Atomic Spectroscopy, 3. Emission Spectrometry
José A. C. Broekaert,
E. Hywel Evans,
José A. C. Broekaert
Universität Dortmund, Fachbereich Chemie, Dortmund, Germany
Search for more papers by this authorE. Hywel Evans
University of Plymouth, Plymouth, United Kingdom
Search for more papers by this authorJosé A. C. Broekaert,
E. Hywel Evans,
José A. C. Broekaert
Universität Dortmund, Fachbereich Chemie, Dortmund, Germany
Search for more papers by this authorE. Hywel Evans
University of Plymouth, Plymouth, United Kingdom
Search for more papers by this authorFirst published: 15 October 2011
Abstract
The article contains sections titled:
1. |
Principles |
2. |
Spectrometers |
3. |
Flame Emission |
4. |
Arcs and Sparks |
5. |
Plasma Sources |
5.1. |
Direct Current Plasmas |
5.2. |
Inductively Coupled Plasmas |
5.3. |
Microwave Plasmas |
6. |
Glow Discharges |
6.1. |
Hollow Cathodes |
6.2. |
Furnace Emission Spectrometry |
6.3. |
Glow Discharges with Flat Cathodes |
6.4. |
New Developments |
7. |
Laser Sources |
References
- 1 G. R. Kirchhoff, R. Bunsen, Philos. Mag. 20 (1860) 89 – 98.
- 2 J. A. C. Broekaert, Bull. Soc. Chim. Belg. 86 (1977) 895 – 906.
- 3 P. N. Keliher, C. C. Wohlers, Anal. Chem. 48 (1976) 333 A – 340 A.
- 4 J. A. C. Broekaert, C. A. Monnig, K. R. Brushwyler, G. M. Hieftje, Spectrochim. Acta Part B 45 B (1990) 769 – 778.
- 5 A. Aziz, J. A. C. Broekaert, F. Leis, Spectrochim. Acta Part B 37 B (1982) 369 – 379.
- 6 E. Sebastiani, K. Ohls, G. Riemer, Fresenius' Z. Anal. Chem. 264 (1973) 105 – 109.
- 7 H. Berndt, W. Slavin, At. Absorpt. Newsl. 17 (1978) 109.
- 8 A. Aziz, J. A. C. Broekaert, F. Leis, Spectrochim. Acta Part B 37 B (1982) 381 – 389.
- 9 S. D. Olsen, A. Strasheim, Spectrochim. Acta Part B 38 B (1983) 973 – 975.
- 10 A. W. Boorn, R. Browner, Anal. Chem. 54 (1982) 1402 – 1410.
- 11 M. P. Doherty, G. M. Hieftje, Appl. Spectrosc. 38 (1984) 405 – 411.
- 12 H. Berndt, Fresenius' J. Anal. Chem. 331 (1988) 321 – 323.
- 13 V. A. Fassel, B. R. Bear, Spectrochim. Acta Part B 41 B (1986) 1089 – 1113.
- 14 P. W. J. M. Boumans, F. J. De Boer, Spectrochim. Acta Part B 30 B (1975) 309 – 334.
- 15 M. Thompson, B. Pahlavanpour, S. J. Walton, G. F. Kirkbright, Analyst (London) 103 (1978) 568 – 579.
- 16 E. Bulska, P. Tschöpel, J. A. C. Broekaert, G. Tölg, Anal. Chim. Acta 271 (1993) 171 – 181.
- 17 E. I. Brooks, K. J. Timmins, Analyst (London) 110 (1985) 557 – 558.
- 18 D. L. Millard, H. C. Shan, G. F. Kirkbright, Analyst (London) 105 (1980) 502 – 508.
- 19 G. Zaray, J. A. C. Broekaert, F. Leis, Spectrochim. Acta Part B 43 B (1988) 241 – 253.
- 20 V. Karnassios, G. Horlick, Spectrochim. Acta Part B 44 B (1989) 1345 – 1360.
