Volume 206, Issue 2 pp. 851-858
Original Paper

A Study of Strong Photoluminescence of SiOx:H Films

Zhi-Xun Ma

Zhi-Xun Ma

State Laboratory for Surface Physics, Institute of Semiconductors, Center for Condensed Matter Physics, Chinese Academy of Sciences, P.O. Box 912, 100083 Beijing, People's Republic of China

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Xian-Bo Liao

Xian-Bo Liao

State Laboratory for Surface Physics, Institute of Semiconductors, Center for Condensed Matter Physics, Chinese Academy of Sciences, P.O. Box 912, 100083 Beijing, People's Republic of China

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Wen-Chao Cheng

Wen-Chao Cheng

State Laboratory for Superlattices and Microstructures, Institute of Semiconductors, Chinese Academy of Sciences, P.O. Box 912, 100083 Beijing, People's Republic of China

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Jie He

Jie He

State Laboratory for Surface Physics, Institute of Semiconductors, Center for Condensed Matter Physics, Chinese Academy of Sciences, P.O. Box 912, 100083 Beijing, People's Republic of China

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Guo-Zhen Yue

Guo-Zhen Yue

State Laboratory for Surface Physics, Institute of Semiconductors, Center for Condensed Matter Physics, Chinese Academy of Sciences, P.O. Box 912, 100083 Beijing, People's Republic of China

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Yong-Qian Wang

Yong-Qian Wang

State Laboratory for Surface Physics, Institute of Semiconductors, Center for Condensed Matter Physics, Chinese Academy of Sciences, P.O. Box 912, 100083 Beijing, People's Republic of China

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Hong-Wei Diao

Hong-Wei Diao

State Laboratory for Surface Physics, Institute of Semiconductors, Center for Condensed Matter Physics, Chinese Academy of Sciences, P.O. Box 912, 100083 Beijing, People's Republic of China

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Guang-Lin Kong

Guang-Lin Kong

State Laboratory for Surface Physics, Institute of Semiconductors, Center for Condensed Matter Physics, Chinese Academy of Sciences, P.O. Box 912, 100083 Beijing, People's Republic of China

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Abstract

We have examined photoluminescence (PL), IR absorption and Raman spectra of a series of hydrogenated amorphous silicon oxide (a-SiOx:H, (0 < x < 2)) films fabricated by plasma enhanced chemical vapor deposition (PECVD). Two strong luminescence bands were observed at room temperature, one is a broad envelope comprising a main peak around 670 nm and a shoulder at 835 nm, and the other, peaked around 850 nm, is found only after being annealed up to 1170 °C in N2 environment. In conjunction with IR and Raman spectra, the origins of the two luminescent bands and their annealing behaviors are discussed on the basis of quantum confinement effects.

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