Rubber, 3. Synthetic
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Rubber, 4. Emulsion Rubbers
Rubber, 5. Solution Rubbers
Rubber, 7. Synthesis by Polyaddition, Polycondensation, and Other Mechanisms
Rubber, 3. Synthetic
Rubber, 3. Synthetic
Rubber, 3. Synthetic
Rubber, 3. Synthetic
Judit E. Puskas
University of Western Ontario, Department of Chemical and Biochemical Engineering, London, Ontario, Canada
Search for more papers by this authorAndreas Ostrowicki
Polysar Rubber Corporation, Sarnia, Ontario, Canada
Search for more papers by this authorJudit E. Puskas
University of Western Ontario, Department of Chemical and Biochemical Engineering, London, Ontario, Canada
Search for more papers by this authorAndreas Ostrowicki
Polysar Rubber Corporation, Sarnia, Ontario, Canada
Search for more papers by this authorAbstract
The article contains sections titled:
1. |
Introduction |
1.1. |
Market and Areas of Application |
1.2. |
Nomenclature and Classification |
1.3. |
Properties |
1.4. |
Production |
1.5. |
Producers |
2. |
Emulsion Rubbers |
2.1. |
Emulsion Styrene - Butadiene Rubber (E-SBR) |
2.1.1. |
Properties, Grades, and Application |
2.1.2. |
Basic Chemistry and Production Processes |
2.1.3. |
Producers and Production Capacities |
2.2. |
Chloroprene Rubber (CR) |
2.2.1. |
Properties, Grades, and Applications |
2.2.2. |
Basic Chemistry and Production Processes |
2.2.3. |
Producers and Production Capacities |
2.3. |
Nitrile Rubber (NBR) |
2.3.1. |
Properties, Grades, and Applications |
2.3.2. |
Basic Chemistry and Production Processes |
2.3.3. |
Producers and Production Capacities |
2.4. |
Emulsion Polybutadiene (E-BR) |
2.4.1. |
Properties and Applications |
2.4.2. |
Basic Chemistry and Production Processes |
2.4.3. |
Producers and Production Capacities |
2.5. |
Acrylate Rubber (ACM) |
2.5.1. |
Properties, Grades, and Applications |
2.5.2. |
Basic Chemistry and Production Processes |
2.5.3. |
Producers and Production Capacities |
2.6. |
Fluororubbers |
2.6.1. |
Chemical Composition and Properties |
2.6.2. |
Vulcanization |
2.6.3. |
Production Processes |
2.6.4. |
Producers, Production, Capacities, and Markets |
3. |
Solution Rubbers |
3.1. |
Synthesis by Anionic Polymerization |
3.1.1. |
Solution 1,3-Butadiene - Styrene Rubber (S-SBR) and Styrene - Isoprene - Butadiene Rubber (S-SIBR) |
3.1.1.1. |
Properties, Grades, and Applications |
3.1.1.2. |
Basic Chemistry and Production Processes |
3.1.1.3. |
Producers and Production Capacities |
3.1.2. |
Lithium - Butadiene (Li-BR) and Lithium - Isoprene (Li-IR) Rubber |
3.1.2.1. |
Properties, Grades, and Applications |
3.1.2.2. |
Basic Chemistry and Production Processes |
3.1.2.3. |
Producers and Production Capacities |
3.2. |
Synthesis by Ziegler - Natta Polymerization |
3.2.1. |
Polybutadiene and Polyisoprene Rubber |
3.2.1.1. |
Properties, Grades, and Applications |
3.2.1.2. |
Basic Chemistry and Production Processes |
3.2.1.3. |
Producers and Production Capacities |
3.2.2. |
Ethylene - Propene Elastomers (EPM, EPDM) |
3.2.2.1. |
Properties, Grades, and Applications |
3.2.2.2. |
Basic Chemistry and Production Processes |
3.2.2.3. |
Producers and Production Capacities |
3.3. |
Synthesis of Butyl Rubber by Cationic Polymerization |
3.3.1. |
Properties, Grades, and Applications |
3.3.1.1. |
Properties |
3.3.1.2. |
Grades |
3.3.1.3. |
Specialty Rubbers |
3.3.1.4. |
Applications |
3.3.2. |
Basic Chemistry and Production Processes |
3.3.2.1. |
Basic Chemistry |
3.3.2.2. |
Industrial Production |
3.3.3. |
Producers and Production Capacities |
3.3.4. |
Storage and Transportation |
3.3.5. |
Legal Aspects |
3.3.6. |
Toxicology and Occupational Health |
4. |
Synthesis by Radical and Other Mechanisms |
4.1. |
EVM and Ethylene Copolymers |
4.1.1. |
Properties, Grades, and Applications |
4.1.2. |