- 21 L. Blain, E. D. Salin, Spectrochim. Acta Part B 47 B (1992) 205 – 217.
- 22 R. Lobinski et al., Fresenius' J. Anal. Chem. 342 (1992) 563 – 568.
- 23 S. ElAlfy, K. Laqau, H. Maßmann, Fresenius' Z. Anal. Chem. 263 (1973) 1 – 14.
- 24 A. Aziz, J. A. C. Broekaert, K. Laqua, F. Leis, Spectrochim. Acta Part B 39 B (1984) 1091 – 1103.
- 25 B. Raeymaekers, P. Van Espen, F. Adams, J. A. C. Broekaert, Appl. Spectrosc. 42 (1988) 142 – 150.
- 26 L. Moenke-Blankenburg: Laser Micro Analysis, Wiley, New York 1989.
- 27 J. Sneddon, T. L. Thiem, Y. Lee: Lasers in Analytical Spectrometry, VCH, New York 1997.
- 28 P. W. J. M. Boumans, Anal. Chem. 44 (1973) 1219–1228.
- 29 M. Dogan, K. Laqua, H. Maßmann, Spectrochim. Acta Part B 27 B (1972) 631 – 649.
- 30 R. Hermann, C. T. J. Alkemade: Chemical Analysis by Flame Photometry, 2nd ed., Interscience Publishers, New York 1983.
- 31 L. Ebdon, M. R. Cave, Analyst (London) 107 (1982) 172 – 178.
- 32 J. Szpunar, Analyst 125 (2000) 963 – 988.
- 33 W. M. R. Dirkx, R. Lobinski, F. C. Adams, Anal. Sci. 9 (1993) 273 – 278.
- 34 W. Gerlach, E. Schweitzer: Die chemische Emissionsspektralanalyse, vol. 1, L. Voss, Leipzig 1930.
- 35 G. R. Harrison: Wavelength Tables, The M.I.T. Press, Cambridge, Mass., 1991.
- 36 A. N. Saidel, V. K. Prokofiev, S. M. Raiski: Spektraltabellen, V.E.B. Verlag Technik, Berlin 1955.
- 37 A. Gatterer, J. Junkes: Atlas der Restlinien, vols. 3, Specola Vaticana, Citta del Vaticano, 1945, 1947, 1959.
- 38 E. W. Salpeter: Spektren in der Glimmentladung von 150 bis 400 nm, vols. 1 – 5, Specola Vaticana, Citta del Vaticano 1973.
- 39 R. K. Winge, V. A. Fassel, V. J. Peterson, M. A. Floyd: ICP Atomic Emission Spectroscopy, Elsevier, Amsterdam 1985.
- 40 P. W. J. M. Boumans: Line Coincidence Tables for ICP-OES, vols. 1 and 2, Pergamon Press, Oxford 1984.
- 41 B. Huang et al.: An Atlas of High Resolution Spectra for Rare Earth Elements for ICP – AES, Royal Society of Chemistry, Cambridge 2000.
- 42 G. Scheibe: Chemische Spektralanalyse, physikalische Methoden der analytischen Chemie, vol. 1, 1933.
- 43 A. Lomakin, Z. Anorg. Allg. Chem. 75 (1930) 187.
- 44 Ullmann, 4th ed., 5, 441 – 500.
- 45
K. Laqua,
W.-D. Hagenah,
H. Wächter,
Fresenius' Z. Anal. Chem.
221
(1967)
142 – 174.
10.1007/BF00983667 Google Scholar
- 46 A. Aziz, J. A. C. Broekaert, F. Leis, Spectrochim. Acta Part B 36 B (1981) 251 – 260.
- 47
N. W. H. Addink:
DC Arc Analysis,
MacMillan,
London
1971.
10.1007/978-1-349-15413-5 Google Scholar
- 48 M. Z. Riemann, Fresenius' Z. Anal. Chem. 215 (1966) 407 – 424.
