Paints and Coatings

Dieter Stoye

Dieter Stoye

(retired)

Hüls AG, Marl, Federal Republic of Germany

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Werner Funke

Werner Funke

Institut für Technische Chemie, Stuttgart, Federal Republic of Germany

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Lutz Hoppe

Lutz Hoppe

Wolff Walsrode AG, Walsrode, Federal Republic of Germany

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Jürgen Hasselkus

Jürgen Hasselkus

Krahn Chemie GmbH, Hamburg, Federal Republic of Germany

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Larry G. Curtis

Larry G. Curtis

Eastman Chemical Products, Kingsport, Tennessee, United States, 37662

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Klaus Hoehne

Klaus Hoehne

Bayer AG, Leverkusen, Federal Republic of Germany

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Hans-Joachim Zech

Hans-Joachim Zech

Hüls AG, Marl, Federal Republic of Germany

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Peter Heiling

Peter Heiling

Wacker-Chemie GmbH, Burghausen, Federal Republic of Germany

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Masaaki Yamabe

Masaaki Yamabe

Asahi Glass Co. Ltd., Hazawa-cho, Kanagawa-ku, Yokohama, Japan

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Klaus Dören

Klaus Dören

Hüls AG, Marl, Federal Republic of Germany

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Hans Schupp

Hans Schupp

BASF AG, Ludwigshafen, Federal Republic of Germany

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Rolf Küchenmeister

Rolf Küchenmeister

Bayer AG, Leverkusen, Federal Republic of Germany

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Martin Schmitthenner

Martin Schmitthenner

Hüls AG, Witten, Federal Republic of Germany

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Wolfgang Kremer

Wolfgang Kremer

Bayer AG, Krefeld-Uerdingen, Federal Republic of Germany

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Wolfhart Wieczorrek

Wolfhart Wieczorrek

Bayer AG, Leverkusen, Federal Republic of Germany

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Hans Gempeler

Hans Gempeler

Ciba-Geigy AG, Basel, Switzerland

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Wolfgang Schneider

Wolfgang Schneider

Ciba-Geigy AG, Basel, Switzerland

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James W. White

James W. White

Dow Corning Ltd., Barry, South Glamorgan, CF6 7YL, United Kingdom

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Anthony G. Short

Anthony G. Short

Dow Corning Ltd., Barry, South Glamorgan, CF6 7YL, United Kingdom

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Werner J. Blank

Werner J. Blank

King Industries, Norwalk, Connecticut, United States, 06852

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Leonard J. Calbo

Leonard J. Calbo

King Industries, Norwalk, Connecticut, United States, 06852

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Dieter Plath

Dieter Plath

Hoechst AG, Wiesbaden, Federal Republic of Germany

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Friedrich Wagner

Friedrich Wagner

Sika-Chemie, Stuttgart, Federal Republic of Germany

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Werner Haller

Werner Haller

Henkel KGaA, Düsseldorf, Federal Republic of Germany

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Karl-Martin Rödder

Karl-Martin Rödder

Hüls AG, Troisdorf, Federal Republic of Germany

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Hans-Joachim Streitberger

Hans-Joachim Streitberger

BASF Corporation, Southfield, Michigan, United States, 48086

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Edmund Urbano

Edmund Urbano

Vianova Kunstharz AG, Graz, Austria

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Richard Laible

Richard Laible

Akzo Coatings GmbH, Stuttgart, Federal Republic of Germany

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Bernd D. Meyer

Bernd D. Meyer

VP Resicoat GmbH, Reutlingen, Federal Republic of Germany

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Engin Bagda

Engin Bagda

Deutsche Amphibolin-Werke, Ober-Ramstadt, Federal Republic of Germany

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Frederick A. Waite

Frederick A. Waite

ICI Paints, Slough, Berkshire SL2 5DS, United Kingdom

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Michel Philips

Michel Philips

Radcure Specialties, Drogenbos, Belgium

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Klaus Köhler

Klaus Köhler

Bayer AG, Krefeld-Uerdingen, Federal Republic of Germany

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Peter Simmendinger

Peter Simmendinger

Ciba-Geigy AG, Basel, Switzerland

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Wolfgang Roelle

Wolfgang Roelle

Bassermann & Co., Mannheim, Federal Republic of Germany

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Wilfried Scholz