Basic Chemistry and Production Processes |
4.1.3. |
Producers and Production Capacities |
4.1.4. |
Toxicology |
4.2. |
Epoxide Rubbers (CO, ECO, GECO, GPO) |
4.2.1. |
Properties, Grades, and Applications |
4.2.2. |
Basic Chemistry and Production Processes |
4.2.3. |
Producers and Production Capacities |
4.3. |
Polynorbornene |
4.3.1. |
Production of 2-Norbornene Monomer |
4.3.2. |
Polymerization |
4.3.3. |
Properties |
4.3.3.1. |
Properties of Pure Polymer |
4.3.3.2. |
Properties of Polynorbornene Rubbers (PNR) |
4.3.4. |
Processing of PNR |
4.3.5. |
Uses |
4.3.6. |
Economic Aspects |
4.3.7. |
Toxicology |
4.4. |
Polyoctenamers |
4.4.1. |
Production of Cyclooctene |
4.4.2. |
Polymerization |
4.4.3. |
Properties |
4.4.4. |
Vulcanization, Processing, and Applications |
4.4.5. |
Economic Aspects |
4.4.6. |
Toxicology |
5. |
Synthesis by Polyaddition, Polycondensation, and Other Mechanisms |
5.1. |
Silicone Rubber |
5.1.1. |
Properties, Grades, and Applications |
5.1.2. |
Production Process and Basic Chemistry |
5.1.3. |
Producers and Markets |
5.2. |
Polyurethane Rubber |
5.3. |
Thiokol Rubber |
5.3.1. |
Properties, Grades, and Applications |
5.3.1.1. |
History |
5.3.1.2. |
Grades |
5.3.1.3. |
Mechanical Properties, Cross-Linking, and Applications |
5.3.2. |
Basic Chemistry and Production Processes |
5.3.3. |
Producers and Production Capacities |
6. |
Synthesis by Polymer Modification |
6.1. |
Halobutyl Rubber |
6.1.1. |
Introduction |
6.1.2. |
Properties, Grades, and Applications |
6.1.3. |
Basic Chemistry and Production Process |
6.1.3.1. |
Basic Chemistry |
6.1.3.2. |
Production |
6.1.4. |
Chemical Analysis |
6.1.5. |
Storage and Transportation |
6.1.6. |
Legal Aspects |
6.1.7. |
Producers and Production Capacities |
6.1.8. |
Toxicology and Occupational Health |
6.1.9. |
New Commercial Development |
6.2. |
Chloropolyethylene and Chlorosulfonyl Polyethylene |
6.2.1. |
Chloropolyethylene |
6.2.1.1. |
Properties, Grades, and Applications |
6.2.1.2. |
Basic Chemistry and Production Processes |
6.2.2. |
Chlorosulfonyl Polyethylene |
6.2.2.1. |
Properties, Grades, and Applications |
6.2.2.2. |
Basic Chemistry and Production Processes |
6.2.3. |
Producers and Production Capacities |
6.3. |
Hydrogenated Nitrile Rubber |
6.3.1. |
Properties, Grades, and Applications |
6.3.2. |
Basic Chemistry and Production Processes |
6.3.3. |
Producers and Production Capacities |
6.4. |
Polyphosphazenes |
6.4.1. |
Properties, Grades, and Applications |
6.4.1.1. |
Properties |
6.4.1.2. |
Commercial Grades and Applications |
6.4.2. |
Basic Chemistry and Production Processes |
6.4.3. |
Producers and Markets |
7. |
Thermoplastic Elastomers |
7.1. |
Introduction |
7.1.1. |
Definition |
7.1.2. |
Global Market |
7.2. |
PVC Blends |
7.3. |
Thermoplastic Polyurethanes |
7.4. |
Styrene Block Copolymers |
7.5. |
Thermoplastic Polyolefins |
7.6. |
Copolyesters |
7.7. |
Copolyether- and Copolyetheresteramides |
8. |
Evaluation of the Present Situation and Remarks on Future Trends |
8.1. |
Market, Producers, and Capacities |
8.1.1. |
Market |
8.1.2. |
Producers, Capacities and Capacity Utilization |
8.2. |
Market Requirements and Impact on Development of Synthetic Rubber |
8.2.1. |
Tires and Tire Rubber |
8.3. |
Production Processes |
8.4. |
Ecological and Health Aspects |
8.4.1. |
Introduction |
8.4.2. |
Health Aspects |
8.4.2.1. |
Raw Materials |
8.4.2.2. |
Processing |
8.4.2.3. |
Use |
8.4.3. |
Environment |
8.4.3.1. |
Recycling |
8.4.4. |
Outlook |
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- 846 Upjohn, US 3 899 467, 1974 (H. W. Bonk, T. M. Shah).
- 847 Bayer, DE-OS 3 329 775, 1983 (W. Goyert).
- 848 C. S. Schollenberger, K. Danbergs, J. Elastomers Plast. 7 (1975) 65.
- 849 L. White, Eur. Rubber J. 173 (1991) Oct., 26.
- 850 Shell, Kraton D and Kraton G Rubbers, Bulletin, no. 09, 1986.
