The authors thank Dr. J. D. Kennedy, University of Leeds (UK) for many helpful discussions and the ¹¹B and ²⁹Si NMR spectra. Research grants to G.F. from NSERC Canada and to L.A.N. from Forbairt (Ireland) are gratefully acknowledged.

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Abstract

Equal numbers of boron and silicon atoms are present in a new type of cage compound whose structure (see picture) is based on an incomplete B₄Si₄ cube in which the boron sites are three-coordinate. This compound, which was synthesized from tert-butyltrichlorosilane, 4-vinylphenylboronic acid, and aqueous aniline, is the first cube-based structure with pairs of the same atoms in adjacent positions.

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Volume39, Issue20

October 16, 2000

Pages 3598-3601

A Novel Borosilicate Cage Compound with an Incomplete B₄Si₄ Cube Structure: [(tBuSi)₄(CH₂=CHC₆H₄B)₄O₁₀]

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A Novel Borosilicate Cage Compound with an Incomplete B4Si4 Cube Structure: [(tBuSi)4(CH2=CHC6H4B)4O10]

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A Novel Borosilicate Cage Compound with an Incomplete B₄Si₄ Cube Structure: [(tBuSi)₄(CH₂=CHC₆H₄B)₄O₁₀]