Wilfried Scholz

BYK-Chemie GmbH, Wesel, Federal Republic of Germany

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Wolfgang Kortmann

Wolfgang Kortmann

BYK-Chemie GmbH, Wesel, Federal Republic of Germany

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Andreas Valet

Andreas Valet

Ciba-Geigy AG, Basel, Switzerland

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Mario Slongo

Mario Slongo

Ciba-Geigy AG, Basel, Switzerland

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Thomas Molz

Thomas Molz

Henkel KGaA, Düsseldorf, Federal Republic of Germany

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Rainer Hiller

Rainer Hiller

BASF Lacke + Farben AG, Münster-Hiltrup, Federal Republic of Germany

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Klaus Werner Thomer

Klaus Werner Thomer

Opel, Bochum, Federal Republic of Germany

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Klaus Vogel

Klaus Vogel

Herberts GmbH, Wuppertal, Federal Republic of Germany

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Ulrich Schernau

Ulrich Schernau

BASF Lacke + Farben AG, Münster, Federal Republic of Germany

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Bernhard Hüser

Bernhard Hüser

BASF Lacke + Farben AG, Münster, Federal Republic of Germany

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Alfred Brandt

Alfred Brandt

ICI Lacke Farben GmbH, Hilden, Federal Republic of Germany

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Alex Milne

Alex Milne

Courtaulds Coatings Ltd., Felling, Gateshead NE10 0JY, United Kingdom

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Helmut Weyers

Helmut Weyers

ICI Lacke Farben GmbH, Hilden, Federal Republic of Germany

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Wolfgang Plehn

Wolfgang Plehn

Umweltbundesamt, Berlin, Federal Republic of Germany

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Hanns-Adolf Lentze

Hanns-Adolf Lentze

CEPE, Brussels, Belgium

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First published: 15 June 2000
Citations: 3

Abstract

The article contains sections titled:

1.

Introduction

1.1.

Fundamental Concepts

1.2.

Historical Development

1.3.

Composition of Paints

1.3.1.

Binders and Resins

1.3.2.

Plasticizers

1.3.3.

Pigments and Extenders

1.3.4.

Paint Additives

1.3.5.

Solvents

1.4.

Paint Application

1.5.

Drying and Film Formation

1.6.

Multicoat Systems

1.7.

Economic Aspects

1.8.

Future Outlook

2.

Types of Paints and Coatings (Binders)

2.1.

Oil-Based Coatings

2.2.

Cellulose-Based Coatings

2.2.1.

Nitrocellulose Lacquers

2.2.1.1.

Raw Materials

2.2.1.2.

Application and Uses

2.2.2.

Organic Cellulose Ester Coatings

2.2.2.1.

Cellulose Acetate Butyrate

2.2.2.2.

Cellulose Acetate Propionate

2.3.

Chlorinated Rubber Coatings

2.3.1.

Starting Products

2.3.2.

Chlorinated Rubber Paints

2.3.3.

Chlorinated Rubber Combination Paints

2.4.

Vinyl Coatings

2.4.1.

General Properties

2.4.2.

Coatings Based on Polyolefins and Polyolefin Derivatives

2.4.3.

Poly(Vinyl Halides) and Vinyl Halide Copolymers

2.4.3.1.

Poly(Vinyl Chloride) and Vinyl Chloride Copolymers

2.4.3.2.

Vinylidene Chloride Copolymers

2.4.3.3.

Fluoropolymer Coatings

2.4.4.

Poly(Vinyl Esters)

2.4.4.1.

Solid Resins

2.4.4.2.

Dispersions

2.4.5.

Poly(Vinyl Alcohol)

2.4.6.

Poly(Vinyl Acetals)

2.4.7.

Poly(Vinyl Ethers)

2.4.8.

Polystyrene and Styrene Copolymers

2.5.

Acrylic Coatings

2.6.

Alkyd Coatings

2.6.1.

Alkyd Resin Binders and Uses

2.6.2.

Additional Raw Materials

2.6.3.

Production

2.6.4.

Environmental and Health Protection Measures

2.7.

Saturated Polyester Coatings

2.7.1.

Properties

2.7.2.

Production of Polyester Resins and Paints

2.7.3.

Cross-Linking of Polyester Resins

2.7.4.

Uses

2.8.

Unsaturated Polyester Coatings

2.8.1.

Unsaturated Polyester Binders

2.8.2.

Other Raw Materials

2.8.3.

Production, Properties, and Uses

2.8.4.

Transportation and Handling

2.9.

Polyurethane Coatings

2.9.1.

Raw Materials

2.9.2.

Polyurethane Systems

2.9.2.1.

One-Pack Systems

2.9.2.2.

Two-Pack Systems

2.9.3.

Properties and Uses

2.10.

Epoxy Coatings

2.10.1.

Epoxy Resin Types

2.10.2.

Curing Agents

2.10.3.

Chemically Modified Epoxy Resins

2.10.4.

Uses

2.10.4.1.

Curing at Ambient Temperature

2.10.4.2.

Curing at Elevated Temperature

2.10.4.3.

Radiation Curing

2.10.4.4.

Occupational Health

2.11.

Silicone Coatings

2.12.

Urea, Benzoguanamine, and Melamine Resins for Coatings

2.13.

Phenolic Resins for Coatings

2.13.1.

Resols

2.13.2.

Novolacs

2.13.3.

Modified Phenolic Resins

2.14.

Asphalt, Bitumen, and Pitch Coatings

2.14.1.

Asphalt and Asphalt Combination Coatings

2.14.2.

Bitumen Coatings

2.14.3.

Bitumen Combination Coatings

2.14.4.

Pitch Coatings

2.14.5.

Pitch Combination Coatings

2.15.

Silicate Coatings

2.15.1.

Water Glass Coatings

2.15.2.