- 851 G. Holden, N. R. Legge: Thermoplastic Elastomers; A Comprehensive Review, Hanser Verlag, New York 1987, p. 47.
- 852 L. J. Fetter, M. Marton, Macromolecules 2 (1969) 453.
- 853 A. Nostey, J. E. McGrath: Block Copolymers: Overview and Critical Survey, Academic Press, New York 1977.
- 854 P. Zelinski, C. F. Wofford, J. Polym. Sci. Part A 3 (1965) 93.
- 855 Phillips, US 3 560 593, 1971 (H. L. Henry).
- 856 Shell, US 3 644 588, 1969 (H. L. Howard).
- 857 Shell, DE 1 905 422, 1968 (H. E. de la Mare, E. F. Bullard).
- 858 Phillips, US 3 637 554, 1972 (R. D. Lundberg, J. V. Koleske, E. R. Walter).
- 859 Shell, US 3 700 633, 1972 (M. M. Wald, M. G. Quam).
- 860 Shell, US 3 595 942, 1971 (M. M. Wald, M. G. Quam).
- 861 Shell, US 3 810 957, 1965 (H. E. Lunk).
- 862 C. D. Shedd: Handbook of Thermoplastic Elastomers, 2nd ed., Van Nostrand Reinhold, New York 1988, p. 46.
- 863 Chemische Werke Hüls, DE 1 271 980, 1963 (F. Seifert, J. Bittscheidt, J. Plenikowski).
- 864 Uniroyal, DE-OS 2 202 706, 1972 (W. K. Fischer).
- 865 A. J. Tinker, R. D. Icenogle, I. Whittle, Rubber World 199 (1989) March, 25.
- 866 Monsanto, DE 2 848 448, 1977 (M. A. Albert, A.-S. Sabet).
- 867 Esso Research, US 3 037 954, 1962 (A. M. Gessler).
- 868 Monsanto, DE 2 632 654, 1975 (A. Y. Coran, B. Das, R. P. Patel).
- 869 Monsanto, EP 0 004 776, 1978 (A. Y. Coran).
- 870 Monsanto, DE 2 709 060, 1976 (A. Y. Coran, R. P. Patel).
- 871 Monsanto, DE 2 726 177, 1976 (A. Y. Coran, R. P. Patel).
- 872 Monsanto, DE 2 657 109, 1975 (A. Y. Coran, R. P. Patel).
- 873 Monsanto, EP 0 036 279, 1980 (A. Y. Coran, R. P. Patel).
- 874 A. Y. Coran, R. Patel, Rubber Chem. Technol. 54 (1981) 892.
- 875 D. Perelli, Technol. Chem. 11 (1991) no. 6, 80, 94.
- 876 Monsanto, EP 109 375, 1982 (Y. L. Wang).
- 877 Monsanto, EP 107 635, 1982 (A.-S. Sabet, K.-S. Shen).
- 878 Mitsubishi, JP 91 292 311, 1990 (T. Fujita, N. Yamamoto).
- 879 Union Carbide, EP 417 710, 1989 (M. R. Rifi, K. H. Lee, M. J. Kriss, H. T. Liu).
- 880 Union Carbide, EP 417 711, 1989 (M. R. Rifi, K. H. Lee, M. J. Kriss, H. T. Liu).
- 881 R. D. Leaversuch, Mod. Plast. Int., (1992) April, 32.
- 882 W. O. Murtland, Rubber World 166 (1972) May, 37.
- 883 Toyobo, JP 77 125 597, 1977 (H. Imanaki, T. Sugitoge, Y. Kijima).
- 884 J. W. Cary, Gummi Fasern Kunstst. 39 (1986) 330.
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- 889 R. K. Adams, G. K. Hoeschele: Thermoplastic Elastomers; A Comprehensive Review, Hanser Publ., New York 1987, p. 163.
- 890 G. Deelens: Thermoplastic Elastomers; A Comprehensive Review, Hanser Publ., New York 1987, p. 215.
- 891 W. J. Farrisey, T. M. Shah: Handbook of Thermoplastic Elastomers, 2nd ed., Van Nostrand Reinhold, New York 1988, p. 252.
- 892 Gummi Fasern Kunstst. 40 (1987) 440.
- 893 A. S. Wood, Mod. Plast. Int. (1988) April, 48.
- 894 J. T. Chapin, B. K. Onder, W. J. Farrisey, Polym. Prepr. Am. Chem. Soc. Div. Polym. Chem. 21 (1980) no. 21, 130.
- 895 Upjohn, US 4 129 715, 1978 (A. T. Chen, W. J. Farrissey, R. G. Nelb).
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- 897 A. Thorn: Thermoplastic Elastomers —An Overview, Rapra Technology Ltd., Shawbury 1996.
- 898 “USSR Uses Much Less Rubber,” Eur. Rubber J. 174 (1992) no. 3, 8 – 9.
