Pigments, Inorganic

Hans G. Völz

Hans G. Völz

Krefeld, Germany

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Jürgen Kischkewitz

Jürgen Kischkewitz

Bayer AG, Krefeld, Germany

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Peter Woditsch

Peter Woditsch

Bayer AG, Krefeld, Germany

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Axel Westerhaus

Axel Westerhaus

Bayer AG, Krefeld, Germany

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Wolf-Dieter Griebler

Wolf-Dieter Griebler

Sachtleben Chemie GmbH, Duisburg, Germany

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Marcel De Liedekerke

Marcel De Liedekerke

Zinkwit Nederland bv, Eijsden, The Netherlands

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Gunter Buxbaum

Gunter Buxbaum

Bayer AG, Leverkusen, Germany

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Helmut Printzen

Helmut Printzen

Bayer AG, Krefeld, Germany

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Manfred Mansmann

Manfred Mansmann

Bayer AG, Krefeld, Germany

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Dieter Räde

Dieter Räde

Bayer AG, Krefeld, Germany

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Gerhard Trenczek

Gerhard Trenczek

Bayer AG, Krefeld, Germany

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Volker Wilhelm

Volker Wilhelm

Bayer AG, Krefeld, Germany

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Stefanie Schwarz

Stefanie Schwarz

BASF Aktiengesellschaft, Ludwigshafen, Germany

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Henning Wienand

Henning Wienand

BASF Aktiengesellschaft, Ludwigshafen, Germany

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Jörg Adel

Jörg Adel

BASF Aktiengesellschaft, Ludwigshafen, Germany

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Gerhard Adrian

Gerhard Adrian

Langelsheim, Germany

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Karl Brandt

Karl Brandt

Dr. Hans Heubach GmbH & Co. KG, Langelsheim, Germany

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William B. Cork

William B. Cork

Reckitt's Colours Ltd., Hull, United Kingdom

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Heinrich Winkeler

Heinrich Winkeler

Degussa AG, Hanau, Germany

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Wielfried Mayer

Wielfried Mayer

Degussa AG, Hanau, Germany

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Klaus Schneider

Klaus Schneider

Degussa AG, Frankfurt/Main, Germany

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Lutz Leitner

Lutz Leitner

Bayer AG, Krefeld, Germany

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Hendrik Kathrein

Hendrik Kathrein

Bayer AG, Krefeld, Germany

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Ekkehard Schwab

Ekkehard Schwab

BASF Aktiengesellschaft, Ludwigshafen, Germany

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Helmut Jakusch

Helmut Jakusch

BASF Aktiengesellschaft, Ludwigshafen, Germany

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Manfred Ohlinger

Manfred Ohlinger

BASF Aktiengesellschaft, Ludwigshafen, Germany

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Ronald Veitch

Ronald Veitch

BASF Aktiengesellschaft, Ludwigshafen, Germany

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Günter Etzrodt

Günter Etzrodt

BASF Lacke+Farben AG, Besigheim, Germany

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Gerhard Pfaff

Gerhard Pfaff

E. Merck KGaA, Darmstadt, Germany

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Klaus-Dieter Franz

Klaus-Dieter Franz

E. Merck KGaA, Darmstadt, Germany

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Ralf Emmert

Ralf Emmert

E. M. Industries, Hawthorne, New York, United States

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Katsuhisa Nitta

Katsuhisa Nitta

Merck Japan, 970/04 Onahama, Japan

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Robert Besold

Robert Besold

Eckart-Werke, Fürth, Germany

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Harald Gaedcke

Harald Gaedcke

BASF Lacke+Farben AG, Stuttgart, Germany

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First published: 15 December 2006
Citations: 13

Abstract

The article contains sections titled:

1.

Introduction

1.1.

General Aspects

1.2.

General Chemical and Physical Properties

1.2.1.

Fundamental Aspects

1.2.2.

Methods of Determination

1.3.

Color Properties

1.3.1.

Fundamental Aspects

1.3.2.

Color Measurement

1.3.3.

Tinting Strength, Lightening Power, and Scattering Power

1.3.4.

Hiding Power and Transparency

1.4.

Stability Towards Light, Weather, Heat, and Chemicals

1.4.1.

Fundamental Aspects

1.4.2.

Test Methods

1.4.2.1.

Light Stability

1.4.2.2.

Weather Resistance

1.4.2.3.

Heat Stability

1.4.2.4.

Fastness to Chemicals

1.5.

Behavior of Pigments in Binders

1.5.1.

Fundamental Aspects

1.5.2.

Test Methods

1.5.2.1.

Pigment - Binder Interaction

1.5.2.2.

Dispersing Behavior in Paint Systems

1.5.2.3.

Miscellaneous Pigment - Binder Systems

2.

White Pigments

2.1.

Titanium Dioxide

2.1.1.

Properties

2.1.2.

Raw Materials

2.1.2.1.

Natural Raw Materials

2.1.2.2.

Synthetic Raw Materials

2.1.3.

Production

2.1.3.1.

Sulfate Method

2.1.3.2.

The Chloride Process

2.1.3.3.

Pigment Quality

2.1.3.4.

Aftertreatment

2.1.3.5.

Problems with Aqueous and Gaseous Waste

2.1.4.

Economic Aspects

2.1.5.

Pigment Properties

2.1.6.

Analysis

2.1.7.

Uses of Pigmentary TiO2

2.1.8.

