Cyano Compounds, Inorganic
Rupprecht Kulzer
Degussa AG, Düsseldorf, Federal Republic of Germany
Search for more papers by this authorJürgen Lorösch
Degussa AG, Düsseldorf, Federal Republic of Germany
Search for more papers by this authorAndreas Rubo
CyPlus GmbH, Hanau-Wolfgang, Federal Republic of Germany
Search for more papers by this authorManfred Sauer
Degussa AG, Düsseldorf, Federal Republic of Germany
Search for more papers by this authorNorbert Steier
CyPlus GmbH, Wesseling, Federal Republic of Germany
Search for more papers by this authorWolfgang Hasenpusch
Degussa AG, Frankfurt, Federal Republic of Germany
Search for more papers by this authorRupprecht Kulzer
Degussa AG, Düsseldorf, Federal Republic of Germany
Search for more papers by this authorJürgen Lorösch
Degussa AG, Düsseldorf, Federal Republic of Germany
Search for more papers by this authorAndreas Rubo
CyPlus GmbH, Hanau-Wolfgang, Federal Republic of Germany
Search for more papers by this authorManfred Sauer
Degussa AG, Düsseldorf, Federal Republic of Germany
Search for more papers by this authorNorbert Steier
CyPlus GmbH, Wesseling, Federal Republic of Germany
Search for more papers by this authorWolfgang Hasenpusch
Degussa AG, Frankfurt, Federal Republic of Germany
Search for more papers by this authorAbstract
The article contains sections titled:
1. |
Hydrogen Cyanide |
1.1. |
Properties |
1.2. |
Production |
1.2.1. |
Andrussow Process |
1.2.2. |
Methane - Ammonia (BMA) Process |
1.2.3. |
Shawinigan Process |
1.3. |
Storage and Transportation |
1.4. |
Economic Aspects and Uses |
2. |
Metal Cyanides |
2.1. |
Alkali Metal Cyanides |
2.1.1. |
Properties |
2.1.2. |
Production |
2.1.2.1. |
Classical Production Processes |
2.1.2.2. |
Current Production Processes |
2.1.2.3. |
Energy Consumption |
2.1.3. |
Packaging and Transport |
2.1.4. |
Responsible Care, Product Stewardship, Sustainable Development, Certification |
2.1.5. |
Emissions and Consumptions |
2.1.6. |
Quality Specifications, Impurities |
2.1.7. |
Uses |
2.1.7.1. |
Gold Mining |
2.1.7.2. |
Chemical Synthesis |
2.1.7.3. |
Electroplating of Metals |
2.1.7.4. |
Hardening of Metals |
2.1.8. |
|
2.2. |
Alkaline Earth Metal Cyanides |
2.3. |
Heavy-Metal Cyanides |
2.3.1. |
Iron Cyanides |
2.3.1.1. |
Properties |
2.3.1.2. |
Production |
2.3.1.3. |
Commercial Forms, Specifications, and Packaging |
2.3.2. |
Cyanides of Copper, Zinc, and Cadmium |
2.3.3. |
Cyanides of Mercury, Lead, Cobalt, and Nickel |
2.3.4. |
Cyanides of Precious Metals |
2.4. |
Cyanide Analysis |
3. |
Detoxification of Cyanide-Containing Wastes |
3.1. |
Wastewater Treatment |
3.2. |
Solid Wastes |
4. |
Cyanogen Halides |
4.1. |
Properties |
4.2. |
Production |
4.3. |
Storage and Transportation |
4.4. |
Uses |
5. |
Cyanogen |
5.1. |
Properties |
5.2. |
Production |
5.3. |
Storage, Transportation, and Uses |
6. |
Toxicology and Occupational Health |
General Reference
- 1 Gmelin, System no. 14, D 1, Kohlenstoff (1971).
- 2 H. E. Williams: Cyanogen Compounds, 2nd ed., Arnold & Co., London 1948.
- 3 M. H. Ford-Smith: The Chemistry of Complex Cyanides, Dep. of Scientific and Industrial Research, Her Majesty's Stationery Office, London 1964.
- 4 A. G. Sharpe: The Chemistry of Cyano Complexes of the Transition Metals, Academic Press, London 1976.
- 5 A. M. Golub et al.: Chemie der Pseudohalogenide, Hüthig Verlag, Heidelberg 1979.
- 6 V. Migrdichian: The Chemistry of Organic Cyanogen Compounds, Reinhold Publ. Co., New York 1947, pp. 97 – 124.
- 7 Houben-Weyl, 8, 90 – 93.
- 8 G. Brauer: Handbuch der präparativen anorganischen Chemie, 2nd ed., vol. 1, Enke Verlag, Stuttgart 1960.
- 9 B. S. Thyagarajan: The Chemistry of the Cyanogen Halides, Intra-Science Chemistry Reports, vol. 2, no. 1, Santa Monica, California 1968, pp. 1 – 89.
- 10 J. MacCordick, Bull. Soc. Chim. Fr. 1973, 50 – 70.
- 11 Gmelin, System no. 14, D3, Kohlenstoff (1976) 149 – 266
- 12 Houben-Weyl, 8, 256 – 265.
- 13 T. K. Brotherton, J. W. Lynn, Chem. Rev. 59 (1959) 841 – 883.
- 14 S. Nakamura, Yuki Gosei Kagaku Kyokai shi 26 (1968) 23 – 26.
- 15 R. H. Fahnenstich, W. Th. Heimberger, F. M. Theissen, W. M. Weigert, Chem. Ztg. 96 (1972) 388 – 396.
- 16 G. Brauer: Handbuch der präparativen anorganischen Chemie, 3rd ed., vol. 2, Enke Verlag, Stuttgart 1978.
- 17 H. W. Roesky, H. Hofmann, Chem. Ztg. 108 (1984) 231 – 238.
- 18 CyPlus, More than Cyanide (Planning, Research & Development, Production, Packaging, Transport, Storage, Handling & Use, Disposal & Recycling), company brochure, Frankfurt am Main, Germany, 2003.
- 19 Degussa, Stets geforscht…, company brochure, Frankfurt am Main, Germany, 1988.
- 20 Degussa, Edelmetalltaschenbuch, Hüthig-Verlag, Heidelberg, Germany, 1995.