- 899 “World Rubber Industry Declines,” “Rubber Use to Rise by 3 %,” Eur. Rubber J. 174 (1992) no. 3, 9.
- 900 J. D. Carr, P. Jumpasul, H. D. Smit: The World Rubber Economy Changes and Challenges, A Joint IRSG/ESI Study, May 1988, IRSG, ESI, London 1988, p. 260.
- 901 In (900), 202.
- 902 W. Hofmann, Kunststoffe 80 (1990) no. 10, 1204 –1209.
- 903 B. Davis, Eur. Rubber J. 178 (1996) July/Aug.
- 904 Rubber and Plastic News, 15th ed., vol. 21, 13. Rubbicana 1992 (Rubber directory and buyer's guide).
- 905 Gummi Adreßbuch mit Bezugsquellennachweis, 12th ed., Curt R. Vincentz Verlag, Hannover 1991.
- 906 D. J. Schuring (ed.): “Tyre Rolling Resistance,” Rubber Division Symposia, vol. 1, American Chemical Society, Chicago, Ill., Oct. 5 – 7, 1982.
- 907 S. Yamashita, “Progress of Synthetic Rubber Chemistry in Japan,” 24th Annual Meeting of the International Institute of Synthetic Rubber Producers, Kyoto, Japan, May 9 – 13, 1983.
- 908 A. Ueda, H. Wantanabe, S. Akita, “Structure and Properties of Newly Developed High Vinyl Poly-butadiene Rubbers,” Int. Rubber Conference, IRC 85, Kyoto, Japan, Oct. 15 – 18, 1985, p. 199 – 204.
- 909 Japan Synthetic Rubber Co., EP 134 909, priority 17.12. 1980 JP (Y. Takeuchi et al.).
- 910 L. H. Krol, “Synthetic Rubbers: Their Outlook for The Eighties,” Rubbercon 81 [Eighty Ore] Int. Rubber Conference (1981). vol. I, Harrogate, England, June 8 – 12 1981, A 3/1 – A 3/9.
- 911 K.-H. Nordsiek, K. H. Kiepert, GAK Kautsch. Gummi Kunstst. 33 (1980) no. 4, 251 – 255.
- 912 G. Day, S. Futamura, Kautsch. Gummi Kunstst. 40 (1987) no. 1, 39 – 53.
- 913 Bridgestone Tire Co., EP-A 254 766, priority 27. 08. 1981 JP (M. Ogawa, M. Ikegami).
- 914 The Goodyear Tire and Rubber Co., EP-A 438 966, priority 28. 12. 1989 US (A. F. Halasa, J. Bergh, F. A. J. Fourgon).
- 915 Sumitomo Chemical Co., EP 186 985, priority 07. 12. 1984 JP (H. Takao, N. Yoshida, A. Imai).
- 916 Michelin et Cie., BE 88 25 65, priority 01. 08. 1980 BE.
- 917 Michelin et Cie., BE 88 25 66, priority 01. 08. 1980 BE.
- 918 K.-H. Nordsiek: “Model Studies for the Development of an Ideal Tire Tread Rubber,” Meeting of the ACS Rubber Division, Indianapolis, May 8 – 11, 1984.
- 919 Bridgestone Corp., EP 476 640, priority 21. 09. 1990 (D. A. Joyner et al.).
- 920 Bridgestone Corp., EP 476 641, priority 21. 09. 1990 (J. W. Kang, T. Hashimoto).
- 921 Bridgestone Corp., EP 476 662, priority 21. 09. 1990 (J. W. Kang, G. B. Seaver, T. Hashimoto).
- 922 The Goodyear Tire and Rubber Co., EP-A 263 054, priority 29. 09. 1986 (A. F. Halasa, B. B. Gross, J. L. Cox, G. F. Balogh).
- 923 The Goodyear Tire and Rubber Co., EP-A 438 967, priority 16. 01. 1990 (W.-L. Hsu, A. F. Halasa).
- 924 The Goodyear Tire and Rubber Co., EP 483 046, priority 22. 10. 1990 (W.-L. Hsu, A. F. Halasa).
- 925 Hüls AG, EP-A 256 261, priority 14. 08. 1986 DE (C. Herrmann et al.).
- 926 Hüls AG, EP-A 302 196, priority 28. 07. 1987 DE (C. Herrmann et al.).
- 927 Hüls AG, EP-A 328 774, priority 13. 02. 1988 DE (C. Herrmann et al.).
- 928 Hüls AG, EP-A 344 441, priority 03. 06. 1988 DE (C. Herrmann et al.).
- 929 Hüls AG, EP-A 362 514, priority 05. 10. 1988 DE (W. Hellermann et al.).
- 930 Hüls AG, EP-A 362 515, priority 04. 08. 1989 DE (W. Hellermann et al.).
- 931 Hüls AG, EP-A 384 033, priority 21. 02. 1989 (J. Wolpers, C. Herrmann, W. Hellermann).
