-8570 (Japan)
Search for more papers by this authorYuichi Ishikawa Prof.
Department of Applied Chemistry Faculty of Engineering, Oita University Oita 870-1192 (Japan) Fax: (+81) 97-554-7907
Search for more papers by this authorGraphical Abstract
Rare organometallic complexes can be stabilized by using an N-confused system as a carbon ligand. A stable organocopper(II) compound of N-confused calix[4]phyrin has been characterized by X-ray crystallography (see picture). Complete π conjugation was found not to be a prerequisite for the formation of the metal–carbon bond.
Supporting Information
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