- 21 Degussa, Metallforschung und Entwicklung, company brochure, Frankfurt am Main, Germany, 1991.
Specific Reference
- 22 H. Bauer, Naturwissenschaften 67 (1980) 1 – 6.
- 23 W. F. Giauque, R. A. Ruehrwein, J. Am. Chem. Soc. 1939, 2626 – 2633.
- 24 G. E. Coates, J. E. Coates, J. Chem. Soc. 1944, 77 – 81.
- 25 G. Bredig, L. Teichmann, Z. Elektrochem. 31 (1925) no. 8, 449 – 454.
- 26 G. Kortüm, H. Reber, Z. Elektrochem. 65 (1961) no. 9, 809 – 812.
- 27 B. Grüttner, M. F. A. Dove, A. F. Clifford: Chemistry in Anhydrous, Prototropic Inorganic Solvents, vol. II, part 1, Pergamon Press, Oxford, London, Edinburgh, New York, Toronto, 1971.
- 28 T. Völker, Angew. Chem. 72 (1960) 379 – 384.
- 29 Röhm & Haas, DE 1 020 320, 1956 (T. Völker, H. Zima).
- 30 W. Ruske, Wiss. Z. Humboldt Univ. Berlin. Math. Naturwiss. Reihe 8 (1958) 557 – 572.
- 31 J. P. Ferris, W. J. Hagan, Tetrahedron 40 (1984) no. 7, 1093 – 1120.
- 32 Ullmann, 3rd ed., 5, 629
- 33 H. Schaefer, Chem.-Tech. Heidelberg 7 (1978) 231 – 237.
- 34 F. Götzen, Hüttenwesen Symposium Int. Gas Union Karlsruhe 12 (1972) 1 – 15; Chem. Abstr. 81 (1974) 65 808 m.
- 35 Ullmann, 3rd ed., 5, 631 – 633.
- 36 Standard Oil, US 4 423 023, 1983 (L. J. Velenyi, H. F. Hardman, F. A. Pesa).
- 37 DuPont, US 4 164 552, 1979 (F. J. Weigert).
- 38 V. D. Sokolovskii, Z. G. Osipova, S. Y. Burylin, React. Kinet. Catal. Lett. 15 (1980) no. 3, 311 – 314.
- 39 Nitto Chem. Ind., EP-A 0 089 118, 1983 (Y. Sasaki, H. Utsumi).
- 40 Monsanto, US 4 457 904, 1984 (J. W. Gambell, S. R. Anvie).
- 41 Standard Oil, US 4 423 023, 1983 (J. L. Velenyi, H. F. Hardman, F. A. Pesa).
- 42 Monsanto, US 4 425 260, 1984 (J. R. Ebner).
- 43 BASF, DE 1 143 497, 1963 (G. Schulze, G. Weiß).
- 44 Sumitomo, DE-OS 2 350 212, 1974 (T. Shiraishi, H. Ichihashi, F. Kato, E. Niihama).
- 45 Distillers Ltd., GB 913 836, 1962.
- 46Proceedings of TOCAT 3 in press.
- 47 H. Bockhorn, R. Coy, F. Fetting, W. Prätorius, Chem. Ing. Tech. 49 (1977) no. 11, 883 – 895.
- 48 DuPont, WO 95/21126, 1995 (R. J. Riegert, M. Mehdizadeh).
- 49 L. Andrussow, Angew. Chem. 48 (1935) no. 37, 593 – 604.
- 50 C. T. Kautter, W. Leitenberger, Chem. Ing. Tech. 25 (1953) no. 12, 697 – 701.
- 51 L. Andrussow, Chem. Ing. Tech. 27 (1955) 469 – 474.
- 52 DuPont, US 4 128 622, 1978 (K. D. Loos, K. C. McCullough, D. Q. Whitworth).
- 53 Johnson Matthey & Co., US 4 469 666, 1984 (D. J. Stephenson, A. E. Heywood, G. L. Selman).
- 54 W. R. Rolingson, J. McPherson, P. D. Montgomery, B. L. Williams, J. Chem. Eng. Data 5 (1960) no. 3, 349 – 351.
- 55 N. Kalkert, H.-G. Schecker, Chem. Ing. Tech. 51 (1979) no. 9, 895.
- 56 Freeport Sulphur, US 2 590 146, 1952 (G. Barsky).
- 57 DOW Chemical, US 2 899 274, 1959 (R. A. Smith, H. H. McClure, G. C. Bond).
- 58 Toyo Koatsu Industries, US 3 112 177, 1968 (S. Fujise, N. Nagai, T. Numata).
- 59 DuPont, US 2 797 148, 1957 (H. C. Carlson).
- 60 DuPont, US 3 914 386, 1974 (N. R. Wilson).
- 61 DuPont, EP-A 0 030 141, 1983 (G. Levitt).
- 62 F. Endter, DECHEMA Monogr. 33 (1959).
- 63 F. Endter, Chem. Ing. Tech. 30 (1958) no. 5, 305 – 310.
- 64 DEGUSSA, DE 959 364, 1954 (F. Endter).
- 65 DEGUSSA, DE 882 985, 1953 (R. Wendlandt, G. Hoffmann, E. Kokert).
- 66 DEGUSSA, DE 1 007 300, 1957 (F. Endter).
- 67 DEGUSSA, DE 3 923 034, 1989 (F. Bittner, C. Hecht, P. Lok-Herber, P. Panster).
- 68 DEGUSSA, DE 19 617 040, 1998 (L. v. Hippel, C. Bussek, J. Sauer, M. Sauer, D. Arntz).
- 69 E. Koberstein, Ind. Eng. Chem. Process. Des. Dev. 12 (1973) no. 4, 444 – 448.
- 70 DEGUSSA, DE-OS 33 09 394, 1983 (R. Manner, H. Schaefer, C. Voigt, W. D. Pfeifer).
- 71 DEGUSSA, DE 31 34 851, 1982 (H. Bruck).
- 72 DEGUSSA, EP-A 0 072 416, 1981 (C. Voigt, P. Kleinschmit).
- 73 DEGUSSA, US 4 289 741, 1981 (C. Voigt, P. Kleinschmit, E. Walter).