- 932 Shell Internationale Research Maatschappij B.V., EP-A 270 178, priority 02. 12. 1986 GB (A. A. Broekhuis, P. Luijk, J. E. Stamhuis).
- 933 Sumitomo Chemical Co., EP-A 270 927, priority 29. 11. 1986 JP (Y. Saito et al.).
- 934 Bayer, EP-A 405 216, priority 24. 06. 1989 DE (H.-W. Engels et al.).
- 935 I. R. Gelling, NR Technol. 18 (1987) no. 2, 21 – 29.
- 936 F. Tsutsumi, M. Sakakibara, N. Oshima: “Structure and Dynamic Properties of New Solution SBR Coupled with Tin Compound,” Meeting of the Rubber Division, American Chemical Society, Cincinnati, Ohio, Oct. 18 – 21, 1988.
- 937 A. Ueda, T. Ohyama, H. Watanabe, A. Yoshioka: “Vibration Isolation Characteristics of Chemically Modified Solution-Polymerized Rubbers for Engine Mount Use,” Meeting of the Rubber Division, American Chemical Society, Cincinnati, Ohio, Oct. 18 – 21, 1988.
- 938 H. Fries, B. Stollfuß: “Structure and Properties of Butadiene Rubber,” Meeting of the Rubber Division, American Chemical Society, Cincinatti, Ohio, Oct. 18 – 21, 1988.
- 939 M. Sakakibara, F. Tsutsumi, I. Hattori, Y. Hongu: “Structure and Properties of Diene Rubbers,” Meeting of the Rubber Division, American Chemical Society, Detroit, Mich. Oct. 8 – 11, 1991.
- 940 Asahi, EP 252 992, priority 10. 01. 1986 (Y. Kitagawa, H. Yamada, A. Saito).
- 941 Asahi, EP-A 260 325, priority 13. 03. 1986 (Y. Kitagawa, Y. Hattori, A. Saito).
- 942 Bayer, EP 218 876, priority 11. 09. 1985 (B. Stollfuß, W. Wieder, W. Nentwig).
- 943 Bridgestone Corp., EP-A 299 074, priority 14. 01. 1987 (T. Hamada, H. Fukuoka, H. Komatsu, T. Fujmaki).
- 944 Bridgestone/Firestone, Inc., EP-A 452 603, priority 09. 04. 1990 US (T. A. Antkowiak, D. F. Lawson, R. W. Koch, M. L. Stayer).
- 945 Bridgestone/Firestone, Inc., EP-A 451 604, priority 09. 04. 1990 US (M. L. Stayer, T. A. Antkowiak, D. F. Lawson, R. W. Koch).
- 946 The Goodyear Tire and Rubber Co., EP-A 316 255, priority 15. 10. 1987 US (A. F. Halasa, B. A. Matrana, S. E. Robertson-Wilcox).
- 947 Nippon Zeon Co., EP 180 141, priority 26. 10. 1984 JP (H. Watanabe, K. Noguchi, T. Kase, S. Akita).
- 948 Nippon Zeon Co., EP 180 853, priority 26. 10. 1984 JP (H. Watanabe, K. Noguchi, T. Kase, A. Shuichi).
- 949 The Yokohama Rubber Co., Nippon Zeon Co., DE-OS 3 635 366, priority 23. 10. 1985 JP (Y. Kikuchi et al.).
- 950 Sumitomo Chemical Co., EP-A 341 496, priority 02. 05. 1988 (A. Imai, T. Seki, K. Yamamoto).
- 951 Bayer, EP-A 7027, priority 08. 07. 1978 DE (G. Sylvester, J. Witte, G. Marwede).
- 952 Bayer, EP-A 11 184, priority 11. 11. 1978 DE (G. Sylvester, J. Witte, G. Marwede).
- 953 Enoxy Chimica, EP-A 92 270, priority 15. 04. 1982 IT (A. Carbonaro, D. Ferraro).
- 954 Enichem. Polimeri, EP-A 127 236, priority 25. 05. 1983 IT (A. Carbonaro, S. Gordini, S. Cucinella).
- 955 Enichem. Elastomeri, EP 201 962, priority 15. 05. 1985 IT (A. Carbonaro, S. Gordini, S. Cucinella).
- 956 Enichem. Elastomeri, EP 201 979, priority 15. 05. 1985 IT (A. Carbonaro, S. Gordini, S. Cucinella).
- 957 Enichem. Elastomeri, EP-A 204 373, priority 05. 06. 1985 IT (A. Carbonaro, D. Ferraro).
- 958 Enichem. Elastomeri, EP 207 540, priority 05. 06. 1985 IT (S. Gordini).
- 959 Enichem. Elastomeri, EP 207 558, priority 01. 07. 1985 IT (S. Gordini, A. Carbonaro, S. Spina).
- 960 Enichem. Elastomers, EP-A 375 421, priority 22. 12. 1988 (D. K. Jenkins, P. J. Ansell).
