Spectroscopic properties of porphyrin dimers incorporating phenylenevinylene linkers
Corresponding Author
Anthony K. Burrell
Department of Chemistry, Institute of Fundamental Sciences, Massey University, Private Bag 11222, Palmerston North, New Zealand
Department of Chemistry, Institute of Fundamental Sciences, Massey University, Private Bag 11222, Palmerston North, New Zealand.Search for more papers by this authorDavid L. Officer
Department of Chemistry, Institute of Fundamental Sciences, Massey University, Private Bag 11222, Palmerston North, New Zealand
Search for more papers by this authorDavid C. W. Reid
Department of Chemistry, Institute of Fundamental Sciences, Massey University, Private Bag 11222, Palmerston North, New Zealand
Search for more papers by this authorSonya M. Scott
Department of Chemistry, Institute of Fundamental Sciences, Massey University, Private Bag 11222, Palmerston North, New Zealand
Search for more papers by this authorKeith C. Gordon
Department of Chemistry, University of Otago, PO Box 56, Dunedin, New Zealand
Search for more papers by this authorCorresponding Author
Anthony K. Burrell
Department of Chemistry, Institute of Fundamental Sciences, Massey University, Private Bag 11222, Palmerston North, New Zealand
Department of Chemistry, Institute of Fundamental Sciences, Massey University, Private Bag 11222, Palmerston North, New Zealand.Search for more papers by this authorDavid L. Officer
Department of Chemistry, Institute of Fundamental Sciences, Massey University, Private Bag 11222, Palmerston North, New Zealand
Search for more papers by this authorDavid C. W. Reid
Department of Chemistry, Institute of Fundamental Sciences, Massey University, Private Bag 11222, Palmerston North, New Zealand
Search for more papers by this authorSonya M. Scott
Department of Chemistry, Institute of Fundamental Sciences, Massey University, Private Bag 11222, Palmerston North, New Zealand
Search for more papers by this authorKeith C. Gordon
Department of Chemistry, University of Otago, PO Box 56, Dunedin, New Zealand
Search for more papers by this authorAbstract
A series of free-base, zinc and mixed free-base–zinc porphyrin dimers were investigated using electrochemistry, electronic absorption, resonance Raman and emission studies. The spectroelectrochemistry of these compounds was also examined. The electronic absorption and resonance Raman data suggest that the two porphyrins in the dimer are behaving as independent chromophores with limited communication. However, emission studies show that energy transfer occurs between the two units. The linking unit is seen to have limited influence on the properties of chromophores. Copyright © 2000 John Wiley & Sons, Ltd.
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