- 74 DEGUSSA, US 4 387 081, 1983 (C. Voigt, P. Kleinschmit, G. Schreyer, G. Sperka).
- 75 N. B. Shine, Chem. Eng. Prog. 67 (1971)
- 76 Shawinigan Chem., CA 573 348, 1959 (H. S. Johnson, A. H. Andersen).
- 77 Shawinigan Chem., US 3 097 921, 1963 (D. J. Kennedy, N. B. Shine).
- 78 Shawinigan Chem., US 3 032 396, 1962 (D. J. Kennedy).
- 79 Hommel-Handbuch der gefährlichen Güter, 4. Lfg., Merkblatt 42, Springer Verlag, Berlin, Heidelberg, New York 1980.
- 80 R. Baxter, Ind. Finish. Wheaton Ill. 53 (1977) no. 12, 38 – 41.
- 81J. E. Johnson, E. R. Poor, US 2 753 248, 1956.
- 82Compur Electronic GmbH, Steinerstraße 15, 8000 München 70, FRG.
- 83
H. B. Northrup,
Trans. Am. Electrochem. Soc.
60
(1931)
49 – 53.
10.1149/1.3497901 Google Scholar
- 84 DEGUSSA, DE 1 149 035, 1963 (C. Albrecht, J. Müller).
- 85 DEGUSSA, DE 1 178 668, 1964.
- 86 L. Hackspill, R. Grandadam, C.R. Acad. Sci. 180 (1925) 931.
- 87 L. Hackspill, R. Grandadam, Ann. Chim. (Paris) 5 (1926) no. 10, 237.
- 88 W. Müller, L. Witzke, Chem. Ing. Tech. 45 (1973) no. 22, 1285 – 1289.
- 89 H. Beyer, G. Dittrich, H. Kunst, F. Schmidt, Chem. Anlagen + Verfahren 1973, no. 11, 69 – 75.
- 90
R. W. E. B. Harman,
F. P. Worky,
Trans. Faraday. Soc.
20
(1925)
502;
10.1039/tf9252000502 Google ScholarChem. Abstr. 19 (1925) 923.
- 91 B. Ricca, G. D'Amore, Gazz. Chim. Ital. 79 (1949) 308 – 322; Chem. Abstr. 43 (1949) 8821.
- 92 E. Deltombe, M. Pourbaix, Proc. Meet. Int. Comm. Electrochem. Thermodyn. Kinet. 6th 1955, 138 – 142; Chem Abstr. 1956, 6896.
- 93 J. Zawidski, T. Witkowski, Rocz. Chem. 5 (1925) 515 – 528; Chem. Abstr. 1926, 3258.
- 94 G. W. Wiegand, M. Tremelling, J. Org. Chem. 37 (1972) 914 – 916.
- 95 DuPont, US 2 773 752, 1953 (V. W. Kremer, C. H. Lemke).
- 96 H. Sulzer, Z. Angew. Chem. 25 (1912) 1268 – 1273.
- 97
G. W. Heisse,
H. E. Foote,
Ind. Eng. Chem.
12
(1920)
331 – 336.
10.1021/ie50124a009 Google Scholar
- 98 J. Hoerth, U. Schindewolf, W. Zbinden, Chem. Ing. Tech. 45 (1973) 641 – 646.
- 99
E. v. Papp,
J. Pogany,
Z. Angew. Chem.
54
(1941)
55.
10.1002/ange.19410540304 Google Scholar
- 100 W. Bucksteeg, Purdue Univ. Eng. Bull. Ext. Ser. 121 (1966) 688 – 695.
- 101 D. C. Hoffmann, Plating (East Orange, NJ) 60 (1973) 157 – 161.
- 102 M. R. Lowndes, Chem. Ind. 34 (1971) 951 – 956.
- 103 C. Fabjan, Galvanotechnik 66 (1975) 100 – 107.
- 104 DEGUSSA, DE 742 074, 1943 (H. Beier).
- 105 J. P. Zumbrunn, Inf. Chim. 124 (1973) 189 – 194.
- 106
H. Stamm,
Z. Angew. Chem.
47
(1934)
579, 791 – 795.
10.1002/ange.19340474803 Google Scholar
- 107 A. T. Kuhn, J. Appl. Chem. Biotechnol. 21 (1971) no. 2, 29 – 34.
- 108 E. Schulek, P. Endröi, Anal. Chim. Acta 5 (1951) 252.
- 109 P. D. Bartlett, R. E. Davis, J. Am. Chem. Soc. 80 (1958) 2513 – 2516.
- 110 K. R. Leininger, J. Westley, J. Biol. Chem. 243 (1968) 1892 – 1899.
- 111 L. G. Sillen, A. E. Mostell: Stability Constants of Metal-Ion Complexes, HMSO, London 1964.
- 112 J. Bailar: The Chemistry of the Coordination Compounds, Reinhold Publ. Co., New York 1956.
- 113 E. Rabald: Dechema-Werkstoff-Tabelle, 3rd ed., part 12, 1963.
- 114 Ullmann, 4 th ed., 8, 253.
- 115 V. Migrdichian: The Chemistry of Organic Cyanogen Compounds, Reinhold Publ. Co., New York 1947.
- 116 Houben-Weyl, 8, 247 – 358.
- 117 DEGUSSA, DE 124 977, 1900; DE 126 241, 1900; DE 148 045, 1901; DE 148 046, 1901; DE 149 678, 1901; GB 265 639, 1926 (H. Freudenberg); DE 851 056, 1943 (W. Stephan).
- 118 R. Norcross, N. Steiner, S. Gos, A. Rubo: “The Cyanide Life Cycle — Packaging & Transport”, Mining J. Mining Environ. Manag. 2001, May, 19 – 21.
- 119 CEFIC, Cyanide Sector Group — Guidelines for Storage, Handling, and Distribution of Alkali Cyanides, May 2000, under revision in 2004.
- 120VCI Brochure “Responsible Care”, (Umweltschutz, Produktverantwortung, Arbeitssicherheit & Gesundheitsschutz, Anlagensicherheit & Gefahrenabwehr, Logistik, Dialog), Frankfurt am Main, Germany, July 2003.