Uses of Nonpigmentary TiO2

2.1.9.

Toxicology

2.2.

Zinc Sulfide Pigments

2.2.1.

Properties

2.2.2.

Production

2.2.3.

Commercial Products

2.2.4.

Uses

2.2.5.

Economic Aspects

2.2.6.

Toxicology

2.3.

Zinc Oxide (Zinc White)

2.3.1.

Introduction

2.3.2.

Properties

2.3.3.

Production

2.3.4.

Quality Specifications

2.3.5.

Uses

2.3.6.

Economic Aspects

2.3.7.

Toxicology and Occupational Health

3.

Colored Pigments

3.1.

Oxides and Hydroxides

3.1.1.

Iron Oxide Pigments

3.1.1.1.

Natural Iron Oxide Pigments

3.1.1.2.

Synthetic Iron Oxide Pigments

3.1.1.3.

Toxicology and Environmental Aspects

3.1.1.4.

Quality

3.1.1.5.

Uses

3.1.1.6.

Economic Aspects

3.1.2.

Chromium Oxide Pigments

3.1.2.1.

Properties

3.1.2.2.

Production

3.1.2.3.

Quality Specifications and Analysis

3.1.2.4.

Storage and Transportation

3.1.2.5.

Uses

3.1.2.6.

Economic Aspects

3.1.2.7.

Toxicology and Occupational Health

3.1.3.

Mixed Metal Oxide Pigments

3.1.3.1.

Properties

3.1.3.2.

Production

3.1.3.3.

Quality Specifications and Analysis

3.1.3.4.

Storage and Transportation

3.1.3.5.

Legal Aspects

3.1.3.6.

Uses

3.1.3.7.

Economic Aspects

3.1.3.8.

Toxicology and Occupational Health

3.2.

Cadmium Pigments

3.2.1.

Cadmium Sulfide

3.2.2.

Cadmium Yellow

3.2.3.

Cadmium Sulfoselenide (Cadmium Red)

3.2.4.

Cadmium Mercury Sulfide (Cadmium Cinnabar)

3.2.5.

Properties and Uses

3.2.6.

Quality Specifications

3.2.7.

Economic Aspects

3.2.8.

Toxicology and Environmental Protection

3.3.

Bismuth Pigments

3.3.1.

Properties

3.3.2.

Production

3.3.3.

Uses

3.3.4.

Toxicology

3.4.

Chromate Pigments

3.4.1.

Chrome Yellow

3.4.2.

Molybdate Red and Molybdate Orange

3.4.3.

Chrome Orange

3.4.4.

Chrome Green and Fast Chrome Green

3.4.5.

Toxicology and Occupational Health

3.5.

Ultramarine Pigments

3.5.1.

Chemical Structure

3.5.2.

Properties

3.5.3.

Production

3.5.4.

Uses

3.5.5.

Toxicity and Environmental Aspects

3.5.6.

Economic Aspects

3.6.

Iron Blue Pigments

3.6.1.

Structure

3.6.2.

Production

3.6.3.

Properties

3.6.4.

Uses

3.6.5.

Toxicology and Environmental Aspects

4.

Specialty Pigments

4.1.

Magnetic Pigments

4.1.1.

Iron Oxide Pigments

4.1.2.

Cobalt-Containing Iron Oxide Pigments

4.1.3.

Chromium Dioxide

4.1.4.

Metallic Iron Pigments

4.1.5.

Barium Ferrite Pigments

4.2.

Anticorrosive Pigments

4.2.1.

Principles

4.2.2.

Phosphate Pigments

4.2.2.1.

Zinc Phosphate

4.2.2.2.

Aluminum Phosphate

4.2.2.3.

Chromium Phosphate

4.2.2.4.

New Pigments Based on Metal Phosphates

4.2.2.5.

Multiphase Phosphate Pigments

4.2.3.

Other Phosphorus-Containing Pigments

4.2.4.

Borosilicate Pigments

4.2.5.

Borate Pigments

4.2.6.

Chromate Pigments

4.2.7.

Molybdate Pigments

4.2.8.

Lead and Zinc Cyanamides

4.2.9.

Ion-Exchange Pigments

4.2.10.

Metal Oxide Pigments

4.2.10.1.

Red Lead

4.2.10.2.

Calcium Plumbate

4.2.10.3.

Zinc and Calcium Ferrites

4.2.10.4.

Zinc Oxide

4.2.11.

Powdered Metal Pigments

4.2.11.1.

Zinc Dust

4.2.11.2.

Lead Powder

4.2.12.

Flake Pigments

4.2.13.

Organic Pigments

4.2.14.

Toxicology

4.3.

Luster Pigments

4.3.1.

Nacreous and Interference Pigments

4.3.1.1.

Optical Principles

4.3.1.2.

Natural Pearl Essence

4.3.1.3.

Basic Lead Carbonate

4.3.1.4.

Bismuth Oxychloride

4.3.1.5.

Metal Oxide - Mica Pigments

4.3.1.6.

New Developments

4.3.1.7.

Uses

4.3.2.

Metal Effect Pigments

4.4.

Transparent Pigments

4.4.1.

Transparent Iron Oxides

4.4.2.

Transparent Iron Blue

4.4.3.

Transparent Cobalt Blue and Green

4.4.4.

Transparent Titanium Dioxide

4.4.5.

Transparent Zinc Oxide

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