Highly Efficient Catalytic Synthesis of Substituted Allenes Using Indium†
Kooyeon Lee
Department of Chemistry, Kangwon National University Chunchon 200-701 (Korea) Fax: (+82) 33-253-7582
Search for more papers by this authorDong Seomoon
Department of Chemistry, Kangwon National University Chunchon 200-701 (Korea) Fax: (+82) 33-253-7582
Search for more papers by this authorPhil Ho Lee Prof. Dr.
Department of Chemistry, Kangwon National University Chunchon 200-701 (Korea) Fax: (+82) 33-253-7582
Search for more papers by this authorKooyeon Lee
Department of Chemistry, Kangwon National University Chunchon 200-701 (Korea) Fax: (+82) 33-253-7582
Search for more papers by this authorDong Seomoon
Department of Chemistry, Kangwon National University Chunchon 200-701 (Korea) Fax: (+82) 33-253-7582
Search for more papers by this authorPhil Ho Lee Prof. Dr.
Department of Chemistry, Kangwon National University Chunchon 200-701 (Korea) Fax: (+82) 33-253-7582
Search for more papers by this authorThis work was supported financially by the CMDS at KAIST. We thank Prof. Sunggak Kim and Prof. Sukbok Chang of KAIST for helpful discussions and Hyosoon Ahn, Keuckchan Bang, and Dr. Sun-young Sung for the preparation of starting materials and preliminary experiments.
Graphical Abstract
Vielseitig, einfach, mild: Allenylindium-Intermediate, die aus Indium und Propargylbromiden gebildet werden, dienten bei Pd-katalysierten Kreuzkupplungen als wirksame Kupplungspartner für eine Reihe von Elektrophilen. Hierbei entstehen Allene, Polyallene und unsymmetrische Bis(allene) in ausgezeichneten Ausbeuten und mit sehr hoher Regio- und Chemoselektivität (für ein Beispiel siehe Schema).
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