- 121 S. Gos, A. Rubo: “Responsible Application of Cyanides”, Randol Gold & Silver Forum '97, Monterey, California, May 18 – 21, 1997, pp. 161 – 165.
- 122 A. Rubo, S. Gos, A. Dickmann, A. Dominguez-Perez, R. Norcross: “Effects of Responsible Care on the Risks, Legal and Cost Aspects of Cyanides”, Randol Gold & Silver Forum '99, Denver, Colorado, May 11 – 14, 1999, pp. 53 – 56.
- 123 A. Dominguez, A. Rubo, S. Gos: “Relation between Risks, Legal Aspects and Costs in the Application of Cyanides”, International Mining and Environment Congress “Clean Technology: Third Millenium Challenge”, Lima, Peru, July 12 – 16, 1999.
- 124 A. Rubo, S. Gos, A. Dickmann, A. Dominguez Perez: “Risk Related Cost Parameters in Handling Cyanides”, 4th International Gold Symposium, Lima, Peru, May 02 – 05, 2000.
- 125 N. Steiner, A. Rubo, A. Aivasidis: “Responsible Cyanide Management in the Gold Mining Industry” Exploitation of Gold Deposits in Thrace, International Meeting, Komotini, Greece, Oct. 14 – 15, 2000.
- 126 S. Gos, A. Rubo, A. Dominguez-Perez: “La Relevancia De Lixivantes Alternativos EN Conexion Con Aspectos Technicos, Seguridad Ocupaccional Y Seguridad Ambiental”, “Technical Factors, Occupational Safety And Environmental Concerns”, Argentinia, Panorama Minero, No. 255, Dic. 2000, pp. 48 – 50.
- 127 F. Harenburg and A. Rubo: “Responsible Care, Sustainable Development in Gold Mining and the Future Role of CyPlus”, Johannesbourg, South Africa, Indaba, 2003.
- 128ISO 9001:2000/14001 and ICMC certification.
- 129CyPlus, press release Jan. 2004 on Certification on ICMC, ISO 9001:2000 and ISO 14001, Hanau-Wolfgang, Germany.
- 130CEFIC, press release on “Alkali Cyanide Mutual Aid Scheme”, Brussels, Belgium, Oct. 2000.
- 131CEFIC, “Responsible Care Status Report”, Brussels, Belgium, 2002.
- 132CEFIC, “Managing Chemicals. Voluntary and Obligatory Programmes”, Brussels, Belgium, 2003.
- 133 A. Smith and T. Mudder: The Chemistry and Treatment of Cyanidation Wastes, Mining Journal Books Limited, London 1991.
- 134 A. Rubo, A. Dickmann, S. Gos: “Laboratory Simulation of HCN Emissions from Tailings Ponds”, Tailings and Mine Waste '00, 2000 Balkema, Rotterdam, pp. 307 – 313, Proceedings of the 7th International Conference on Tailings and Mine Waste '00, Fort Collins, Colorada, USA, 23 – 26 Jan. 2000.
- 135CyPlus CombinOx™, A New Technology For Cyanide Destruction, E.A. Devuyst/Inco Tech, Johannesbourg, South Africa, Indaba 2003, presentation on request through CyPlus.
- 136 J. Lorösch, Process and Environmental Chemistry of Cyanidation, Degussa, Frankfurt am Main, Germany, 2001, pp. 401 – 406.
- 137 A. Griffiths, H. Knorre, S. Gos, R. Higgins: “The Detoxification of Gold-Mill Tailings with Hydrogen Peroxide”, J. S. Afr. Inst. Min. Metall. 87 (1987) no. 9, 279 – 283.
- 138 T. Mudder, S. Whitlock: “Biological Treatment of Cyanidation Wastewaters”, Min. Metall. Process. (1989) 161 – 165.
- 139 A. Rubo, S. Gos: “Treatment after Cyanide Contamination”, Mining Magazine 2002 240 – 246.
- 140 A. Rubo, Degussa-Huels AG, “The Cyanide Life Cycle”, Workshop “ Management of Cyanide in the Gold Industry Beyond 2001”, AJ Parker Cooperative Research Centre for Hydrometallurgy, Dec. 5, 2001, Kalgoorlie, Australia.
- 141 Golden Prospects in Europe, brochure, published by euromines, Avenue de Broqueville, 12, B-1150 Bruxelles, 2002, sponsored by Boliden, Newmont, Normandy Madencilik A.S., Rio Narcea Gold Mines LTD, Thracean Gold Mining S.A., CyPlus GmbH (Degussa Group).
- 142Euromines brochure, Occupational Health and Safety Management in the European Mining Industry, Brussels, Belgium.
- 143 E. von der Linden: “Goldbergbau und Zyanlaugung - Die Rolle der Banken in der Finanzierung”, Erzmetall 7/8 (2000) 471 ff.
- 144 M. Ericsson: “M&A im Bergbau erreichen im Jahr 2001 einen neuen Höchststand, Gold und Eisenerzbau”, Erzmetall 3 (2002).
- 145 S. Gos, A. Rubo, Degussa-Huels AG, “Alternative Lixiviants for Gold Leaching — a Comparison”, Randol Gold & Silver Forum 2000, Vancouver, BC, Canada, April 25 – 28, 2000, pp. 271 – 281.
- 146 Praktische Galvanotechnik, 2nd ed., Leuze Verlag, Saulgau 1970, p. 291.
- 147 I. G. Farben, DE 529 506, 1928 (C. Schumann, R. Fick); DE 529 575, 1928 (R. Fick).
- 148
G. H. Buchanan,
Trans. Am. Electrochem. Soc.
60
(1931)
93.
10.1149/1.3497912 Google Scholar
- 149
G. H. Buchanan,
Trans. Electrochem. Soc.
60
(1931)
93 – 112.
10.1149/1.3497912 Google Scholar
- 150 H. H. Franck, W. Burg, Z. Electrochem. Angew. Phys. Chem. 40 (1934) 686 – 692.
- 151 Shin-inchi Ohno, Bull. Chem. Soc. Jpn. 40 (1969) 1765 – 1769.
- 152 H. Bauer, Münchener Beiträge z. Abwasser, Fisch. u. Flußbiol. 28 (1979) 181 – 192.