- 49 R. Avni in E. L. Grove (ed.): Applied Atomic Spectroscopy, vol. 1, Plenum Press, New York 1978.
- 50 K. Slickers: Die automatische Atom-Emissions-Spektralanalyse, Brühlsche Universitätsdruckerei, Gießen 1992.
- 51 K. Slickers: Automatic Atomic Emission Spectroscopy, Brühlsche Universitätsdruckerei, Gießen 1993.
- 52 K. H. Koch, Spectrochim. Acta Part B 39 B (1984) 1067 – 1079.
- 53 K. Tohyama, J. Ono, M. Onodera, M. Saeki: Research and Development in Japan, Okochi Memorial Foundation, 1978, pp. 31 – 35.
- 54 D. M. Coleman, M. A. Sainz, H. T. Butler, Anal. Chem. 52 (1980) 746 – 753.
- 55 A. Montaser: Inductively Coupled Plasmas in Analytical Atomic Spectrometry, 2nd ed., Wiley-VCH, New York 1998.
- 56 S. J. Hill (ed.): Inductively Coupled Plasma Spectrometry and its Applications, Sheffield Academic Press, Sheffield 1999.
- 57 V. V. Korolev, E. E. Vainshtein, J. Anal. Chem. USSR (Engl. Transl.) 14 (1959) 658 – 662.
- 58 M. Margoshes, B. Scribner, Spectrochim. Acta 15 (1959) 138 – 145.
- 59 E. Kranz in: Emissionsspektroskopie, Akademie-Verlag, Berlin 1964, p. 160.
- 60 J. Reednick, Am. Lab. 1979, no. 5, 127 – 133.
- 61 R. J. Decker, Spectrochim. Acta Part B 35 B (1980) 19 – 35.
- 62 F. Leis, J. A. C. Broekaert, H. Waechter, Fresenius' Z. Anal. Chem. 333 (1989) 2 – 5.
- 63 G. W. Johnson, H. E. Taylor, R. K. Skogerboe, Spectrochim. Acta Part B 34 B (1979) 197 – 212.
- 64 T. B. Reed, J. Appl. Phys. 32 (1961) 821 – 824.
- 65 S. Greenfield, I. L. Jones, C. T. Berry, Analyst (London) 89 (1964) 713 – 720.
- 66 R. H. Wendt, V. A. Fassel, Anal. Chem. 37 (1965) 920 – 922.
- 67 R. Rezaaiyaan et al., Appl. Spectrosc. 36 (1982) 626–631.
- 68 D. J. Kalnicki, V. A. Fassel, R. N. Kalnicky, Appl. Spectrosc. 31 (1977) 137 – 150.
- 69 B. Raeymaekers, J. A. C. Broekaert, F. Leis, Spectrochim. Acta Part B 43 B (1988) 941 – 949.
- 70 I. Ishii, A. Montaser, Spectrochim. Acta Part B 46 B (1991) 1197 – 1206.
- 71 P. W. J. M. Boumans, F. J. de Boer, Spectrochim. Acta Part B 32 B (1977) 365 – 395.
- 72 L. De Galan, Spectrochim. Acta Part B 39 B (1984) 537 – 550.
- 73 M. Huang, D. S. Hanselmann, P. Y. Yang, G. M. Hieftje, Spectrochim. Acta Part B 47 B (1992) 765–786.
- 74 J. A. C. Broekaert, F. Leis, Anal. Chim. Acta 109 (1979) 73 – 83.
- 75 F. H. Walters, L. R. Parker, Jr., S. L. Morgan, S. N. Deming: Sequential Simplex Optimization, CRC Press, Inc., Boca Raton 1991.
- 76 G. L. Moore, P. J. Humphries-Cuff, A. E. Watson, Spectrochim. Acta Part B 39 B (1984) 915 – 929.
- 77
M. L. Parsons,
A. R. Forster,
D. Anderson:
An Atlas of Spectral Interferences in ICP Spectroscopy,
Plenum Press,
New York
1980.
