Remarkable Anionic Axial Ligand Effects of Iron(III) Porphyrin Complexes on the Catalytic Oxygenations of Hydrocarbons by H2O2 and the Formation of Oxoiron(IV) Porphyrin Intermediates by m-Chloroperoxybenzoic Acid
Wonwoo Nam Prof. Dr.
Department of Chemistry and Division of Molecular Life Sciences Ewha Womans University, Seoul 120-750 (Korea) Fax: (+82) 2-3277-2384
Search for more papers by this authorMi H. Lim
Department of Chemistry and Division of Molecular Life Sciences Ewha Womans University, Seoul 120-750 (Korea) Fax: (+82) 2-3277-2384
Search for more papers by this authorSo-Young Oh
Department of Chemistry and Division of Molecular Life Sciences Ewha Womans University, Seoul 120-750 (Korea) Fax: (+82) 2-3277-2384
Search for more papers by this authorJung H. Lee
Department of Chemistry and Division of Molecular Life Sciences Ewha Womans University, Seoul 120-750 (Korea) Fax: (+82) 2-3277-2384
Search for more papers by this authorHa J. Lee
Department of Chemistry and Division of Molecular Life Sciences Ewha Womans University, Seoul 120-750 (Korea) Fax: (+82) 2-3277-2384
Search for more papers by this authorSeung K. Woo
Department of Chemistry Sogang University Seoul 121-742 (Korea)
Search for more papers by this authorCheal Kim Prof. Dr.
Department of Fine Chemistry Seoul National Polytechnic University Seoul 139-743 (Korea)
Search for more papers by this authorWoonsup Shin Prof. Dr.
Department of Chemistry Sogang University Seoul 121-742 (Korea)
Search for more papers by this authorWonwoo Nam Prof. Dr.
Department of Chemistry and Division of Molecular Life Sciences Ewha Womans University, Seoul 120-750 (Korea) Fax: (+82) 2-3277-2384
Search for more papers by this authorMi H. Lim
Department of Chemistry and Division of Molecular Life Sciences Ewha Womans University, Seoul 120-750 (Korea) Fax: (+82) 2-3277-2384
Search for more papers by this authorSo-Young Oh
Department of Chemistry and Division of Molecular Life Sciences Ewha Womans University, Seoul 120-750 (Korea) Fax: (+82) 2-3277-2384
Search for more papers by this authorJung H. Lee
Department of Chemistry and Division of Molecular Life Sciences Ewha Womans University, Seoul 120-750 (Korea) Fax: (+82) 2-3277-2384
Search for more papers by this authorHa J. Lee
Department of Chemistry and Division of Molecular Life Sciences Ewha Womans University, Seoul 120-750 (Korea) Fax: (+82) 2-3277-2384
Search for more papers by this authorSeung K. Woo
Department of Chemistry Sogang University Seoul 121-742 (Korea)
Search for more papers by this authorCheal Kim Prof. Dr.
Department of Fine Chemistry Seoul National Polytechnic University Seoul 139-743 (Korea)
Search for more papers by this authorWoonsup Shin Prof. Dr.
Department of Chemistry Sogang University Seoul 121-742 (Korea)
Search for more papers by this authorThis work was supported by Center for Cell Signaling Research (1999-2-122-002-4), the Korean Research Foundation (KRF-99-042-D00068), and the MOST through the Women's University Research Fund (99-N6-01-01-A-07).
Abstract
A marked influence on the catalytic epoxidation and hydroxylation of hydrocarbons by aqueous 30 % H2O2 in an aprotic solvent and on the formation of oxoiron(IV) porphyrin intermediates in m-chloroperoxybenzoic acid (m-CPBA) reactions in polar solvent is shown by the anionic axial ligands of an electron-deficient iron(III) porphyrin complex [Fe(tpfpp)X] (tpfpp=meso-tetrakis(pentafluorophenyl)porphinato dianion; see scheme).
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