- 961 Enichem. Elastomeri, EP-A 386 808, priority 17. 02. 1989 IT (P. Andreussi, R. Bianchi).
- 962 The Goodyear Tire and Rubber Co., EP 236 253, priority 19. 02. 1986 US (M. C. Throckmorton, R. W. Stachowiak, C. L. Wilson).
- 963 Japan Synthetic Rubber Co., DE 3 224 288, priority 29. 06. 1981 JP (Y. Takeuchi, M. Sakakibara, T. Shibata).
- 964 Japan Synthetic Rubber Co., EP-A 406 920, priority 05. 09. 1988 JP (I. Hattori, M. Sakakibara, F. Tsutsumi, M. Yoshizawa).
- 965 Polysar Ltd., EP 232 592, priority 18. 11. 1975 US (D. C. Edwards, J. A. Crossman).
- 966 The Firestone Tire and Rubber Co., EP 100 434, priority 14. 07. 1982 US (G. G. A. Böhm).
- 967 Bridgestone Corp., EP-A 470 693, priority 11. 06. 1990 JP (M. Araki, Y. Morimoto).
- 968 General Tire Inc., EP 263 216, priority 02. 09. 1986 US (J. L. Palombo, R. L. Miller).
- 969 The Goodyear Tire and Rubber Co., EP 231 143, priority 23. 01. 1986 US (A. J. Bell).
- 970 The Goodyear Tire and Rubber Co., EP-A 357 535, priority 24. 08. 1988 US (G. L. Burroway, G. F. Magoun, R. N. Gujarathi).
- 971 The Goodyear Tire and Rubber Co., EP-A 359 694, priority 14. 09. 1988 US (R. M. Scriver, W.-L. Hsu, A. F. Halasa).
- 972 The Goodyear Tire and Rubber Co., EP-A 434 596, priority 21. 12. 1989 US (B. R. Hahn, W.-L. Hsu, D. D. Callander, A. F. Halasa).
- 973 The Goodyear Tire and Rubber Co., EP-A 468 914, priority 26. 07. 1990 US (D. B. Patterson, A. F. Halasa).
- 974 The Goodyear Tire and Rubber Co., EP 476 305, priority 23. 08. 1990 (W. C. T. Tung et al.).
- 975 The Goodyear Tire and Rubber Co., EP 477 635, priority 17. 09. 1990 (G. Cohn, D. D. Callander, W. C. T. Tung).
- 976 The Goodyear Tire and Rubber Co., EP-A 470 040, priority 02. 08. 1990 US (G. O. Schulz, D. K. Parker).
- 977 The Goodyear Tire and Rubber Co., EP 482 478, priority 24. 10. 1990 (W.-L. Hsu, A. F. Halasa).
- 978 Hüls AG, EP-A 258 554, priority 19. 08. 1986 DE (R. Ollenik, W. Kleinert, M. Müller).
- 979 Industrie Pirelli S.p.A., GB 2 122 110, priority 24. 06. 1982 IT (P. L. Robicci).
- 980 Pirelli Coordinamento Pneumatici S.p.A., EP 408 941, priority 21. 07. 1989 IT (M. Mezzanotte).
- 981 Pirelli Coordinamento Pneumatici S.p.A., EP 454 025, priority 24. 04. 1990 IT (P. Borgonovo, G. Ghilardi).
- 982 Sumitomo Rubber Industries, EP-A 426 388, priority 26. 10. 1989 JP (S. Takatsu, K. Muraoka).
- 983 Michelin et Cie., DE-OS 3 149 716, priority 16. 12. 1980 FR (P. Durif).
- 984 Michelin et Cie., DE-OS 3 209 581, priority 16. 03. 1981 FR (C. Ancel, P. Philibert).
- 985 Michelin et Cie., EP 220 642, priority 24. 10. 1985 FR (J. Gouttebess, P. Villaine).
- 986 Höchst AG, EP 149 836, priority 07. 01. 1984.
- 987 Mitsubishi Rayon Co. Ltd., EP-A 423 759, priority 18. 10. 1989 JP (Y. Fukuda, H. Inada, H. Sato).
- 988 E. I. Du Pont, EP-A 426 019, priority 31. 10. 1989 US (F. Y. Kafka).
- 989 Du Pont, EP-A 426 024, priority 31. 10. 1989 US (F. Y. Kafka).
- 990 Bayer, EP-A 255 632, priority 02. 08. 1986 DE (J. Peter, G. Pampus).
- 991 Polysar Ltd., EP 265 671, priority 29. 09. 1986 US (J. Odar, W. von Hellens).
- 992 Bridgestone Tire Co., Japan Synthetic Rubber Co., DE 3 228 547, priority 31. 07. 1981 JP (Y. Takeuchi et al.).
- 993 The Firestone Tire and Rubber Comp., EP 139 848, priority 06. 09. 1983 US (D. F. Graves).