10.1007/978-1-4684-1024-2 Google Scholar
- 78 M. R. Cave, O. Butler, J. M. Cook, M. S. Cresser, L. M. Garden, D. L. Miles, J. Anal. At. Spectrom. 15 (2000) 181 – 235.
- 79 U.S. Environmental Protection Agency: Methods for the Determination of Metals in Environmental Samples, EPA600491010, Washington DC 1991.
- 80 U.S. Environmental Protection Agency: Methods for the Determination of Metals in Environmental Samples, Supplement 1, EPA600R94111, Washington DC 1994.
- 81 B. Fairman, M. Hinds, S. M. Nelms, D. M. Penny, P. Goodall, J. Anal. At. Spectrom. 14 (1999) 1937 – 1969.
- 82 R. E. Russo, X. L. Mao, O. V. Borisov, Trends Anal. Chem. 17 (1998) 461.
- 83 W. B. Barnett, V. A. Fassel, R. N. Kniseley, Spectrochim. Acta Part B 23 B (1968) 643 – 664.
- 84 S. A. Meyers, D. H. Tracy, Spectrochim. Acta Part B 38 B (1983) 1227 – 1253.
- 85 P. W. J. M. Boumans, M. C. Lux-Steiner, Spectrochim. Acta Part B 37 B (1982) 97 – 126.
- 86 J. A. C. Broekaert, F. Leis, K. Laqua, Talanta 28 (1981) 745 – 752.
- 87 K. Vermeiren, C. Vandecasteele, R. Dams, Analyst (London) 115 (1990) 17 – 22.
- 88 K. Dittrich et al., J. Anal. At. Spectrom. 3 (1993) 1105 – 1110.
- 89 A. G. Cox, L. G. Cook, C. W. McLeod, Analyst (London) 110 (1985) 331 – 333.
- 90 H. G. C. Human, R. H. Scott, A. R. Oakes, C. D. West, Analyst (London) 101 (1976) 265 – 271.
- 91 A. Lemarchand, G. Labarraque, P. Masson, J. A. C. Broekaert, J. Anal. At. Spectrom. 2 (1987) 481 – 484.
- 92 T. Ishizuka, Y. Uwamino, Spectrochim. Acta Part B 38 B (1983) 519 – 527.
- 93 R. K. Skogerboe, G. N. Coleman, Anal. Chem. 48 (1976) 611 A – 622 A.
- 94 A. E. Croslyn, B. W. Smith, J. D. Winefordner, Crit. Rev. Anal. Chem. 27 (1997) 199 – 255.
- 95 R. Mavrodineanu, R. C. Hughes, Spectrochim. Acta 19 (1963) 1309 – 1307.
- 96 A. Disam, P. Tschöpel, G. Tölg, Fresenius' Z. Anal. Chem. 310 (1982) 131 – 143.
- 97 S. Hanamura, B. W. Smith, J. D. Winefordner, Anal. Chem. 55 (1983) 2026 – 2032.
- 98 C. I. M. Beenakker, Spectrochim. Acta Part B 32 B (1977) 173 – 178.
- 99 D. Kollotzek, P. Tschöpel, G. Tölg, Spectrochim. Acta Part B 37 B (1982) 91 – 96.
- 100 G. Heltai, J. A. C. Broekaert, F. Leis, G. Tölg, Spectrochim. Acta Part B 45 B (1990) 301 – 311.
- 101 P. S. Moussanda, P. Ranson, J. M. Mermet, Spectrochim. Acta Part B 40 B (1985) 641 – 651.
- 102 D. Kollotzek et al., Fresenius' Z. Anal. Chem. 318 (1984) 485 – 489.
- 103
P. Uden:
Element-Specific Chromatographic Detection by Atomic Emission Spectroscopy,
American Chemical Society,
Washington
1992.
10.1021/bk-1992-0479 Google Scholar
- 104 J. Hubert, M. Moisan, A. Ricard, Spectrochim. Acta Part B 33 B (1979) 1 – 10.
