Combinatorial Methods in Catalysis and Materials Science

Oliver Brümmer

Oliver Brümmer

Symyx Technologies, Inc., Santa Clara, CA 95051, USA

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Keith A. Hall

Keith A. Hall

Symyx Technologies, Inc., Santa Clara, CA 95051, USA

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Margarete Leclerc

Margarete Leclerc

Symyx Technologies, Inc., Santa Clara, CA, USA, 95051

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Silvia E. Lee

Silvia E. Lee

Symyx Technologies, Inc., Santa Clara, CA, USA, 95051

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Vince Murphy

Vince Murphy

Symyx Technologies, Inc., Santa Clara, CA, USA, 95051

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First published: 15 January 2003
Citations: 1

Abstract

The article contains sections titled:

1.

Introduction

2.

Enzyme Mimetics and Metal Complexes as Enzyme Mimetics

2.1.

Combinatorial Libraries of Catalysts as Enzyme Mimetics

2.2.

Combinatorial Synthesis Enzyme Mimetics

2.2.1.

Hydrolytically Active Metal Complexes

2.2.2.

Evolutionary Solid-Phase Synthesis of Oxygenase Mimics

2.2.3.

Libraries of Organic Acylation Catalysts

3.

Combinatorial Catalysis in Asymmetric Synthesis

3.1.

Combinatorial Catalyst Libraries in Enantioselective Additions of Dialkylzinc Reagents

3.2.

Ligands for the Lewis Acid-Catalyzed Asymmetric Aza Diels - Alder Reaction

3.3.

Divergent Ligand Synthesis for Enantioselective Alkylations

3.4.

Chiral Phosphine Ligands for Asymmetric Hydrogenation

3.5.

Asymmetric Reactions Catalyzed by Schiff Base-Type Ligands: the Positional Scanning Approach

3.6.

Identification of Novel Catalysts for Asymmetric Epoxidations by the Positional Scanning Approach

4.

Multidimensional Combinatorial Screening for the Identification of Novel Catalysts

4.1.

Catalyst Discovery and Optimization Using Catalyst Arrays

4.2.

Parallel Array Screening for Catalyst Optimization Using Discovery and Focused Ligand Libraries

5.

One-Pot, Multi-Substrate Screening

6.

Combinatorial Approaches to Olefin Polymerization Catalysts

7.

Combinatorial Inorganic Catalysis

7.1.

Combinatorial Libraries of Homogeneous Polyoxometalate-Based Catalysts

7.2.

Combinatorial Libraries and High-Throughput Screening of Heterogenous Polyoxometalate Catalysts

8.

Combinatorial Heterogeneous Catalysis

8.1.

Oxidative Dehydrogenation of Ethane

8.2.

Oxidative Dehydrogenation of Propane

8.3.

Catalytic Oxidation of CO and Reduction of NO

9.

Combinatorial Electrocatalysis

9.1.

Electrocatalysts for Fuel Cells

9.2.

Combinatorial Electrosynthesis

10.

High-throughput Screening Tools for Catalysis

11.

Combinatorial Solid-State Materials Science

11.1.

Materials Library Synthesis

11.1.1.

Vapor Deposition Techniques

11.1.2.

Alternative Library Synthesis Techniques

11.2.

High-Throughput Screening for Materials

11.2.1.

Optical Screening

11.2.2.

X-Ray Characterization

11.3.

Applications of Materials

11.3.1.

Superconductivity

11.3.2.

Ferromagnetic Semiconductors

11.3.3.

Magnetoresistant Materials

11.3.4.

Dielectric and Ferroelectric Materials

11.3.5.

Luminescent Materials

12.

Organic Materials and Polymers

12.1.

Schiff Bases for Nonlinear Optical (NLO) Materials

12.2.

Artificial Receptors for Small Organic Molecules

12.3.

New Materials for the Separation of Enantiomers

12.4.

Molecular Imprinting

12.5.

Polymer Topologies and Functionalization

13.

Summary and Outlook

The full text of this article hosted at iucr.org is unavailable due to technical difficulties.