Alkyl Silicates

3.

Paint Systems

3.1.

Solventborne Paints

3.1.1.

General Information

3.1.2.

Properties and Raw Materials

3.1.3.

Environmental Protection and Application Technology

3.2.

Solvent-Free and Low-Solvent (High-Solids) Paints

3.2.1.

Principles

3.2.2.

Production and Uses

3.3.

Waterborne Paints

3.3.1.

Properties

3.3.2.

Production and Application

3.3.3.

Uses and Environmental Aspects

3.4.

Coating Powders

3.4.1.

Introduction and Economic Importance

3.4.2.

Production

3.4.3.

Properties

3.4.4.

Testing

3.4.5.

Storage and Transportation

3.4.6.

Environmental Aspects and Safety

3.4.7.

Uses

3.5.

Waterborne Dispersion Paints (Emulsion Paints)

3.6.

Nonaqueous Dispersion Paints

3.7.

Radiation-Curing Systems

3.7.1.

Introduction

3.7.2.

Radiation-Curable Systems Based on Acrylates

3.7.3.

Equipment

3.7.4.

Fields of Application

3.8.

Electrodeposition Paints

4.

Pigments and Extenders

4.1.

Inorganic Pigments

4.2.

Organic Pigments

4.3.

Extenders

4.3.1.

Introduction

4.3.2.

Properties

4.3.3.

Modification of Extenders

5.

Paint Additives

5.1.

Defoamers

5.2.

Wetting and Dispersing Additives

5.3.

Surface Additives

5.4.

Driers and Catalysts

5.5.

Preservatives

5.6.

Rheology Additives

5.7.

Light Stabilizers

5.8.

Corrosion Inhibitors

5.9.

Use and Testing of Additives

6.

Paint Removal

6.1.

Paint Removal from Metals

6.1.1.

Chemical Paint Removal

6.1.2.

Thermal Paint Removal

6.1.3.

Mechanical and Low-Temperature Paint Removal

6.2.

Paint Removal from Wood and Mineral Substrates

7.

Production Technology

7.1.

Principles

7.2.

Paint-Making Processes

7.2.1.

Varnishes

7.2.2.

Paints

7.2.3.

Powder Coatings

7.3.

Apparatus

7.3.1.

Mixers

7.3.2.

Dissolvers

7.3.3.

Kneaders and Kneader Mixers

7.3.4.

Media Mills

7.3.5.

Roller Mills

7.3.6.

Auxiliary Equipment

8.

Paint Application

8.1.

Types of Substrate

8.2.

Pretreatment of Substrate Surfaces

8.2.1.

Pretreatment of Metallic Substrates

8.2.1.1.

Cleaning

8.2.1.2.

Degreasing

8.2.1.3.

Formation of Conversion Layers

8.2.2.

Pretreatment of Plastics

8.2.3.

Pretreatment of Wood

8.3.

Application Methods

8.3.1.

Spraying (Atomization)

8.3.2.

Electrostatic Atomization

8.3.3.

Dipping

8.3.4.

Miscellaneous Wet Paint Coating Methods

8.3.5.

Powder Coating

8.3.6.

Coating of Plastics and Wood

8.4.

Paint Curing Methods

9.

Properties and Testing

9.1.

Properties of Coating Materials

9.2.

Properties of Coatings

9.2.1.

Films for Testing

9.2.2.

Optical Properties

9.2.3.

Mechanical Properties

9.2.4.

Chemical Properties

9.2.5.

Weathering Tests

10.

Analysis

10.1.

Analysis of Coating Materials

10.1.1.

Separation of the Coating Material into Individual Components

10.1.2.

Analysis of Binders

10.1.3.

Analysis of Pigments and Extenders

10.1.4.

Analysis of Solvents

10.1.5.

Analysis of Additives

10.2.

Analysis of Coatings

11.

Uses

11.1.

Coating Systems for Corrosion Protection of Large Steel Constructions (Heavy-Duty Coatings)

11.2.

Automotive Paints

11.2.1.

Car Body Paints

11.2.2.

Other Automotive Coatings

11.3.

Paints Used for Commercial Transport Vehicles

11.3.1.

Railroad Rolling Stock

11.3.2.

Freight Containers

11.3.3.

Road Transport Vehicles

11.3.4.

Aircraft Coatings

11.4.

Marine Coatings

11.4.1.

Substrate, Surface Preparation, and Priming

11.4.2.

Ship Paint Systems

11.4.3.

Fouling and Antifouling

11.5.

Coil Coating

11.6.

Coatings for Domestic Appliances

11.7.

Coatings for Packaging (Can Coatings)

11.8.

Furniture Coatings

11.9.

Coatings for Buildings

11.9.1.

Exterior-Use Coatings

11.9.2.

Interior-Use Coatings

12.

Environmental Protection and Toxicology

12.1.

Clean Air Measures

12.2.

Wastewater

12.3.

Solid Residues and Waste

12.4.

Toxicology

13.

Economic Aspects

The full text of this article hosted at iucr.org is unavailable due to technical difficulties.