- 994 The Firestone Tire and Rubber Corp., EP 197 285, priority 21. 03. 1985 US (W. W. Schloman, J. A. Davis).
- 995 Bridgestone Corp., DE-OS 3 628 844, priority 27. 08. 1985 JP (E. Takiguchi, T. Kikutsugi).
- 996 The Firestone Tire and Rubber Corp., EP 234 303, priority 14. 02. 1986 US (S. Futamura).
- 997 Continental Gummi-Werke AG, Deutsches Institut Kautschuktechnologie e.V., DE-OS 3 626 240, priority 02. 08. 1986 DE (J. Peter, G. Pampus).
- 998 Continental AG, DE 3 720 461, priority 20. 06. 1987 DE (R. Mahling, W. Klapp, W. Holzbach).
- 999 Continental AG, DE-OS 3 740 303, priority 27. 11. 1987 DE (G. Kaiser, J. Peter).
- 1000 Continental AG, EP-A 366 915, priority 31. 10. 1988 DE (H. Stevens, G. Kaiser).
- 1001 The Goodyear Tire and Rubber Corp., EP-A 448 904, priority 28. 03. 1990 US (J. K. Clark).
- 1002 Hüls AG, EP 168 524, priority 05. 07. 1984 DE (K.-H. Nordsiek, H. Schwesig).
- 1003 Hüls AG, EP 173 791, priority 18. 04. 1984 DE (K.-H. Nordsiek, J. Wolpers, J. Tornau).
- 1004 Hüls AG, EP-A 333 999, priority 23. 03. 1988 DE (R. Tappe).
- 1005 Japan Synthetic Rubber Co., Bridgestone Corp., DE-OS 3 636 970, priority 30. 10. 1985 JP (F. Tsutsumi et al.).
- 1006 Japan Synthetic Rubber Co., Bridgestone Corp., EP-A 328 284, priority 01. 02. 1988 JP (M. Sakakibara, F. Tsutsumi, M. Kondo, Y. Yagi).
- 1007 Japan Synthetic Rubber Co., EP-A 405 904, priority 26. 09. 1989 JP (M. Kondo, I. Sugita, I. Furuta, F. Tsutsumi).
- 1008 The Goodyear Tire and Rubber Co., EP 477 682, priority 24. 09. 1990 (T. D. Linster).
- 1009 Pirelli Coordinamento Pneumatici S.p.A., EP-A 448 112, priority 23. 03. 1990 IT (L. Garro, M. Martin).
- 1010 Sumitomo Chemical Co., EP 263 885, priority 10. 04. 1986 JP (H. Takao et al.).
- 1011 Uniroyal Chemical Co., EP-A 342 288, priority 20. 05. 1988 (J. M. Mitchell, D. E. Wingrove, C. F. Eckert).
- 1012 Bayer, EP-A 313 917, priority 24. 10. 1987 and 02. 06. 1988 DE (W. Obrecht, Z. Szentivanyi).
- 1013 The Firestone Tire and Rubber Comp., EP 151 212, priority 09. 01. 1984 US (T. F. Donatelli, P. F. Murray).
- 1014 Bridgestone Corp., DE 3 540 456, priority 15. 11. 1984 JP (Y. Hirata et al.).
- 1015 The Firestone Tire and Rubber Co., EP 177 695, priority 21. 09. 1984 US (D. P. Tate, D. F. Graves).
- 1016 The Firestone Tire and Rubber Co., EP-A 287 806, priority 13. 04. 1987 (D. F. Graves, H. W. Engels).
- 1017 Bridgestone Corp., EP 328 291, priority 02. 02. 1988 (T. Yamada, R. Fujio).
- 1018 Bridgestone Corp., EP-A 333 317, priority 16. 02. 1988 (I. Nakajima, K. Hatakeyama, Y. Hirata).
- 1019 Bridgestone Corp., EP-A 405 827, priority 29. 06. 1989 JP (T. Saito, J. Yatsunami, I. Wada, T. Takizawa).
- 1020 Continental Gummi-Werke AG, DE-OS 3 033 711, priority 08. 09. 1980 DE (R. Sohnemann).
- 1021 Semperit Reifen Aktiengesellschaft, EP-A 406 214, priority 28. 06. 1989 AT (O. Beckmann).
- 1022 The Goodyear Tire and Rubber Co., EP 149 956, priority 06. 01. 1984 US (P. H. Sandstrom).
- 1023 The Goodyear Tire and Rubber Co., EP-A 335 817, priority 29. 03. 1988 US (L. G. Wideman, G. F. Castner).
- 1024 The Goodyear Tire and Rubber Co., EP-A 363 302, priority 06. 10. 1988 US (S. K. Mowdood, B. K. Kansupada).
- 1025 Hüls AG, EP-A 385 072, priority, 1989 DE (G. Hörpel, K.-H. Nordsiek).