- 105 U. Richts, J. A. C. Broekaert, P. Tschöpel, G. Tölg, Talanta 38 (1991) 863 – 869.
- 106 Q. Jin, C. Zhu, M. W. Borer, G. M. Hieftje, Spectrochim. Acta Part B 46 B (1991) 417 – 430.
- 107 R. M. Barnes, E. E. Reszke, Anal. Chem. 62 (1990) 2650.
- 108 K. A. Forbes, E. E. Reszke, P. C. Uden, R. M. Barnes, J. Anal. At. Spectrom. 6 (1991) 57.
- 109
R. K. Marcus (ed.):
Glow Discharge Spectroscopies,
Plenum Press,
New York
1993.
10.1007/978-1-4899-2394-3 Google Scholar
- 110 K. I. Zil'bershtein: Spectrochemical Analysis of Pure Substances, A. Hilger, Bristol 1977, pp. 173 – 227.
- 111 B. Thelin, Appl. Spectrosc. 35 (1981) 302 – 307.
- 112 S. Caroli: Improved Hollow Cathode Lamps for Atomic Spectroscopy, Ellis Horwood, Chichester 1985.
- 113 H. Falk, E. Hoffmann, C. Lüdke, Spectrochim. Acta Part B 39 B (1984) 283 – 294.
- 114 W. Grimm, Spectrochim. Acta Part B 23 B(1968) 443 – 454.
- 115 J. B. Ko, Spectrochim. Acta Part B 39 B (1984) 1405 –1423.
- 116 F. Leis, J. A. C. Broekaert, K. Laqua, Spectrochim. Acta Part B 42 B (1987) 1169 – 1176.
- 117 A. Bengtson, Spectrochim. Acta Part B 40 B (1985) 631 – 639.
- 118 R. M. Lowe, Spectrochim. Acta Part B 31 B (1978) 257 – 261.
- 119 N. P. Ferreira, J. A. Strauss, H. G. C. Human, Spectrochim. Acta Part B 38 B (1983) 899 – 911.
- 120 J. A. C. Broekaert, R. Pereiro, T. K. Starn, G. M. Hieftje, Spectrochim. Acta Part B 48 B (1983) 1207–1220.
- 121 M. R. Winchester, C. Lazik, R. K. Marcus, Spectrochim. Acta Part B 46 B (1991) 483 – 499.
- 122 N. Jakubowski, D. Stüwer, W. Vieth, Fresenius' Z. Anal. Chem. 331 (1988) 145 – 149.
Further Reading
-
S. Ahuja:
Trace and Residue Analysis,
Kirk Othmer Encyclopedia of Chemical Technology,
5th edition,
John Wiley & Sons,
Hoboken, NJ,
online DOI: 10.1002/0471238961.2018010301082110.a01.
10.1002/0471238961.2018010301082110.a01 Google Scholar
- J. M. Andrade-Garda: Basic Chemometric Techniques in Atomic Spectroscopy, RSC Publ., Cambridge 2009.
-
A. Corney:
Atomic and Laser Spectroscopy,
Clarendon Press,
Oxford
2006.
10.1093/acprof:oso/9780199211456.001.0001 Google Scholar
- T. Fujimoto, A. Iwamae: Plasma Polarization Spectroscopy, Springer, Heidelberg, 2007.
-
G. Gauglitz:
Spectroscopy,
Kirk Othmer Encyclopedia of Chemical Technology,
5th edition,
John Wiley & Sons,
Hoboken, NJ,
online DOI: 10.1002/0471238961.1916050313030415.a01.pub2.
10.1002/0471238961.1916050313030415.a01.pub2 Google Scholar
- V. K. Jain: Introduction to Atomic and Molecular Spectroscopy, Alpha Science, Oxford 2007.
- H.-J. Kunze: Introduction to Plasma Spectroscopy, Springer, Heidelberg 2009.