Zeitschrift für anorganische und allgemeine Chemie

Article

Kinetic Study of the Oxidation of tert-Butanol by Cerium(IV) in Perchloric Acid Media

Corresponding Author

F. Mata-Pérez Dr.

Valladolid/Spain, Departamento de Química-Física, Facultad de Ciencias, Universidad de Valladolid

Departamento de Química Física, Facultad de Ciencias, Universidad, E-47005 Valladolid/SpainSearch for more papers by this author

C. Francisco,

C. Francisco

Valladolid/Spain, Departamento de Química-Física, Facultad de Ciencias, Universidad de Valladolid

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M. P. Alvarez,

M. P. Alvarez

Valladolid/Spain, Departamento de Química-Física, Facultad de Ciencias, Universidad de Valladolid

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F. Mata-Pérez Dr.,

Corresponding Author

F. Mata-Pérez Dr.

Valladolid/Spain, Departamento de Química-Física, Facultad de Ciencias, Universidad de Valladolid

Departamento de Química Física, Facultad de Ciencias, Universidad, E-47005 Valladolid/SpainSearch for more papers by this author

C. Francisco,

C. Francisco

Valladolid/Spain, Departamento de Química-Física, Facultad de Ciencias, Universidad de Valladolid

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M. P. Alvarez,

M. P. Alvarez

Valladolid/Spain, Departamento de Química-Física, Facultad de Ciencias, Universidad de Valladolid

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First published: 13 February 2002

https://doi.org/10.1002/1521-3749(200202)628:2<431::AID-ZAAC431>3.0.CO;2-M

Citations: 5

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Abstract

The kinetics of the oxidation of tert-butanol by cerium(IV) in perchloric acid has been investigated spectrophotometrically. The water role has been elucidates by using acidity criteria. A tentative mechanism consistent with the kinetics is discussed where a complex cerium(IV)-alcohol is formed, the equilibrium constant for its formation being calculated. The ratedetermining step is a bimolecular process between ions of positive charge.

REFERENCES

1 V. W.Reid, R. K.Truelove, Analyst, 1952, 77, 325.
10.1039/an9527700325
CAS Web of Science® Google Scholar
2 V. W.Reid, D. G.Salman, Analyst, 1955, 80, 704.
Google Scholar
3 S. S.Muhammad, K. V.Rao, Bull. Chem. Soc. Jpn., 1963, 36, 943.
10.1246/bcsj.36.943
CAS Web of Science® Google Scholar
4 H. G.Offner, D. A.Skoog, Anal. Chem., 1965, 37, 1018.
10.1021/ac60227a018
CAS Web of Science® Google Scholar
5 H. L.Hintz, D. C.Johnson, J. Org. Chem., 1967, 32, 556.
10.1021/jo01278a009
CAS Web of Science® Google Scholar
6 G. G.Guilbault, W. H.McCurdy, J. Phys. Chem., 1963, 67, 283.
10.1021/j100796a016
CAS Web of Science® Google Scholar
7 S. S.Muhammad and K. V.Rao, Bull. Chem. Soc. Jpn., 1963, 36, 949.
10.1246/bcsj.36.949
CAS Web of Science® Google Scholar
8 B.Sethuram, S. S.Muhammad, Acta Chim. Acad. Sci. Hung., 1965, 46, 125.
CAS Web of Science® Google Scholar
9 M.Ardon, J. Chem. Soc. 1957, 1811.
10.1039/jr9570001811
CAS Web of Science® Google Scholar
10 G.Mino, S.Kaizermann, E.Rasmussen, J. Am. Chem. Soc., 1959, 81, 1494.
10.1021/ja01515a053
CAS Web of Science® Google Scholar
11 W. H.McCurdy Jr., G. G.Guilbault, J. Phys. Chem., 1960, 64, 1825.
10.1021/j100841a006
Web of Science® Google Scholar
12 Y. W.Chang, F. H.Westheimer, J. Am. Chem. Soc., 1960, 82, 1401.
10.1021/ja01491a030
CAS Web of Science® Google Scholar
13 L. B.Young, W. S.Trahanovsky, J. Am. Chem. Soc., 1969, 91, 5060.
10.1021/ja01046a021
CAS Web of Science® Google Scholar
14 J. S.Littler, W. A.Waters, J. Chem. Soc. 1960, 2767.
10.1039/jr9600002767
CAS Web of Science® Google Scholar
15 T. J.Harwick, E.Roberson, Can. J. Chem., 1972, 29, 828.
10.1139/v51-095
Web of Science® Google Scholar
16 S. B.Hanna, R. R.Kessler, A.Merbach, S.Ruzicka, J. Chem. Educ., 1972, 53, 524.
10.1021/ed053p524
Google Scholar
17 H. O. House, Modern Synthetic Reactions, W. A. BenjaminInc. , New York, N. Y. 1965, p. 83.
Google Scholar
18 L.Zucker, L. P.Hammett, J. Am. Chem. Soc., 1939, 61, 2791.
10.1021/ja01265a067
CAS Google Scholar
19 J. F.Bunnett, F. P.Olsen, Can. J. Chem., 1966, 44, 1899.
10.1139/v66-286
CAS Web of Science® Google Scholar
20 J. L.Heidt, M. E.Smith, J. Am. Chem. Soc., 1948, 70, 2476.
10.1021/ja01187a050
CAS Web of Science® Google Scholar
21 M.Ardon, G.Stein, J. Chem. Soc. 1956, 104.
10.1039/jr9560000104
CAS Web of Science® Google Scholar
22 K. G.Everett, D. A.Skoog, Anal. Chem., 1971, 43, 1531.
10.1021/ac60306a008
Web of Science® Google Scholar
23 S. M.Tuwar, V. A.Morab, S. T.Nandibewoor, J.Raju, TransitionMet. Chem., 1991, 16, 430.
10.1007/BF01129458
CAS Web of Science® Google Scholar
24 T.Moeller, D. F.Martin, L. C.Thompson, R.Ferrus, G.Feistel, W. J.Randall, Chem. Rev., 1965, 65, 1.
10.1021/cr60233a001
CAS Web of Science® Google Scholar
25 S. V.Rao, V.Jagannadham, React. Kinet. Cat. Lett., 1985, 27, 239.
10.1007/BF02070450
CAS Web of Science® Google Scholar
26 Vogel's Textbook of Practical Organic Chemistry, Fourth Edition, Longman, New York 1978, p. 270.
Google Scholar
27 R. Q. Brewster, C. A. Vanderwerf, W. E. McEwen, Curso Prácticode Quýmica Orgánica, Alhambra, Madrid 1975, p. 100.
Google Scholar
28 R. M. Silverstein, G. C. Bassler, T. C. Morrill, SpectrometricIdentification of Organic Compounds, John Willey and Sons, New York 1981, p. 233 and 239.
Google Scholar
29 F.Hassan, J.Rocek, J. Am. Chem. Soc., 1972, 94, 3181; J. Am. Chem. Soc. 1974, 96, 534.
10.1021/ja00764a048
Web of Science® Google Scholar

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Volume628, Issue2

February 2002

Pages 431-436

Kinetic Study of the Oxidation of tert-Butanol by Cerium(IV) in Perchloric Acid Media

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Kinetic Study of the Oxidation of tert-Butanol by Cerium(IV) in Perchloric Acid Media

Abstract

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