- 1026 Hüls AG, EP-A 432 416, priority 12. 12. 1989 DE (G. Hörpel, H. G. Haag, K.-H. Nordsiek).
- 1027 Sumitomo Rubber Industries, EP-A 386 905, priority 04. 03. 1989 GB (B. D. W. Powell).
- 1028 Sumitomo Chemical Co., EP-A 345 594, priority 07. 06. 1988 (I. Kurimoto, N. Inui, T. Yamaguchi).
- 1029 Sumitomo Chemical Co., EP-A 409 565, priority 17. 07. 1989 JP (N. Inui, H. Nagasaki, S. Yachigo, M. Oikawa).
- 1030 The Goodyear Tire and Rubber Co., EP 476 310, priority 28. 08. 1990 (L. G. Wideman, P. H. Sandstorm, G. F. Balogh, D. J. Keith).
- 1031 Continental AG, DE-OS 3 924 528, priority 25. 07. 1989 DE (H. Stevens, R. Teves).
- 1032 Continental AG, DE-OS 3 924 529, priority 25. 07. 1989 DE (H. Stevens, R. Teves).
- 1033 Continental AG, DE-OS 3 924 530, priority 25. 07. 1989 DE (H. Stevens, R. Teves).
- 1034 Continental AG, EP-A 410 311, priority 25. 07. 1989 DE (H. Stevens, R. Teves).
- 1035 Nippon Zeon Co., EP-A 420 449, priority 18. 09. 1989 JP (Y. Saito).
- 1036 Degussa AG, EP-A 468 140, priority 25. 07. 1990 DE (S. Wolff, U. Göre).
- 1037 M. Nedev, E. Karadimova, GAK Kautsch. Gummi Kunstst. 44 (1991) no. 12, 1133.
- 1038 M. Nedev, E. Karadimova, GAK Kautsch. Gummi Kunstst. 45 (1992) no. 1, 30 – 31.
- 1039 Compagnie Générale Des Etablissements Michelin – Michelin & Cie, EP-A 501 227, priority 25. 02. 91 (R. Rauline)
- 1040 G. W. Marwede, B. Stollfuß, A. J. M. Sumner: “Current Status of Tyre Elastomers in Europe,” IISRP Meeting, Cancon/Mexico, May 4 – 6, 1992.
- 1041 Polysar Ltd., US 4 645 793, priority 19. 12. 1985 US (W. von Hellens, Sheikh A. H. Mohammed, R. Hallman).
- 1042 Bridgestone Corporation, US 4 886 850, priority 17. 06. 1986 JP (M. Ogawa, Y. Shiomura, T. Takizawa).
- 1043 Bridgestone/Firestone Inc., EP-A 463 205, 1990 (A. E. Oberster, C. M. Roland, G. G. A. Böhm).
- 1044 The Goodyear Tire and Rubber Co., EP 240 448, priority 05. 03. 1986 US (T. J. Botzman).
- 1045 The Goodyear Tire and Rubber Co., EP-A 448 903, priority 26. 03. 1990 US (R. J. Gartland, A. F. Finelli, A. J. Bell).
- 1046 Sumitomo Chemical Co., EP-A 447 191, priority 12. 03. 1990 JP (Y. Keisaku et al.).
- 1047 Uniroyal Chemical Co., US 4 973 627, priority 13. 10. 1989 US (J. M. Mitchell).
- 1048 Mitsui Petrochemical Industries Ltd., EP-A 446 480, priority 05. 10. 1989 JP (H. Nakahama, T. Mishima).
- 1049 Mitsui Petrochemical Industries Ltd., EP-A 446 382, priority 05. 10. 1989 JP (H. Nakahama, T. Mishima).
- 1050 W. von Hellens, D. C. Edwards, Z. J. Lobos, Rubber and Plastic News, (1990) Oct. 1, 61 – 64.
- 1051 Polysar Ltd., US 4 665 963, priority 19. 10. 1984 US (J. Timar, Sheikh A. H. Mohammed, J. Walker).
- 1052 Polysar Ltd., US 4 614 772, priority 26. 09. 1985 US (D. C. Edwards, D. Padlija).
- 1053 Polysar Ltd., EP-A 314 416, priority 28. 10. 1987 US (Sheikh A. H. Mohammed, C. W. von Hellens).
- 1054 Exxon Research and Engineering Co., US 4 384 072, priority 30. 09. 1981 US (N. F. Newman, R. C. Kowalski).
- 1055 Exxon Research and Engineering Co., US 4 632 963, priority 05. 04. 1984 US (I. J. Gardner et al.).
- 1056 Exxon Chemical Patents Inc., EP-A 320 263, priority 11. 12. 1987 US (K. W. Powers, H.-C. Wang, D. C. Handy, J. V. Fusco).
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- 1058 Exxon Chemical Patents Inc., WO 91/18050, priority 14. 05. 1990 (D. F. Kruse, R. C. Keller).
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- 1286 EU Directive 93/11/EEC.
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