- 153The Chemistry of the Ferrocyanides, vol. VII, American Cyanamid Co., New York 1953.
- 154 Ullmann, 4th ed., 18, 463 – 467. B. A. Hutchins, L. E. West, J SMPTE, 66 (1957) 764 – 768.
- 155 J. Jostan, H. Mietz, DE 2 534 213, 1975 (J. Jostan, H. Miez).
- 156 Ullmann, 3rd ed., 5, 659.
- 157 American Cyanamid, US 3 695 833, 1972 (O. F. Wiedeman, K. W. Saunders, M. N. O'Connor).
- 158 G. Grube: Die elektrolytische Darstellung des Ferricyankaliums, Enke Verlag, Stuttgart 1913.
- 159 DEGUSSA, DE 2 016 848, 1972 (H. Reinhardt, K. Treibinger, G. Kallrath).
- 160 Ch. E. MacKinnon, Symp. Salt, 2nd, 1 (1965) 356 – 364.
- 161 R. Noyes: “Citric Acid Production Processes,” Chem. Process. (Chicago) 37 (1969) 70 – 120.
- 162 A. Dinsmoor Webb: “Chemistry of Winemaking,” Adv. Chem. Ser. 137 (1974) 278 – 305.
- 163 DuPont, US 2 512 719, 1950 (R. O. Hull); US 2 585 902, 1952 (A. G. Gray).
- 164 R. D. Crozier, Mining Magazine, February 1979, p. 174.
- 165 DuPont, DE-OS 1 951 260, 1970 (W. T. Hess).
- 166 H. J. Barber, J. Chem. Soc. 1943, 79.
- 167 DuPont, DE-OS 2 012 444, 1970 (J. D. Rushmere).
- 168 W. Biltz, Z. Anorg. Chem. 170 (1928) 161 – 183.
- 169 K. Masaki, Bull. Chem. Soc. Jap. 6 (1931) 143 – 147.
- 170 BASF, FR 1 539 598, 1968.
- 171 L. Wöhler, J. F. Roth, Chem. Ztg. 50 (1926) 761 – 763 and 781 – 782.
- 172 H. Karst, Z. Gesamte Schiess Sprengstoffwes. 77 (1922) 116 – 117.
- 173 G. Paulèt, Presse Méd. 66 (1958) 1435.
- 174 G. Denigés, Ann. Chim. Phys. 6 (1895) 381.
- 175 W. Leithe: Die Analyse der org. Verunreinigungen in Trink-, Brauch- und Abwässern, Wissenschaftl. Verlags GmbH, Stuttgart 1972.
- 176 E. Asmus, H. Garschagen, Z. Anal. Chem. 138 (1953) 414 – 422.
- 177 Annual Book ASTM Standards, American Society for Testing and Materials, Philadelphia 1983, D 2036 – 82.
- 178 German Standard Methods for the Analysis of Water, Waste Water and Sludge, DIN 38 405, part 13, DIN Deutsches Institut für Normung e.V., D-1000 Berlin 30.
- 179 D. J. Barkley, J. C. Ingles, Report 221, Canmet, February 1970.
- 180 A. Smith, T. Mudder: Chemistry and Treatment of Cyanidation Wastes, Mining Journal Books Ltd., London 1991, p. 36.
- 181 W. S. Spector: Handbook of Toxicology, vol. I, Saunders, Philadelphia, London.
- 182 P. Doudoroff: Toxicity to Fish of Cyanides and Related Compounds, A Review. Environmental Protection Agency Report No. EPA–600/3–76–038 (1976).
- 183 P. Doudoroff: A Critical Review of Recent Literature on the Toxicity of Cyanides to Fish, American Petroleum Institute, Washington, D.C. 1980.
- 184 J. L. Huiatt, J. E. Kerrigan, F. A. Olson, G. L. Potter: Cyanide from Mineral Processing, Proceedings of a Workshop, Utah Mining and Mineral Resources Research Institute, College of Mines and Mineral Industries, 209 W.C. Browning Building, Salt Lake City, Utah, 1983.
- 185 USEPA: Ambient Water Quality Criteria for Cyanide, United States Environmental Protection Agency. EPA-440/5–80–00 (1980).
- 186 B. F. Dodge, D. C. Reams: “A Critical Review of the Literature Pertaining to the Disposal of Waste Cyanide Solutions, part 2,” Plating (East Orange, N.J.) 36 (1949) 571 – 577, 664.
- 187 A. K. Reed et al.: An Investigation of Techniques for Removal of Cyanide from Electroplating Waste, U.S. Environ. Protection Agency, Water Pollution Control Series, Program No. 120 10 EIE 11/71 (1971).
- 188 J. C. Ingles, J. S. Scott: Overview of Cyanide Treatment Methods, Cyanide in Gold Mining Seminar, Ottawa, Ontario, 1981.
- 189 J. Conrad, M. Jola: “Cyanidentgiftung heute,” Oberfläche Surf. 13 (1972) no. 7, 143 – 148.
- 190 L. E. Lancy, W. Nohse, D. Wystrach: “Practical and Economical Comparison of the Most Common Metal Finishing Waste Treatment Systems,” Plating (East. Orange, N.J.) 59 (1972) 126 – 130.
- 191 G. C. White: Handbook of Chlorination, Van Nostrand Reinhold Co., New York 1972.
- 192
W. Stumm,
H. Woker,
H. W. Fischer,
Z. Hydrol.
16
(1954)
1 – 21.
10.1007/BF02485763 Google Scholar
- 193 H. Knorre, Galvanotechnik 66 (1975) 374 – 383.
- 194 J. P. Zumbrunn, Inf. Chim. 124 (1973) 189 – 194.
- 195 DEGUSSA, DE 2 352 856, 1973 (J. Fischer, H. Knorre, G. Pohl); US 3 970 554, 1976 (J. Fischer, H. Knorre, G. Pohl).
- 196 DEGUSSA, DE 2 917 714, 1983 (K. Eiermann, R. Goedecke, H. Knorre, R. Möller).
- 197 DEGUSSA, DE 3 125 452, 1981 (H. Knorre, J. Fischer, K. Stutzel); US 4 416 786, 1983 (H. Knorre, J. Fischer, K. Stutzel).
- 198 H. Knorre, A. Griffiths, Conference on Cyanide and the Environment, University of Arizona, Tucson, Dec. 1984.
- 199 S. Gos, F. Ladwig, Proceedings Randol Gold Forum ′92, Vancouver 1992.
- 200 C. A. Walker, W. Zabban, Plating (East Orange, N.J.) 40 (1953) 777 – 780.
- 201 G. Wysocki, B. Höke, Wasser Luft Betr. 18 (1974) 311 – 314.
- 202 R. S. Murphy, J. B. Nesbitt, Eng. Res. Bull. P. State Univ. Coll. Eng. B 88 (1964); Chem. Abstr. 61 (1964) 11 740 d.
- 203 K. Marquardt, Metalloberfläche 23 (1969) no. 8, 231 – 236.
- 204 W. Götzelmann, Galvanotechnik 64 (1973) 588 – 600.
- 205E. Deruyst, V. A. Ettel, G. J. Barbely, J. Roy Gordon Research Laboratory, Sheridan Park, Mississauga, Ontario, presented at the 1982 AIME Annual Meeting, Dallas, Texas.
- 206 Presentation, E. Deruyst, Indaba Conference, 19th Feb. 2003, www.cyplus.com.
- 207 W. Götzelmann, G. Spanier, Galvanotechnik 54 (1963) 265.
- 208 C. L. Berthollet, Ann. Chim. Phys. 1 (1789) 30 – 35.
- 209 L. J. Gay-Lussac, Ann. Chim. Phys. 95 (1815) 200 – 213.
- 210 F. S. Fawcett, R. D. Lipscomb, J. Am. Chem. Soc. 82 (1960) 1509 – 1510.
- 211 H. Schachner, W. Sundermeyer, J. Fluorine Chem. 18 (1981) 259 – 268.
- 212 R. Ch. Paul, R. L. Chauhan, R. Parkash, J. Sci. Ind. Res. 33 (1974) 31 – 38.
- 213 F. S. Fawcett, R. S. Lipscomb, J. Am. Chem. Soc. 86 (1964) 2576 – 2579.
- 214 Geigy, GB 942 545, 1983.
- 215 A. A. Woolf, J. Chem. Soc. 1954, 252 – 265.
- 216
E. Mulder,
Recl. Trav. Chim. Pays-Bas
5
(1880)
84 – 98.
10.1002/recl.18860050303 Google Scholar
- 217 D. M. Yost, W. E. Stone, J. Am. Chem. Soc. 55 (1933) 1889 – 1895.
- 218 P. L. Bailey, E. Bishop, Analyst (London) 97 (1972) 691 – 695.
- 219 D. Martin, H.-J. Niclas, Chem. Ber. 100 (1967) 187 – 195.
- 220 J. V. Bodrikov, B. V. Danova, Zh. Org. Khim 8 (1972) no. 12, 2462 – 2467.
- 221 J. Iwai, T. Iwashige, Y. Yuma, N. Nakamune et al., Chem. Pharm. Bull. 12 (1964) 1446 – 1451.
- 222 Mobil Oil, US 3 433 821, 1969 (L. A. Hamilton, P. S. Landis).
- 223 E. H. Bartlett, C. Eaborn, D. R. M. Walton, J. Organomet. Chem. 46 (1972) , no. 2, 267 – 269.
- 224 Nippon Carbide Industries Co., JP-Kokai 80 133 352, 1980.
- 225 Bayer, DE 1 958 095, 1971 (E. Enders, K. Wedemeyer, D. Lesch).
- 226 Bayer, DE 3 538 128, 1985 (R. Fauss, H. J. Riebel).
- 227 Bayer, DE 2 507 671, 1976 (G. Rottloff, R. Sundermann, E. Grigat, R. Putter).
- 228 Bayer, DE 2 507 705, 1976 (G. Rottloff, R. Sundermann, E. Grigat, R. Putter).
- 229 Bayer, DE 1 183 903, 1964 (K. Goliasch, E. Grigat, R. Putter).
- 230 K. Lempert, G. Doleschall, Tetrahedron Lett. 1963, 781.
- 231 J. v. Braun, Chem. Ber. 33 (1900) 1438 – 1452.
- 232 G. Fodor, Sh. Abidi, Tetrahedron Lett. 1971, no. 18, 1369 – 1372.
- 233 R. Graf, Chem. Ber. 89 (1956) 1071 – 1079.
- 234 Lonza, CH 680 292, 1990 (T. Cieslewski, R. Chuck, M. Gross, M. P. Galli).
- 235 DEGUSSA, DE 1 911 174, 1979 (W. Weigert, T. Lussling, F. Theissen).
- 236 DEGUSSA, DE 1 768 154, 1977 (T. Lussling, F. Theissen, W. Weigert).
- 237 DEGUSSA, DE-OS 3 006 492, 1981 (A. Kleemann, P. Schalke).
- 238 Lonza, DE-OS 2 449 013, 1975 (A. Egger, E. Widmer, A. Faucci, R. Gregorin).
- 239 DEGUSSA, DE-OS 3 006 424, 1981 (A. Kleemann, P. Schalke)
- 240
E. Mayer,
Angew. Chem.
81
(1969)
627.
10.1002/ange.19690811614 Google Scholar
- 241 Standard Oil, US 3 105 023, 1963 (R. W. Foreman, F. Veatch).
- 242 H. Schröder, Z. Anorg. Allg. Chem. 297 (1958) 296 – 299.
- 243 Nilok Chemicals Inc., GB 967 458, 1960.
- 244 DEGUSSA, DE 833 490, 1949 (H. Huemer).
- 245 DEGUSSA, DE 842 067, 1950 (H. Huemer, H. Schulz).
- 246 DEGUSSA, DE 827 358, 1949 (1952) (H. Huemer, H. Schulz, W. Pohl).
- 247 DEGUSSA, DE-OS 2 521 580, 1976 (L. Devlies, R. Hendricx, K. Henkel, N. Kriebitzsch, M. Petzold).
- 248 Ciba-Geigy Corp., US 4 100 263, 1978 (R. Miller).
- 249 Bayer, DE-OS 3 117 054, 1982 (H. Königshofen, D. Bruck, A. Nierth, M. Zlokarnik, H. J. Uhlmann).
- 250 Agripat SS.A, DE-OS 1 801 311, 1969 (W. S. Durrell, R. J. Eckert, Jr.).
- 251 SKW Trostberg, DE-OS 2 838 016, 1980 (G. Buchreiter, P. Kniep, K. Scheinost, H. R. Vollbrecht).
- 252 DEGUSSA, DE-OS 2 154 721, 1973 (F. Geiger, W. Weigert).
- 253 Bayer, DE-OS 2 157 973, 1973 (Z. Kricsfalussy, K. Blöcker, J. Pawlowski, B. Scherhag, R. Weiler).
- 254 DEGUSSA, DE-AS 2 521 581, 1977 (W. Heimberger, G. Schreyer).
- 255 DEGUSSA, DE-AS 2 521 582, 1979 (W. Heimberger, G. Schreyer).
- 256 Röhm, DE-AS 2 442 161, 1975 (W. Gruber, F. Schnierle, G. Schröder).
- 257 Asahi Chemical Ind., JP 5 5020–224, 1980.
- 258 SKW-Trostberg, DE-OS 3 103 963, 1982 (U. Kriele, H. Michand, A. Michlbauer).
- 259 DuPont, US 3 023 077, 1959 (S. V. R. Mastrangelo).
- 260 DEGUSSA, DE 2 931 353, 1982 (F. Bittner, W. Heimberger, K. Henkel, N. Kriebitzsch, M. Petzold).
- 261 Agripat, FR 1 555 981, 1969 (W. J. Evers).
- 262 Ciba-Geigy Corp., US 4 255 167, 1981 (R. M. Babb, M. J. Guillory).
- 263 DEGUSSA, DE-OS 2 363 867, 1975 (F. Geiger, W. Heimberger, H. Schmitt, G. Schreyer).
- 264 DEGUSSA, DE-OS 1 809 607, 1970 (F. Geiger, W. Weigert, T. Lussling).
- 265 DEGUSSA, DE-OS 2 154 721, 1973 (F. Geiger, W. Weigert).
- 266 T. S. Price, S. J. Green, Chem. News J. Phys. Sci. 120 (1920) 101 – 102.
- 267 American Cyanamid, US 3 226 182, 1965 (J. F. Martino).
- 268 W. W. Hartmann, E. E. Dreger, Org. Synth. Coll. 2 (1943) 150 – 151.
- 269 E. Schulek, V. Gervay, Z. Anal. Chem. 92 (1933) 406 – 417.
- 270 B. Bak, H. Hillebert, Org. Synth. 32 (1952) 29 –31.
- 271 C. A. Goy, D. H. Shaw, H. O. Pritchard, J. Phys. Chem. 69 (1965) 1504 – 1507.
- 272 M. S. Kharasch, A. R. Stiles, E. V. Jensen, A. W. Dewis, Ind. Eng. Chem. 41 (1949) 2840 – 2842.
- 273
A. B. Van Cleave,
R. L. Eager,
Can. J. Res. Sect. F
25
(1947)
284 – 290.
10.1139/cjr47f-035 Google Scholar
- 274
A. B. Van Cleave,
H. E. Mitton,
Can. J. Res. Sect. B
25
(1947)
430 – 439.
10.1139/cjr47b-050 Google Scholar
- 275
A. B. Van Cleave,
V. C. Haskell,
J. H. Hudson,
A. M. Kristjanson,
Can. J. Res. Sect. B
27
(1949)
266 – 279.
10.1139/cjr49b-029 Google Scholar
- 276 M. J. Grossman, Chem. Eng. News 58 (1980) no. 35, 43.
- 277 American Cyanamid, US 1 727 093, 1929 (G. Barsky).
- 278
W. Mandelung,
E. Kern,
Justus Liebigs Ann. Chem.
427
(1922)
1 – 34.
10.1002/jlac.19224270102 Google Scholar
- 279 Nilok Chemicals, US 3 429 658, 1969 (G. V. Vosseller).
- 280 B. Witkop, Adv. Protein. Chem. 16 (1961) 221 – 321.
- 281 L. J. Gay-Lussac, Ann. Chim. (Paris) 95 (1815) 172 – 199.
- 282 H. J. Rodewald, Chemiker-Ztg. 89 (1965) 522 – 525.
- 283 R. D. Dresdner, J. Merrit, J. P. Royal, Inorg. Chem. 4 (1965) 1228 – 1230.
- 284 J. B. Conway, R. H. Wilson, A. V. Grosse, J. Am. Chem. Soc. 75 (1953) 499.
- 285 J. Janin, A. Bouvier, Spectrochim. Acta 20 (1964) 1787 – 1798.
- 286 N. C. Robertson, R. N. Pease, J. Am. Chem. Soc. 64 (1942) 1880 – 1886.
- 287 Asahi Chemicals Ind., JP-Kokai 80 20 224, 1980.
- 288 Asahi Chemicals Ind., JP-Kokai 80 422 242, 1980.
- 289 N. B. H. Henis, Y.-H. So, L. L. Miller, J. Am. Chem. Soc. 103 (1981) , 4632 – 4633.
- 290 N. B. H. Henis, L. L. Miller, J. Am. Chem. Soc. 104 (1982) 2526 – 2529.
- 291 Y.-H. So, L. L. Miller, J. Am. Chem. Soc. 103 (1981) 4202 – 4209.
- 292 H. Bock, J. Wittmann, H. J. Arpe, Chem. Ber. 115 (1982) 2326 – 2337.
- 293 DuPont, US 3 564 039, 1971 (O. W. Webster).
- 294 G. J. Janz, 1,4 [One,Four] Cycloaddition React. 1967, 97.
- 295 G. J. Janz, Inorg. Synthesis 5 (1957) 43 – 48.
- 296 Hoechst, DE-OS 2 460 779, 1976 (W. Riemenschneider, P. Wegener).
- 297 Asahi Chem. Ind., JP-Kokai 74 13 3326, 1970.
- 298 DEGUSSA, FR 2 003 105, 1969.
- 299 Asahi Chem. Ind., JP 74 13 110, 1974.
- 300 Asahi Kasei Kogyo, DE 2 456 035, 1974 (S. Kamada, T. Yamashita, T. Ide, R. Ajiki, T. Kitamura).
- 301 Asahi Chem. Ind., JP 76 29 429, 1976.
- 302 W. Riemenschneider, Chem. Ing. Tech. 50 (1978) 55.
- 303 V. D. Parkhomenko, V. K. Steba, A. A. Pivovarov, B. J. Mel'nikov, Khim. Tekhnol. 4 (1981) 3 – 4; Chem. Abstr. 95 (1981) 149 178 h.
- 304 Hoechst, DE 2 427 269, 1982 (W. Riemenschneider, P. Wegener).
- 305 L. M. Weinstock, P. Davis, B. Handelsman, R. Tull, J. Org. Chem. 32 (1967) 2823 – 2829.
- 306 H. W. Roesky, K. Keller, J. W. Bats, Angew. Chem. 95 (1983) 904.
- 307 G. Jacquemin, Ann. Chim. Phys. 6 (1885) 140.
- 308 E. Pfeil, DE 1 163 302, 1965 (E. Pfeil, K. H. Schäfer, R. Nebeling).
- 309 DEGUSSA, DE-AS 2 461 204, 1977 (W. Heimberger, G. Schreyer, H. Schmitt).
- 310 Sagami Chemical Research Center, Tokio, DE-AS 1 297 589, 1969 (S. Nakamura).
- 311 Asahi Kasei Kogyo K. K., DE-AS 2 355 040, 1977 (T. Yamashita, T. Ide, S. Kamada, T. Kitamura).
- 312 Hoechst, DE-AS 2 427 268, 1979 (W. Riemenschneider, P. Wegener).
- 313 Union Oil Comp. of California, US 3 630 671, 1971 (M. J. Block).
- 314 Union Oil Comp. of California, US 3 769 388, 1973 (K. L. Olivier, M. J. Block).
- 315 DEGUSSA, DE-OS 2 012 509, 1971 (W. Heimberger, T. Lussling, W. Weigert).
- 316 DEGUSSA, DE-OS 2 022 454, 1971 (J. Heilos, W. Heimberger, T. Lussling, W. Weigert).
- 317 DEGUSSA, DE-OS 2 022 455, 1971 (J. Heilos, W. Heimberger, T. Lussling, W. Weigert).
- 318 DEGUSSA, DE-AS 2 118 819, 1974 (J. Heilos, W. Heimberger, T. Lussling, W. Weigert).
- 319 Pure Oil Comp., US 2 884 308, 1956 (W. L. Fierce, W. J. Sandner).
- 320 Röhm, DE-OS 2 341 370, 1973 (W. Gruber, G. Schröder).
- 321 Mitsubishi, DE-OS 2 532 307, 1976 (T. Onoda, T. Yokohama, K. Shinpei).
- 322 DEGUSSA, DE-OS 1 927 847, 1970 (F. Geiger, T. Lussling, W. Weigert).
- 323 American Cyanamid, US 2 730 430, 1956 (J. K. Dixon, J. E. Longfield).
- 324 DEGUSSA, DE 1 283 815, 1967 (R. Fahnenstich, H. Schulz).
- 325 Bayer, DE-OS 3 229 415, 1984 (R. Fauß, K. H. Linker, K. Findeisen).
- 326 W. Tsang, S. H. Bauer, M. Cowperthwaite, J. Chem. Phys. 36 (1962) 1768 – 1775.
- 327 Asahi Chemical Industries, JP-Kokai 75 93 893, 1975.
- 328 J. B. Conway, A. V. Grosse, J. Am. Chem. Soc. 80 (1958) 2972 – 2976.
- 329 R. P. Welcher, D. J. Berets, L. E. Sentz, Ind. Eng. Chem. 49 (1957) 1755 – 1758.
- 330 R. Dailey and A. Weissler: Monograph on Ferrocyanide Salts, Food and Drug Administration Report No. FDA/BF–79/28 Washington, D.C., 1978.
- 331 A. Harsten, Blackhill, Engineer (London) 22 (1934) 145 – 174.
- 332 B. G. Anderson, Sewage Works J. 16 (1944) 1156.
- 333 G. Bringmann, R. Kühn, Z. Wasser Abwasser Forsch. 10 (1977) 87 – 98.
- 334 C. Henderson, Q. H. Pickering, A. E. Lencke, Eng. Bull. Purdue Univ. Ext. Ser. 1960, no. 106, 120 – 130.
- 335 W. P. Bridges: Sodium Cyanide as a Fish Poison, Special Scientific Report Fisheries No. 253, US Dept. Interior (1958).
- 336 J. R. Hawley: The Use, Characteristics and Toxicity of Mine-Mill Reagents in the Province of Ontario, Ontario Ministry of Environment, 135 St. Clair Avenue West, Toronto 1972.
- 337 W. Bucksteeg, Schweiz. Z. Hydrol. 22 (1960) 407.
- 338 G. Bringmann, R. Kuhn: “The Toxic Effect of Waste Water on Aquatic Bacteria, Algae, and Small Crustaceans,” Gesund. Ing. 80 (1959) 115 – 120.
- 339 B. G. Anderson: “The Toxicity Thresholds of Various Sodium Salt Determined by the Use of Daphnia magna,” Sewage Works J. 18 (1946) 82.
- 340 Patty's Industrial Hygiene and Toxicology, 3rd ed., J. Wiley & Sons, New York 1978, p. 4845.
- 341 TLVs, Threshold Limit Values for Chemical Substances in the Work Environment, (Adopted by ACGiH for 1984 – 85) American Conference of Governmental Industrial Hygienists.
- 342 MAK. Mitteilung XX der Senatskommission zur Prüfung gesundheitsschädlicher Arbeitsstoffe, 1984.
- 343 F. Brivet, J. F. Delfraissy, M. Duche, P. Bertrand, J. Dormont, “Acute Cyanide Poisoning; Recovery with Nonspecific Supportive Therapy”, Intensive Care med. 9 (1983) 33.
Further Reading
- J. E. Clennell: The Cyanide Handbook, Wexford College Press, Palm Springs, CA 2007.
- D. A. Dzombak, R. S. Ghosh, G. M. Wong-Chong (eds.): Cyanide in Water and Soil, CRC Press, Boca Raton, Fla. 2005.